Yazarlar
- Duran, Celal(26)
- Ozdes, Duygu(21)
- Baltaci, Cemalettin(10)
- Gundogdu, Ali(10)
- Gül, Abdulkadir(9)
- Çullu, Mustafa(8)
- Aksüt, Yavuz Selim(7)
- Baltacı, Cemalettin(7)
- Barut, Abdulkadir(7)
- Bozbeyoglu, Pinar(7)
- Erol, Ismail(7)
- Ozeken, Sengul Tugba(7)
- Peker, Iskender(7)
- Eker, Hasan(6)
- Külekçi, Gökhan(6)
- Altuner, Elif Esra(5)
- Ar, Ilker Murat(5)
- Güzel, Melih(5)
- Karahan, Selim(5)
- Karpuz, Ömer(5)
- Kıranşan, Murat(5)
- Odabaş, Halil İbrahim(5)
- Seferoğlu, Mehmet Tevfik(5)
- Uysal, Turan(5)
- Demir Şahin, Demet(4)
- Imamoglu, Mustafa(4)
- Karpuz, Omer(4)
- Top, Yener(4)
- Akar, Bülent(3)
- Akpinar, Muhammet Vefa(3)
- Akpınar, Özlem(3)
- Avci, Ibrahim(3)
- Aydoğmuş, Ercan(3)
- Bozbeyoğlu, Pınar(3)
- Cakir, Mehmet Ali(3)
- Camoglu, Aslihan Yilmaz(3)
- Cavusoglu, Ibrahim(3)
- Daulay, Amru(3)
- Ercikdi, Bayram(3)
- Komut, Osman(3)
Yayınlar
- MakaleYalnız künye2027Efficacy of blue light-assisted ClO2 for Salmonella decontamination on basil leaves: inactivation kinetics, quality preservation, and microbiota dynamics
Lian, Yi; Liu, Songlin; Ozturk, Samet; Wei, Xinyao
Frequent Salmonella outbreaks associated with basil leaves highlight the need for effective postharvest decontamination. Conventional microbial sanitizers often fail to inactivate pathogens while preserving product quality, creating a demand for novel decontamination technologies suitable for basil. In this study, the microbial safety of basil under typical consumption scenarios was evaluated and a blue light-assisted ClO2 (COM) decontamination process for basil leaves was developed. Mathematical models were used to describe the microbial inactivation kinetics, and a systematic comparison was conducted against traditional single-chemical sanitizers (H2O2, HClO, ClO2, and 75% ethanol) in terms of microbial safety and final product quality. Results showed that simulated cooking scenarios, including pizza baking and hot soup immersion, were insufficient to reduce the Salmonella levels below the detection limit (<10 CFU/g) under a high initial load of 9.7 log CFU/g. Compared to the single-chemical treatments, 100 mg/L COM treatment achieved significantly higher decontamination (p < 0.05) by reducing Salmonella and background microbiota by 4.8 and 3.5 log CFU/g, respectively, with treatment time of 15 min. The inactivation kinetics of Salmonella showed a non-linear inactivation kinetics, which was captured by the Weibull model with a low RMSE value (RMSE = 0.16), although the AICc value (11.37) indicated limited model parsimony. Furthermore, the COM treatment significantly reduced bacterial richness (with the Chao1 index decreasing from 316 to 71) and effectively inactivated key spoilage organisms (Pseudomonas) as well as members of the Enterobacteriaceae, Actinomycetota, and Bacillota groups. Compared with the 100 mg/L ClO2 treatment alone (1.40 mg/kg), the 100 mg/L COM treatment resulted in a ClO2 residue concentration below the detection limit, without significantly altering visual appearance, color, chlorophyll content, total phenolics, or polyphenol oxidase activity (p > 0.05). Overall, blue light-assisted ClO2 treatment effectively reduced microbial contamination and reduced ClO2 residues while preserving the physical quality of basil, representing a promising decontamination approach for the fresh produce industry.
- MakaleAçık Erişim2026Lojıstık verımlılıkten sürdürülebılır kalkınmaya: G20 ülkelerı ıçın lpı ve sdgs endekslerının entegratıf analızı
Macit, Nazife Sahin
Bu çalışma, G20 ülkelerinde lojistik performans ile sürdürülebilir kalkınma arasındaki etkileşimi, 2022 yılı Lojistik Performans Endeksi (LPI) ve seçilmiş Sürdürülebilir Kalkınma Hedefleri (SKH) göstergeleri temelinde, bütüncül bir perspektifle incelemiştir. Korelasyon analizi ile LPI genel skoru ve alt boyutları ile SKH göstergeleri arasındaki ilişkinin boyutunu ve yönünü; sonrasında çok kriterli karar verme (ÇKKV) ve Borda yöntemleri ile ülkelerin bütünleşik performans sıralamasını açığa çıkarmayı hedeflemektedir. Korelasyon analizleri, özellikle gümrük işlemleri verimliliği, lojistik hizmetlerin kalitesi ve zamanında teslimat alt boyutları ile ithal oransızlaşma arasında; gümrük işlemleri verimliliği ile temel içme suyu hizmetlerine erişim arasında, zamanında teslimat ile temel sanitasyon hizmetlerine erişim gibi SKH göstergeleri arasında anlamlı pozitif ilişkiler olduğunu göstermiştir. Diğer taraftan, yetersiz beslenme oranı ile LPI ve alt göstergeleri arasında negatif fakat anlamsız bir ilişkinin olduğu, ayrıca elektriğe erişim ile LPI göstergeleri arasında da anlamlı bir korelasyon bulunmadığı tespit edilmiştir. SITDE yöntemi ile hesaplanan kriter ağırlıkları hesaba katılarak ülkelerin performanslarının değerlendirilmesinde FANMA, SWEI ve TODIFFA yönteminden faydalanılmış ve ortaya çıkan sonuçların birleşimi ise Borda yöntemi ile gerçekleştirilmiştir. Yapılan bütünleşik değerlendirme sonucunda Almanya, Fransa ve Çin’in en yüksek entegre lojistik ve sürdürülebilir kalkınma performansına sahip olduğu; Güney Afrika, Endonezya ve Meksika’nın ise en düşük performans sergilediği ortaya çıkmıştır. Sonuçlar, gelişmiş lojistik altyapının hem ekonomik rekabet gücünü hem de sürdürülebilir kalkınmaya katkıyı desteklediğini ortaya koymakta ve politika yapıcılar için lojistik ve sürdürülebilirlik stratejilerinin entegrasyonuna yönelik önemli ipuçları sunmaktadır.
- MakaleAçık Erişim2026Removal of Pb(II) ions from aqueous solutions by Brevibacillus agri-loaded clay: Kinetic, isotherm, and artificial neural network modeling
Belduz, Ali Osman; Inan, Kadriye; Duran, Celal; Ozdes, Duygu; Ozeken, Sengul Tugba; Nalçaoğlu, Aleyna; Şeker, Serdal
In this study, a novel and efficient adsorbent was developed by immobilizing inactivated Brevibacillus agri biomass onto an abundant natural clay via a simple synthesis route for Pb(II) removal from aqueous media. The adsorption behavior of inactivated Brevibacillus agri-loaded clay (BLC) was evaluated using batch experiments by investigating the effects of initial solution pH (2.0–6.0), BLC dosage (0.5–4.0 g/L), contact time (1–180 min), initial Pb(II) concentration (10–420 mg/L), temperature (25–80°C), and the presence of foreign ions. The optimum conditions were determined to be an initial solution pH of 5.0 and a contact time of 120 min. Isotherm models were applied to elucidate the interactions between Pb(II) ions and BLC, while kinetic studies were conducted to evaluate the adsorption performance and underlying mechanisms. The maximum adsorption capacity of BLC was determined as 65.4 mg/g according to the Langmuir isotherm model. Thermodynamic parameters revealed that Pb(II) adsorption on BLC was exothermic, feasible, and spontaneous at 25ºC. Artificial neural network (ANN) studies provided highly accurate predictions by modeling and confirmed the reliability and applicability of the model for Pb(II) removal in industrial applications. This study presents an innovative and sustainable approach for heavy metal removal, offering an effective solution applicable to environmental remediation processes.
- MakaleAçık Erişim2026Formulation of mechanical properties of hybrid fiber alkali-activated concretes by data analysis
Aksut, Yavuz Selim; Yetgín, Sukru
In this study, ground blast furnace slag (GBFS) and waste volcanic rock dust (RD) produced in a natural stone processing plant were used as binders. The binders were activated with Sodium Hydroxide (NaOH) and Sodium Silicate (Na2SiO3) to produce two types of concrete: alkali-activated concrete without fibers (AAC) and alkali-activated concrete with fibers (FAAC). In the production of concrete, steel and polyester fibers were used separately and hybrid at 0.25%, 0.50%, 0.75% and 1.0% by volume and a total of 117 15x15x15 cm cube specimens were produced. The mechanical properties of the specimens were evaluated by concrete surface hardness, ultrasonic pulse velocity and concrete compressive strength tests at 3, 7 and 28 days. The results obtained using non-destructive test methods were matched with concrete compressive strength values using various empirical formulas. Calculated concrete compressive strength values and actual concrete compressive strength values were compared using data analysis method. As a result, it was observed that there was a very significant correlation between the experimental compressive strength and the combined method in which 7-day surface hardness and ultrasound transmission rate were used together to calculate the compressive strength.
- MakaleYalnız künye2026Financial Inclusion, Energy Intensity, and Natural Resources: Environmental Insights From BRICS and MINT Economies
Pala, Fahrettin; Barut, Abdulkadir; Torusdag, Mustafa; Pilatin, Abdulmuttalip; Henni, Mohamed Djafar
In developing economies, rapid economic growth intensifies environmental pressures, thereby increasing the importance of financial inclusion, energy intensity, and natural resource dependence for environmental sustainability. This situation necessitates a holistic examination of the determinants of environmental degradation in emerging markets, which motivates this study. In this context, the study examines the effects of financial inclusion, energy intensity, and natural resource rents on carbon dioxide (CO2) emissions in BRICS and MINT countries and empirically tests the validity of the Environmental Kuznets Curve (EKC) hypothesis. Accordingly, annual panel data covering the period 2000-2020 are analysed using a machine learning (ML)-based estimation framework, the Augmented Mean Group (AMG) estimator, and Panel Quantile Regression (PQR). The findings indicate that natural resource rents increase CO2 emissions in BRICS, whereas they reduce emissions in MINT. Moreover, energy intensity and income per capita are found to increase CO2 emissions across all quantiles in both country groups. The environmental impact of financial inclusion is heterogeneous, reducing CO2 emissions in BRICS countries while increasing emissions in MINT countries. These results underscore the critical importance of explicitly incorporating country-specific heterogeneity into environmental sustainability policy design.
- MakaleAçık Erişim2026Mercury Removal from Glycine Leach Solutions Using Sodium Sulfide (Na2S) Precipitation
Kantarci, Sadiye; Alp, Ibrahim; Youpoungam, Abdou Azizi; Sivircik, Salih
Amino acid leaching has been considered an environmentally friendly alternative for gold recovery; however, the dissolution of mercury (Hg) during the leaching of amalgamation tailings remains a major challenge. This study is a novelty study that focuses on Hg removal by passing the Hg-containing tailings, previously processed by amalgamation, into solution via glycine (NH(2)CH2COOH) leaching. In this regard, a precipitation method using sodium sulfide (Na2S) was developed to remove Hg from solutions obtained after glycine leaching. The effects of precipitation time, pH, Na2S dosage, and temperature were investigated. The effects of pH, precipitation time, and temperature were found to be limited within the investigated ranges. The results showed that Na2S dosage was the most effective parameter in mercury removal. The initial Hg concentration of 12,160 ppb was reduced to 223 ppb at a Na2S:Hg molar ratio of 60, corresponding to approximately 98% removal efficiency under the selected operating conditions. Increasing the Na2S:Hg ratio to 80 resulted in a slightly higher removal efficiency (similar to 99%) with a final Hg concentration of 144 ppb; however, a ratio of 60 was considered optimal in terms of reagent consumption and process efficiency. The outcomes indicate that Hg removal with Na2S is a rapid and effective process under alkaline conditions, while Au remains in solution and Cu and Ag are partially removed, indicating limited selectivity and the need for further optimization. Therefore, this study provides a basis for developing more environmentally friendly processes for amalgamation tailings.
- MakaleYalnız künye2026Selective extraction of rare earth elements from end-of-life NdFeB magnets via low-temperature NH4Cl-based chlorination roasting and water leaching
Kumas, Cavit; Prasetia, Hendra; Sumardi, Slamet; Astuti, Widi; Mufakhir, Fika Rofiek; Daulay, Amru; Wicaksono, Mahruri Arif
Neodymium-iron-boron (NdFeB) magnets are critical components in the transition to a low-carbon energy economy due to their superior magnetic properties. They have significantly higher rare earth element (REE) content (25-35%) compared to natural resources (0.15-2%), making end-of-life NdFeB magnets a valuable secondary REE source. In this study, the selective recovery of REEs from end-of-life NdFeB magnets was investigated using water leaching following chlorination roasting with NH4Cl. A series of experiments was conducted to evaluate the effect of NH4Cl on the NdFeB magnet ratio, roasting temperatures, and roasting duration. Under optimal conditions (300 degrees C, 3 h, NH4Cl at twice the stoichiometric requirement), the roasted products were subjected to water leaching (500 rpm, 90 degrees C, liquid - solid ratio of 20 mL/g, 1 h). resulting in over 95% REE dissolution. Rare earth oxalates were precipitated from the pregnant leach solution with 90% efficiency using 1.5 times the stoichiometric requirement of oxalic acid. Subsequent calcination at 850 degrees C for 2 h yielded rare earth oxides with 99.8% REE purity. Moreover, the dissolution of iron was effectively suppressed through a simple two-stage Fe(OH)3 precipitation step, providing a more economical and selective recovery route. Les aimants de n & eacute;odyme-fer-bore (NdFeB) sont des composants critiques de la transition vers une & eacute;conomie & eacute;nerg & eacute;tique & agrave; faible carbone gr & acirc;ce & agrave; leurs propri & eacute;t & eacute;s magn & eacute;tiques sup & eacute;rieures. Ils ont une teneur en & eacute;l & eacute;ments de terres rares (ETR) sup & eacute;rieures (25-35%) aux ressources naturelles (0.15-2%), ce qui rend les aimants de NdFeB en fin de vie une source secondaire pr & eacute;cieuse d'ETR. Dans cette & eacute;tude, on a examin & eacute; la r & eacute;cup & eacute;ration s & eacute;lective des ETR des aimants de NdFeB en fin de vie par lixiviation aqueuse apr & egrave;s grillage chlorurant avec du NH4Cl. On a effectu & eacute; une s & eacute;rie d'exp & eacute;riences pour & eacute;valuer l'effet du rapport NH4Cl/aimant de NdFeB, des temp & eacute;ratures et de la dur & eacute;e de grillage. Dans des conditions optimales (300 degrees C, 3 h et une concentration de NH4Cl deux fois sup & eacute;rieure & agrave; la st oe chiom & eacute;trie requise), on a soumis les produits grill & eacute;s & agrave; une lixiviation aqueuse (500 tr/min, 90 degrees C, rapport liquide/solide de 20 mL/g, 1 h) conduisant & agrave; une dissolution de plus de 95% des ETR. On a pr & eacute;cipit & eacute; les oxalates de terres rares & agrave; partir de la solution de lixiviation enrichie avec une efficacit & eacute; de 90% en utilisant 1.5 fois la quantit & eacute; st oe chiom & eacute;trique requise d'acide oxalique. Une calcination ult & eacute;rieure & agrave; 850 degrees C pendant 2 h a produit des oxydes de terres rares d'une puret & eacute; de 99.8%. De plus, la dissolution du fer & eacute;tait efficacement supprim & eacute;e par une simple & eacute;tape de pr & eacute;cipitation de Fe(OH)3 en deux phases, offrant une voie de r & eacute;cup & eacute;ration plus & eacute;conomique et plus s & eacute;lective.
- MakaleYalnız künye2026An integrated process for rare earth elements recovery and silica production from Turkish bauxite-related ores
Uysal, Turan; Erüst, Ceren; Erdemoglu, Murat; Sis, Hikmet
The evaluation of bauxite-associated shales as a secondary source of rare earth elements (REEs) is strategically important for securing a sustainable supply of critical raw materials used in advanced technologies. In this study, shale ore associated with bauxite, unsuitable for aluminium production due to its high silica content, was investigated as a potential resource for valuable REEs. The effect of thermal activation on REE recovery was examined, and the potential use of the leach residue as a silica source was assessed. Based on acid leaching results, the optimum calcination temperature was identified as 700 degrees C. Under these conditions, high REE recoveries were achieved: 92.9% La, 89.9% Ce, 89.0% Pr, 88.7% Nd, and 73.0% Sm. After leaching, the residue was enriched in alumina and silica. To improve silica purity and recover remaining REEs and Al, a second-stage leaching process was applied. This resulted in a byproduct containing 55% SiO2 with a specific surface area of 48 m2 g-1, indicating its potential as a silica source. The results demonstrate that bauxite-associated shale can be sustainably valorised through intensive milling, calcination, and acid leaching, enabling efficient REE recovery and the production of a silica-rich byproduct. L'& eacute;valuation de schistes associ & eacute;s & agrave; la bauxite comme source secondaire d'& eacute;l & eacute;ments de terres rares (ETR) est strat & eacute;giquement importante pour garantir un approvisionnement durable en mati & egrave;res premi & egrave;res critiques utilis & eacute;es dans les technologies avanc & eacute;es. Dans cette & eacute;tude, on a examin & eacute; le minerai de schiste associ & eacute; & agrave; la bauxite, inappropri & eacute; & agrave; la production d'aluminium en raison de sa teneur & eacute;lev & eacute;e en silice, comme ressource potentielle d'ETR pr & eacute;cieux. On a examin & eacute; l'influence de l'activation thermique sur la r & eacute;cup & eacute;ration des ETR et l'on a & eacute;valu & eacute; l'utilisation potentielle du r & eacute;sidu de lixiviation comme source de silice. D'apr & egrave;s les r & eacute;sultats de la lixiviation acide, on a identifi & eacute; la temp & eacute;rature optimale de calcination & agrave; 700 degrees C. Dans ces conditions, on a obtenu des r & eacute;cup & eacute;rations d'ETR & eacute;lev & eacute;es: 92.9% de La, 89.9% de Ce, 89.0% de Pr, 88.7% de Nd et 73.0% de Sm. Apr & egrave;s la lixiviation, le r & eacute;sidu & eacute;tait enrichi en alumine et en silice. Afin d'am & eacute;liorer la puret & eacute; de la silice et de r & eacute;cup & eacute;rer les ETR et l'Al restants, on a appliqu & eacute; une deuxi & egrave;me & eacute;tape de lixiviation. Cela a engendr & eacute; un sous-produit contenant 55% de SiO2 et pr & eacute;sentant une surface sp & eacute;cifique de 48 m2/g, indiquant son potentiel en tant que source de silice. Les r & eacute;sultats d & eacute;montrent que le schiste associ & eacute; & agrave; la bauxite peut & ecirc;tre valoris & eacute; de mani & egrave;re durable par broyage intensif, calcination et lixiviation acide, permettant une r & eacute;cup & eacute;ration efficace des ETR et la production d'un sous-produit riche en silice.
- MakaleAçık Erişim2026An Approach to the Evaluation of Spent Coffee Grounds: Use in Functional Apricot Bar Formulation
Berktaş, Serap; İncegül, Yasemin; Çam, Mustafa
Fruit bars are snack products obtained by mushing fruit, adding sugar, pectin, and other ingredients, and drying the resulting mixture. The aim of this study was to investigate the effects of spent coffee grounds (SCGs), a valuable waste product of the coffee industry, on the physicochemical and bioactive properties of a snack fruit bar enriched with bioactive properties after mushing apricot fruit. Results showed that apricot bars containing 2.5%, 5%, and 7.5% SCGs had higher phenolic, flavonoid, antioxidant activity (ABTS and DPPH), ascorbic acid, and total carotenoid contents compared to the control group. Especially, the fruit bar containing 7.5% SCG stood out in terms of tested bioactive properties. Therefore, it has been determined that the antioxidant and phenolic compounds found in SCGs are also reflected in fruit bars. Furthermore, α-amylase and lipase inhibition values were increased in the enriched fruit bars, and the potential of the developed fruit bars to exhibit antidiabetic and antiobesity properties was improved. Furthermore, the intestinal phase phenolic compound bioaccessibility values of the enriched fruit bars (87.40%–133.3%) were higher than the SCG-free control fruit bar (91.7%). The potential for creating an alternative product with improved nutritional and economic benefits by adding a waste product rich in bioactive compounds such as SCGs to the fruit bar formulation was evaluated. Such products could be considered a new alternative to a functional snack product group rich in bioactive substances that could be incorporated into today's diet.
- MakaleAçık Erişim2026GREEN SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF IRON OXIDE NANOPARTICLES FROM ROBINIA PSEUDOACACIA L. FRUITS FOR DYE REMOVAL FROM AQUEOUS SOLUTIONS
Demir, Semra; Akar, Bülent; Baltaci, Cemalettin
In this study, iron oxide nanoparticles were produced and characterized using a green synthesis method with Robinia pseudoacacia fruits. The structural and functional properties of the nanoparticles were investigated using XRD, TEM/EDX, and FTIR analyses. The results indicated that the produced iron oxide nanoparticles had nanoscale particle sizes and exhibited a poorly crystalline (predominantly amorphous) structure according to XRD analysis. The comparative adsorption performance of the synthesized FeONPs and fruit powder in the removal of malachite green (MG), phenol red (PR) and methylene blue (MB) from aqueous solutions was evaluated. According to the results, the adsorption capacity followed the order MB> MG > PR. FeONPs exhibited consistently higher Qₑ values across all dye systems compared to the fruit powder. High removal efficiencies were obtained at low and moderate initial concentrations, while increasing the adsorbent dose enhanced the overall removal but resulted in a reduction in the adsorption capacity per unit mass. The obtained findings indicate that biosynthesized iron oxide nanoparticles can be used as an efficient and environmentally friendly adsorbent for eliminating environmental pollutants.
- MakaleAçık Erişim2026A concise approach for interpreting the removal kinetic of 2,4-D by carbonized peanut shell
Gülen, Jale; Karpuz, Ömer
The present study displays the adsorption characteristics of dichloro phenoxy acetic acid (2.4-D) on biomass-based peanut shell (BPC) carbon. Experiments were conducted by varying some parameters like concentration, pH, and temperature. 2,4-D adsorption uptake was increased from 0.504 to 3.826 mg/g with rising concentration from 1 µg/mL to 5 µg/mL and giving the highest adsorption at acidic pH. 1.605 mg/g uptake was obtained at pH 2.7. The data were in good harmony with Langmuir, Freundlic, Dubinin-Radushkevich (DR), and Generalized isotherms. The monolayer adsorption capacity was found as 42.62 ± 0.3257 mg/g. The kinetic was governed by the first-order kinetic. Various kinetic models were employed and particle diffusion was predominated for 2,4-D adsorption. Thermodynamics were explained in detail. The mean adsorption energy (E) was shown by the physical sorption, and Gibbs energy was the indicator of the spontaneous nature of the adsorption. Standard enthalpy, entropy, and Gibbs values were recorded as 5.064 ± 139.84, 18.849 ± 0.148, and 0,7414 ± 0.0943 J/mol. The results showed that BPC was an eco-friendly and cost-effective material.
- MakaleAçık Erişim2026Investigation of the Antioxidant, Antibacterial, and Food Safety Potential of Silver and Copper Nanoparticles Green Synthesized Using Pointed Cherry Laurel (Prunus laurocerasus L.) Extract
Kobya, Havva Nur; Gül, Abdulkadir; Karpuz, Ömer; Baltacı, Cemalettin
This study reports the green synthesis of silver (PFAgNPs) and copper (PFCuNPs) nanoparticles using an aqueous extract of pointed cherry laurel (Prunus laurocerasus L.) fruit (PF-E) and explores their applicability in food safety. The NPs were characterized via UV–Vis spectroscopy, FT-IR, XRD, SEM, EDX, and TEM confirming their successful formation and morphology. Total phenolic content (TPC), flavonoid content (TFC), and antioxidant capacity (TAC) were measured for both PF-E and the synthesized NPs. While PFCuNPs exhibited higher TPC, PFAgNPs showed superior TFC and TAC. Notably, antioxidant assays (DPPH, ABTS, FRAP) indicated stronger radical scavenging activity for PFCuNPs. Antibacterial tests against Escherichia coli, Enterococcus faecalis, Staphylococcus aureus, and Pseudomonas aeruginosa revealed broad-spectrum activity of PFAgNPs, with the highest inhibition against E. coli (19.4 ± 0.3 mm), whereas PFCuNPs showed dose-dependent efficacy, strongest against E. faecalis (9.6 ± 0.2 mm). LC–MS/MS analysis of the PF-E extract revealed quinic acid (63.42 mg/g), chlorogenic acid (2.38 mg/g), protocatechuic acid (0.07 mg/g), protocatechuic aldehyde (0.04 mg/g), hesperidin (0.03 mg/g), and naringenin (0.02 mg/g) as major components. The adsorption efficiencies of the synthesized PFAgNPs and PFCuNPs were evaluated against the toxic food contaminants patulin and HMF using both standard aqueous solutions and real food systems (apple juice). In standard aqueous solutions, PFAgNPs achieved removal efficiencies of 70.96% for patulin and 52.22% for HMF, while PFCuNPs showed 61.08% and 36.38%, respectively, at 5 g/L after 240 min. In real food systems, the adsorption efficiencies decreased, with PFAgNPs and PFCuNPs removing 34.24% and 32.90% of patulin, and 39.09% and 31.87% of HMF, respectively. The adsorption kinetics of HMF and patulin onto PFCuNP and PFAgNP were found to conform to both the pseudo-first-order and pseudo-second-order kinetic models for aqueous solutions as well as real samples. These findings confirm that the biosynthesized NPs offer dual functionality as antibacterial agents and toxin adsorbents, presenting a green, sustainable approach to food safety enhancement.
- MakaleAçık Erişim2026The Spiritual Roots of Sustainable Consumption Among Muslim Consumers: Environmental and Health Consciousness as Mediating Pathways
Hacıkeleşoğlu, Hızır; Avcı, İbrahim; Vural, Muhammet Enes
Research on sustainable consumption has largely emphasized secular motivations, leaving the psychological role of spirituality/religiosity underexplored within Muslim societies. Addressing this gap, this study investigates the relationship between spirituality and sustainable consumption behaviors (SCBs) among Muslim consumers in Türkiye, with environmental and health consciousness examined as parallel mediating mechanisms. Data were collected from 414 adult Muslim consumers through an online survey and analyzed using confirmatory factor analysis and structural path analysis via Hayes’ PROCESS macro (Model 4). The empirical findings indicate that spirituality is significantly and positively associated with sustainable consumption behaviors both directly and indirectly. Environmental consciousness emerged as a numerically stronger mediating pathway than health consciousness in the relationship between spirituality and sustainable consumption. Notably, when both mediators are included in the model, the direct path from spirituality to sustainable consumption behaviors becomes non-significant, consistent with a full-mediation pattern in the estimated model, in line with the value–attitude–behavior hierarchy. These results suggest that spirituality’s association with consumption decisions is, within the estimated model, transmitted through intervening attitudinal states. The study suggests that sustainable consumption initiatives in Muslim contexts can be meaningfully strengthened by integrating eco-friendly practices with consumers’ underlying spiritual and religious values.
- MakaleYalnız künye2026Identification of patulin-producing Penicillium isolates from decayed apples, their patulin production profiles, and the feasibility of high-purity patulin preparation
Dağ, Murat; Bozbeyoğlu, Pınar; Gül, Abdulkadir; Karpuz, Ömer; Baltacı, Cemalettin
This study presents a combined evaluation of patulin contamination by integrating fungal identification, assessment of toxin production, and the feasibility of obtaining high-purity patulin from biological sources. Fungal isolates recovered from naturally decayed apples collected from different agricultural environments in Türkiye were identified using MALDI-TOF MS and morphological characteristics, and were assigned to Penicillium expansum at a probable species level. The patulin production potential of the isolates was evaluated by inoculating them onto red, yellow, and green apple matrices under controlled laboratory conditions over an extended incubation period. Quantitative analysis using HPLC–UV, supported by LC–MS/MS confirmation, revealed substantial variability in patulin levels (7.58–49.80 mg/kg) depending on both isolate and apple matrix. Higher patulin levels were generally observed in yellow apple tissues, whereas lower levels were detected in red apples, suggesting a possible influence of matrix-related compositional factors. In addition, patulin was isolated and enriched using column chromatography with TLC-guided fractionation, yielding a high-purity compound (98.8%) with low moisture content (0.21%). Structural identity was confirmed by LC–MS/MS analysis. Overall, the findings indicate that patulin production is influenced by strain-level variability and matrix-related factors. Furthermore, the study demonstrates the feasibility of producing high-purity patulin suitable for in-house analytical applications. However, the produced material should not be considered a certified reference material, and further validation would be required for broader analytical use.
- MakaleYalnız künye2026Determining the effect of blockchain technology on the medical waste management process in the circular economy framework using integrated FUCOM-ARAS methods
Batar, Bilge; Peker, İskender
Background: The circular economy concept aims to reduce environmental impact by promoting resource reuse, minimizing waste through input reduction, and lowering costs. Rising costs are leading healthcare facilities and other organizations to prioritize medical waste management. Blockchain technology, introduced in 2008, functions as a database of auditable and traceable transactions built on a network of trust-based blocks. Key features such as transparency, reliability, accessibility, flexibility, and automation can significantly enhance the efficiency of medical waste management processes, thereby contributing to the circular economy. Objective: This study aims to evaluate the effectiveness of medical waste management—critical for healthcare institutions and sustainable development—within the framework of the circular economy. Multi-criteria decision-making (MCDM) techniques are used to assess the contributions of blockchain technology to this process. Methods: A literature review was conducted to identify relevant criteria and alternatives. The Full Consistency Method (FUCOM), an MCDM technique, was used to calculate the weight of each criterion. The Additive Ratio Assessment (ARAS) method was applied to rank the alternatives. Conclusion: According to the analysis's findings, transparency, traceability, and dependability are the three most important criteria, respectively. The stages of medical waste storage, disposal, and transportation have the highest priority ratings among the available options. According to these results, incorporating blockchain technology into medical waste management can significantly improve system traceability and reliability, enhancing its role in the circular economy. Notably, the storage phase is the most appropriate for implementing blockchain. However, the other phases’ comparatively high appropriateness scores attest to the technology's capacity to be used efficiently across the waste management cycle. This integration promotes traceable and transparent procedures, guaranteeing dependable waste management procedures in healthcare facilities and supporting the objectives of the circular economy and sustainability. Additionally, the sensitivity analysis shows that when the weighting of criterion is altered, the ranking of alternatives changes as well. This dynamic interaction emphasizes how blockchain technology may be successfully integrated into all phases rather than being restricted to just one because waste management is cyclical and holistic.
- Kitap BölümüYalnız künye2026Fungi-Derived Food Additives and Flavors
Arpa Zemzemoğlu, Tuba Eda; Eker, Tülin
The growing global population, the decline in edible food sources, technological advancements, and limited time have led to significant changes in society's eating habits. The increasing preference for ready-to-eat and semi-prepared foods has also resulted in higher consumption of food additives. In today's conditions, food additives are used at various stages of the food supply chain, from farm to fork, for different purposes. However, excessive intake of food additives may have negative health effects. For this reason, there has been a growing interest in natural food additives in recent years. Due to their functional properties, edible mushrooms are widely used as versatile ingredients in food product development. This chapter aims to determine the potential of edible mushrooms as food additives. Edible mushrooms can be used as meat substitutes in various food products, reducing fat and animal protein content while increasing dietary fiber and amino acid levels. When used as fat replacers, they lower fat levels in processed foods and enhance sensory properties. When incorporated as flour substitutes in baked goods, they boost dietary fiber, protein content, and antioxidant capacity. Additionally, mushrooms act as natural salt and phosphate substitutes, reducing sodium levels in meat products and replacing synthetic additives while maintaining sensory acceptability and product quality. Mushrooms also have great potential as natural colorants. Their natural origin, low-cost and high-yield production, and wide color spectrum make them suitable for use as food additives. These multifunctional roles of edible mushrooms highlight their potential to enhance nutritional profiles and promote sustainability in food formulations.
- MakaleYalnız künye2026Utilizing Pollutant Waste Cheese Whey into Low-cost Broth for Bacterial Growth and Protein Production
Alkowlani, Amir Towfiq Hasan; Beldüz, Ali Osman; Çanakçi, Sabriye; Bektaş, Kadriye İnan; Ay, Fulya; Özyurt, Taner; Yıldız, Oktay
Cheese whey (CW), an abundant and nutrient-rich byproduct of cheese production, accounts for approximately 85% of milk volume and is generated globally in quantities reaching 145–200 million tons annually. Despite its biochemical complexity and high organic load, CW remains underutilized in microbial biotechnology. Its pollutant potential is up to 100 times higher than domestic sewage due to extreme biological oxygen demand (BOD), chemical oxygen demand (COD), high nutrient content, and acidity. Untreated discharge causes severe oxygen depletion, damages aquatic ecosystems, degrades soil, and contributes to climate change. This study evaluates CW as a sustainable and cost-effective alternative to synthetic bacterial growth media. Ten bacterial strains were cultured for 17 h in different forms of CW fresh, aged (up to two years), and dried and compared with standard Luria Bertani (LB) medium. Bacterial growth was assessed using optical density at 600 nm (OD₆₀₀), and protein yields were measured in µg/µL. CW supported growth ranged from OD₆₀₀ 2.36–4.46, comparable to 2.53–4.16 in LB, with protein yields between 0.19 and 0.43 µg/µL versus 0.18–0.44 µg/µL in LB. These findings demonstrate that CW can effectively support bacterial proliferation and protein production, offering a novel valorization route for a major agro-industrial pollutant while reducing environmental harm and fermentation costs.
- MakaleYalnız künye2026Improving the hydrothermal reduced graphene oxide supercapacitor with heat-moisture-treated potato starch as binder
Daulay, Amru; Yassaroh, Yassaroh; Samada, Lukmanul Hakim; Amrulloh, M. Hanif; Kumaş, Cavit; Nariswari, Mentari Kirana; Putri, Devi Mariska; Chambioso, Yugo
Alternative binders that can be processed in water are still in the early stages of development for more efficient and sustainable supercapacitors. However, their electrochemical performance is still below average. This study uses heat-moisture-treated starch (starch HMT) as a binder for reduced graphene oxide (rGO) supercapacitors. Starch HMT has been fabricated at 120 °C. The XRD diffractogram exhibits peaks at 2θ angles of 15°, 17°, 22°, and 24°. The 2θ values indicate that potato starch is of type B. FTIR spectra show the formation of OH, C–O–C, C-O, C–O–C, and C-H bonds. SEM images show cracks in the morphology. Electrochemical testing shows a specific capacity of 230 F/g at a current density of 1 A/g. The charge–discharge stability of the electrodes at 5000 cycles is 90%. These results offer a framework for developing electrode materials and binders for supercapacitors.
- Derleme MakaleYalnız künye2026Activated Carbon Derived from Coal and its Application for Wastewater Treatment
Daulay, Amru; Yassaroh, Yassaroh; Huda, Miftahul; Sumardi, Slamet; Prasetia, Hendra; Kumaş, Cavit; Yusmiati; Lestari, Devi
Coal is used to produce fuels, chemicals, and other high-value-added products to improve efficiency. Activated carbon (AC) derived from coal is an important part of coal’s resource utilization and is high-value-added. This study presents relevant research on AC derived from coal, including raw material selection, preparation methods, modification techniques, and regeneration methods. The potential applications of AC derived from coal for the adsorption of contaminants, including heavy metals, pesticides, pharmaceutical compounds, and organic and inorganic compounds, are reviewed. One of the advantages of using AC derived from coal in wastewater treatment is high adsorption, low cost, and sustainability.
- Kitap BölümüYalnız künye2026Bio-based and Biodegradable Nanocomposites for Clean Energy Applications
Bozbeyoglu, Pinar; Altuner, Elif Esra
The growing global demand for energy and the environmental concerns associated with fossil fuels have accelerated the search for sustainable alternatives. Bio-based and biodegradable nanocomposites represent a new generation of materials that combine ecological compatibility with superior mechanical, thermal, and electrical properties. This chapter provides a comprehensive overview of bio-based polymer matrices (such as PLA, PHA, PBS, PEF, PVA, and natural polymers like cellulose, chitosan, and lignin) and their integration with nanofillers, including graphene, carbon nanotubes, TiO2, ZnO, and nanoclay. The synergistic effects of these hybrid structures are discussed in the context of clean energy technologies, such as solar cells, fuel cells, batteries, supercapacitors, and piezoelectric nanogenerators. In addition, the chapter highlights green synthesis routes, characterization methods, life cycle assessment (LCA), and industrial perspectives, emphasizing how nanocomposite design bridges performance enhancement with environmental sustainability.
