Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYalnız künye2013Scopus SJRQ1
    Evaluation of the effect of earthquake frequency content on seismic behavior of cantilever retaining wall including soil-structure interaction

    Cakir, Tufan

    A three-dimensional backfill-structure-soil/foundation interaction phenomenon is simulated using the finite element method in order to analyze the dynamic behavior of cantilever retaining wall subjected to different ground motions. Effects of both earthquake frequency content and soil-structure interaction are evaluated by using five different seismic motions and six different soil types. The study mainly consists of three parts. In the first part, following a brief review of the problem, the finite element model with viscous boundary is proposed under fixed-base condition. In the second part, analytical formulations are presented by using modal analysis technique to provide the finite element model verification, and reasonable agreement is found between numerical and analytical results. Finally, the method is extended to further investigate parametrically the effects of not only earthquake frequency content but also soil/foundation interaction, and nonlinear time history analyzes are carried out. By means of changing the soil properties, some comparisons are made on lateral displacements and stress responses under different ground motions. It is concluded that the dynamic response of the cantilever wall is highly sensitive to frequency characteristics of the earthquake record and soil-structure interaction.

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  • MakaleAçık Erişim2013Scopus SJRQ2
    The effect of prenatal exposure to 900-MHz electromagnetic field on the 21-old-day rat testicle

    Hanci, Hatice; Odaci, Ersan; Kaya, Haydar; Aliyazicioǧlu, Yüksel; Turan, Ibrahim; Demir, Selim; Çolakoǧlu, Serdar

    The aim of this study was to investigate the effect of exposure to a 900-MHz electromagnetic field (EMF) in the prenatal term on the 21-old-day rat testicle. Pregnant rats were divided into control (CG) and EMF (EMFG) groups. EMFG was exposed to 900-MHz EMF during days 13-21 of pregnancy. Newborn CG rats were obtained from the CG and newborn EMFG (NEMFG) rats from the EMFG. Testicles were extracted at postnatal day 21. Lipid peroxidation and DNA oxidation levels, apoptotic index and histopathological damage scores were compared. NEMFG rats exhibited irregularities in seminiferous tubule basal membrane and epithelium, immature germ cells in the lumen, and a decreased diameter in seminiferous tubules and thickness of epithelium. Apoptotic index, lipid peroxidation and DNA oxidation were higher in NEMFG rats than in NCG. 21-day-old rat testicles exposed to 900-MHz EMF in the prenatal term may be adversely affected, and this effect persists after birth.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
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  • MakaleYalnız künye2013Scopus SJRQ1
    The effect of composite patches on the failure of adhesively-bonded joints under bending moment

    Akpinar, Salih

    In this study, it was aimed to compare mechanical behavior of double-strap joints with aluminum (AA2024-T3) or 16-ply laminate of carbon/epoxy composite (T300/934) patches of different orientation angles at their overlap area subjected to bending moment. For this purpose, AA2024-T3 aluminum was used as adherend, while the adhesive was a two-part paste (DP 460). Six different types of joint samples were subjected to bending moment. The effect of patch material on failure load and stress distribution was examined experimentally and numerically. In the numerical analysis, the composite patches were assumed to behave linearly elastic, while adherend and adhesive layers were assumed to be nonlinear. It was found that the data obtained from 3-D finite element analysis were coherent with experimental results. Meanwhile, experiments showed that fiber orientation angles of the patches markedly affected the failure load of joints, failure mode and stress distributions appeared in adhesive and composite.

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  • MakaleYalnız künye2013Scopus SJRQ2
    Radical scavenging and antioxidant capacity of serotonin

    Sarikaya, S. Beyza Öztürk; Gülçin, Ilhami

    Serotonin is a monoamine neurotransmitter and biochemically derived from tryptophan. The present paper examines the in vitro antioxidant and radical scavenging capacity of serotonin using different in vitro methodologies. For the determination of antioxidant activity of serotonin, 1,1-diphenyl-2-picryl-hydrazyl free radical (DPPH) scavenging, 2,2́-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) radical scavenging activity, total antioxidant activity determination by ferric thiocyanate, total reducing ability determination by Fe3+-Fe2+ transformation method, superoxide anion radical scavenging by riboflavin-methionine-illuminate system, H2O2 scavenging and ferrous ions (Fe +) chelating activities of serotonin were performed. Also, butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), α-tocopherol and trolox, a water-soluble analog of α-tocopherol, were used as the reference antioxidant radical scavenger compounds. Serotonin completely inhibited lipid peroxidation of a linoleic acid emulsion at 15 μg/mL concentration. On the other hand, the above mentioned standard antioxidants displayed inhibition of 92.2, 99.6, 84.6 and 95.6% on peroxidation of linoleic acid emulsion, respectively at the 45 μg/mL concentration. In addition, serotonin was effective in DPPH· scavenging, ABTS•+ radical scavenging, superoxide anion radical scavenging, H2O2 scavenging, ferric ions (Fe3+) reducing power and metal chelating on ferrous ions (Fe+) activities. Also, those various antioxidant activities were compared to BHA, BHT α-tocopherol and trolox as references antioxidant compounds.

    • SDG 3 · Sağlık ve Kaliteli Yaşam
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  • MakaleAçık Erişim2013Scopus SJRQ3
    Solid phase extraction of Cd(ii) and pb(ii) ions by a new carbothioamide derivative

    Ozdes, Duygu; Duran, Celal; Bayrak, Hacer; Serencam, Huseyin; Basri Senturk, Hasan

    An effective, simple, low cost and accurate sorption-spectrophotometric platform for the extractions and subsequent quantifications of Cd(II) and Pb(II) ions in food and environmental samples has been described in this dissertation. The separation and preconcentration of the analyte ions were accomplished by solid phase extraction method based on the adsorption of their N-(4-methylphenyl)-2-{[(4-phenyl-5-pyridin-4-yl-4H-1,2,4-triazol-3-yl)thio] acetyl} hydrazinecarbothioamide (MFPTAHK) complex on Amberlite XAD-8 resin in a mini column. The developed method was systematically investigated in different set of experimental parameters that influence the separation and preconcentration of Cd(II) and Pb(II) ions. The precision of the method was determined by reproducibility studies and expressed as relative standard deviations (RSD %) which were less than 4% for both analyte ions. The limits of detections (LODs) for Cd(II) and Pb(II) ions based on the three times the standard deviation of the blanks (N:10) were found to be 0. 31 ?g L-1 and 0. 86 ?g L-1, respectively. The developed SPE procedure was utilized for the simultaneous extraction and determinations of Cd(II) and Pb(II) ions levels in rice, cracked wheat and red lentil as food samples and various water samples.

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  • MakaleYalnız künye2013Scopus SJRQ1
    Effects of laminate carbon/epoxy composite patches on the strength of double-strap adhesive joints: Experimental and numerical analysis

    Akpinar, Salih

    In this study, mechanical properties of double-strap joints with aluminum or composite patches of different orientation angles at their overlap area were investigated under tensile loading. For this purpose, AA2024-T3 aluminum was used as adherend, while patches were either AA2024-T3 aluminum or 16-ply laminate of carbon/epoxy composite with five different orientation angles ([0]16, [90]16, [0/90]8, [45/-45]8, [0/45/-45/90]4). A two-part paste adhesive (DP 460) was used to bond adherend and patches. Six different types of joint samples were subjected to tensile loading. The effect of patch material on failure load and stress distribution was examined experimentally and numerically. As a result, it was concluded that the data obtained from 3-D finite element analysis were coherent with experimental results and additional to that fiber orientation angles of the patches markedly affected the failure load of joints, failure mode and stress distributions appeared in adhesive and composite.

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  • MakaleYalnız künye2013Scopus SJRQ1
    Single-Laboratory Validation for the Determination of Aflatoxin B1, B2, G1, and G2 in Foods Based on Immunoaffinity Column and Liquid Chromatography with Postcolumn Derivatization and Fluorescence Detection

    Baltacı, Cemalettin; İlyasoğlu, Huri; Yüksel, Ferhat

    This study presents a method validation procedure for the determination of aflatoxin B1, B2, G1, and G2 in hazelnut, hazelnut paste, walnut, peanut, pistachio, corn, and wheat. The method consisting of clean-up with immunoaffinity column, high performance liquid chromatography with postcolumn derivatization and fluorescence detection was validated in accordance with Commission Regulation 2004/882/EC. The selectivity, linearity, decision limit, detection capability, detection and quantification limits, precision, recovery, ruggedness, and measurement uncertainty of the method were determined. The limit of detection and limit of quantification values (μg/kg) were: aflatoxin B1, 0. 02, 0. 07; aflatoxin B2, 0. 01, 0. 02; aflatoxin G1, 0. 02, 0. 07; and aflatoxin G2, 0. 01, 0. 03. The relative standard deviation values for the repeatability and within-laboratory reproducibility were below 4 and 5 %, respectively. The recovery values of the spiked samples ranged from 80 to 105 %. These results complied with minimum performance criteria established by regulation 2006/401/EC. Therefore, the procedure can be implemented for the routine analysis of aflatoxins in the studied matrices.

    • SDG 2 · Açlığa Son
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  • MakaleYalnız künye2013Scopus SJRQ4
    A new record of the genus paranemastoma redikorzev, 1936 (Opiliones: Nemastomatidae) from Turkey

    Kurt, Kemal; Erman, Ömer Köksal; Snegovaya, Nataly Yu.

    Paranemastoma kalischevskyi (Roewer, 1951) is recorded in Turkey for the first time. The morphological characteristic features, exact locality and general distribution are provided for this species.

    AtıfScopus2WoS3OpenAlex2
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  • MakaleAçık Erişim2013Scopus SJRQ1
    On numerical solution to fractional non-linear oscillatory equations

    Merdan, Mehmet; Gökdoǧan, Ahmet; Yildirim, Ahmet

    In this article, the multi-step differential transform method (MsDTM) is applied to give approximate solutions of nonlinear ordinary differential equation such as fractional-non-linear oscillatory and vibration equations. The results indicate that the method is very effective and sufficient for solving non-linear differential equations of fractional order.

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  • Kitap BölümüYalnız künye2013
    Geophysical approach for the detection and evaluation of geothermal energy potential stimulated from geology and tectonics in Cappadocia Region (Central Turkey)

    Maden, Nafiz

    Geothermal energy, which is a renewable energy source, can be used to heat buildings or generate electricity and does not contribute to air pollution when used properly, and it is heat continuously produced inside the earth that generates geological phenomena on a planetary scale. Central Anatolia is a triangular region which is limited by North Anatolian Fault Zone (NAFZ) to the north, East Anatolian Fault Zone (EAFZ) to the east, Dead sea FZ and Cyprus FZ to the south. The tectonic structure of the Cappadocia region is composed of NW trending Salt Lake Fault Zone extending approximately 220 km in length, Salanda fault zone extending 140 km, and NE trending Central Anatolian Fault zone more than 700 km in length. There are 82 geothermal regions having 171 sources with low and high temperatures due to the young volcanism and tectonic activities in this region. These geothermal regions caused by fault and fracture zones extending to the mantle parallel to the tectonic zones of the region and are situated on the areas having low Curie, high heat flow values. The Curie point depth, heat flow and geothermal gradient values determined from geophysical data of the region are correlated with tectonics and geothermal potential of the region. While the minimum crustal thickness is 38 km, the maximum crustal thickness is 41 km in Mt. Hasan and Mt. Erciyes. The Curie point depth value is computed as 13.7 km determined from magnetic anomaly data of the region. The geothermal gradient and heat flow values are estimated to be 42.3 °Ckm-1, 88.8 mWm-2, respectively. Geothermal systems and reservoir temperature of geothermal sources should be understood clearly to provide sustainability of the project with respect to the economical conditions. Various geothermometers methods have been used to determine the reservoir temperature in order to estimate the field of usage of the thermal water before the drilling stage because of the high price of the borehole. Silica geothermometers method applied to the SiO2 content of the sources gives the best information about the reservoir temperature. The maximum temperatures and depth to reservoir of the geothermal sources located in the Kayseri region are estimated as 131.8 °C, 1.14 km, respectively, in Kayseri region. It is concluded from these values that the Cappadocia region has very high geothermal potential caused by tectonic activities after the Late Triassic and partial melting of the lower crust.

  • MakaleYalnız künye2013Scopus SJRQ2
    A statistical assessment of current seismic quiescence along the North Anatolian fault zone: Earthquake precursors

    Öztürk, Serkan

    The variations of the current seismicity rate on the North Anatolian Fault Zone in the beginning of 2009 have been analyzed based on the phenomenon of precursory seismic sequence before crustal main shocks. For this purpose, a statistical assessment is made to detect the seismic quiescence situation by using the standard normal deviate Z-value. Eight seismic quiescence regions are observed and quiescence anomalies in these regions have been observed since the beginning of 2005. On the Marmara part of the North Anatolian Fault Zone, four quiescence areas have been found on Silivri, in the Black Sea, around Izmit region and Çanakkale, Saros Gulf. On the Anatolian part of the North Anatolian Fault Zone, two quiescence areas have been observed on the Düzce fault and around the city of Amasya. Other anomalies have been observed around Erzincan, Elaziǧ and Bingöl regions on the eastern part of the North Anatolian Fault Zone. Due to the occurrences of the last strong earthquakes "MW = 6.0-Elaziǧ earthquake, 2010 March 08; MW = 5.2 - Çanakkale (Saros Gulf) earthquake, 2010 November 03; MW = 5.5-Erzincan earthquake, 2011 September 22 and MW = 5.1-Marmara Ereǧlisi (Tekirdaǧ) earthquake, 2012 June 07", other seismic quiescence regions may contribute to the forecasting of impending main shocks. Spatial and temporal estimates of the future seismic hazard of the North Anatolian Fault Zone are provided based on the results.

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  • MakaleAçık Erişim2013Scopus SJRQ1
    A numeric-analytic method for time-fractional Swift-Hohenberg (S-H) equation with modified Riemann-Liouville derivative

    Merdan, Mehmet

    In this paper, the fractional variational iteration method (FVIM) was applied to obtain the approximate solutions of time-fractional Swift-Hohenberg (S-H) equation with modified Riemann-Liouville derivative. A new application of fractional variational iteration method (FVIM) was extended to derive analytical solutions in the form of a series for these equations. Numerical results showed the FVIM is powerful, reliable and effective method when applied strongly nonlinear equations with modified Riemann-Liouville derivative.

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  • MakaleYalnız künye2013Scopus SJRQ3
    Application of carrier element free coprecipitation (CEFC) method for determination of Co(II), Cu(II) and Ni(II) ions in food and water samples

    Serencam, Huseyin; Duran, Celal; Ozdes, Duygu; Bektas, Hakan

    A simple and highly sensitive separation and preconcentration procedure, which has minimal impact on the environment, has been developed. The procedure is based on the carrier element free coprecipitation (CEFC) of Co(II), Cu(II), and Ni(II) ions by using 2-{4-[2-(1H-indol-3-yl)ethyl]-3-(4-methylbenzyl)-5-oxo- 4,5-dihydro-1H-1,2,4-triazol- 1-yl}-N'-(pyridin-2-yl methylidene)acetohydrazide (IMOTPA), as an organic coprecipitant. The levels of analyte ions were determined by flame atomic absorption spectrometry (FAAS). The detection limits for Co(II), Cu(II) and Ni(II) ions were found to be 0.40, 0.16 and 0.17 μg L-1, respectively, and the relative standard deviations for the analyte ions were lower than 3.0%. Spike tests and certified reference material analyses were performed to validate the method. The method was successfully applied for the determination of Co(II), Cu(II) and Ni(II) ions levels in sea and stream water as liquid samples and red pepper, black pepper, and peppermint as solid samples.

    AtıfScopus10WoS10
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  • MakaleYalnız künye2013Scopus SJRQ2
    A multistage variational iteration method for solution of delay differential equations

    Gökdoǧan, Ahmet; Merdan, Mehmet; Ertürk, Vedat Suat

    In this paper, the approximate solution of delay differential equations is obtained by a reliable algorithm based on an adaptation of the classical variational iteration method (VIM), which is called the multi-stage variational iteration method (MSVIM). Examples are carried out and numerical results with comparison to exact solutions, VIM and MATLAB dde23 solver are given. The comparison reveals that the MSVIM is a promising tool to solve delay differential equations.

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  • MakaleYalnız künye2013Scopus SJRQ1
    The effect of the spew fillet on an adhesively bonded single-lap joint subjected to bending moment

    Akpinar, Salih; Doru, Muhammet Onur; Özel, Adnan; Aydin, Murat Demir; Jahanpasand, Hamed Ghaffarzadeh

    The mechanical behaviors of an adhesively bonded single lap joint with a spew fillet under bending moment, where the widths of the upper-adherend and lower-adherend are not the same, were studied experimentally and numerically. Using AA2024-T3 aluminum alloy as adherend and DP460 as paste adhesive, four different types of single-lap joint samples (without spew fillet, with spew fillet at joint edges, with spew fillet at joint ends and with spew fillet at all edges) were produced for experimental studies. Stress analyses in the single-lap joint were performed with a three dimensional non-linear finite element method by considering the geometrical non-linearity and non-linear material behaviors of both adhesives (DP460) and adherend (AA2024-T3). The single lap joint with the spew fillet with different widths had a significant effect on the stress distribution. Additionally, the spew fillet increased the load carrying capacity of the joint and decreased the stress concentration of the joint.

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  • MakaleYalnız künye2013Scopus SJRQ2
    Organic geochemical characteristics and depositional environments of the eocene deposits in the eastern black sea region, NE Turkey

    Eker, C.S.

    Type of organic material, thermal maturity, depositional environment, and source rock potential of Eocene aged clastic rocks of the Eastern Black Sea Region were investigated. Based on total organic carbon values, clastic rocks range from weak-good source rock. Samples contain a mixture of Type I-Type III kerogen. Based on T max values, Eocene aged clastic rocks were thermally mature. Moretane/hopane ratio of samples <0.15, 22S/(22S + 22R) homohopane (C32), and 20S/(20S + 20R) sterane (C29) maturity parameters were equal or very close to equilibrium value of oil generation. The deposition environment was transitional marine environment and clastic rocks do not have the potential to form hydrocarbon.

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  • MakaleYalnız künye2013Scopus SJRQ2
    Separation and pre-concentration of palladium(II) from environmental and industrial samples by formation of a derivative of 1,2,4-triazole complex on Amberlite XAD-2010 resin

    Serencam, Huseyin; Bulut, Volkan Numan; Tufekci, Mehmet; Gundogdu, Ali; Duran, Celal; Hamza, Sibel; Soylak, Mustafa

    A simple separation/pre-concentration method was developed for extraction of Pd(II) in various environmental samples, based on its adsorption of 4-phenyl-5-{[(4-phenyl-5-pyridin-4-yl-4H-1,2,4-triazole-3-yl)thio]methyl}-4H-1,2,4-triazole-3-thyol (PPTTMET) complex on Amberlite XAD-2010 resin in a mini column. The ligand has high affinity for Pd(II) among many other metals that are taken into consideration. The flame atomic absorption spectrometry is employed to determine the concentration of Pd(II). The optimum working conditions which were determined are as follows: 0.05 mol L-1 HNO3 as working medium, 1.0 mol L-1 HCI in acetone as elution solvent, 0.75 mg of PPTTMET amount and 750 mL of sample volume. The system was independent from the flow rates between 3.1 and 23.1 mL min-1. The Pd(II) adsorption capacity of Amberlite XAD-2010 resin was found to be 12.8 mg g-1 and the enrichment factor was calculated as 375. The method was successfully applied for the determination of Pd(II) in motorway dust samples, anodic sludge, gold ore, industrial electronic waste materials and various water samples.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
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  • MakaleYalnız künye2013Scopus SJRQ2
    Biosorption properties of Morus alba L. for Cd (II) ions removal from aqueous solutions

    Serencam, Huseyin; Ozdes, Duygu; Duran, Celal; Tufekci, Mehmet

    The abundantly available industrial waste product Morus alba L. pomace (MAP) is one of the cost-effective biosorbent for removal of metal ions from aqueous solutions. Hence, in the present study, we aimed to test the ability of MAP to remove Cd(II) ions through batch biosorption process. Firstly, MAP was characterized using several techniques, and then the influence of various experimental parameters such as initial pH of the aqueous solution, initial Cd(II) concentration, contact time, MAP concentration, and temperature were evaluated upon the biosorption process. It was found that the maximum uptake of Cd(II) ions occurred at initial pH 6.0 and optimum contact time was observed as 60 min. Cd(II) ions adsorption on MAP analyzed by the Langmuir and Freundlich isotherm models and the maximum monolayer biosorption capacity of MAP was found to be 21.69 mg g-1 by using the Langmuir isotherm model. The pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion models were employed to describe the biosorption kinetics. In order to investigate the thermodynamic properties of the biosorption process, the changes in the Gibbs free energy (â̂†G), enthalpy (â̂†H), and entropy (â̂†S) were also evaluated and it has been concluded that the process was feasible, spontaneous, and endothermic in the temperature range of 5-40 C.

    • SDG 6 · Temiz Su ve Sanitasyon
    • SDG 12 · Sorumlu Üretim ve Tüketim
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  • MakaleYalnız künye2013Scopus SJRQ3
    The effect of water stress on spikelet position weight variation in wheat

    Yildirim, Mustafa

    This study was conducted in Eskisehir during the 2004-05 and 2005-06 growing seasons, and aimed to evaluate the response of six bread wheat varieties to rainfed and irrigated conditions in terms of grain yield, heading date, plant height and position weight variation (PWV). Of the six varieties tested, three (Sultan, Yildiz, Bezostaja) are drought-sensitive cultivars and three (Gerek, Altay, Sonmez) are drought-tolerant cultivars. Spikes from each variety were divided into five spikelet groups in order to study the effect of spikelet position upon grain weight (S1, S2, S3, S4 and S5, with S1 the spikelet closest to the base). This study focused on position weight variation (PWV) in order to better understand how 1000-kernel weight is affected by spikelet position under both rainfed and irrigated conditions and thus gains a better understanding of wheat resistance to drought. Linear increases in grain yield, heading date and plant height were observed in response to irrigated conditions, whereas a linear increase in PWV was observed in response to rainfed conditions for both seasons. Grain yield was negatively associated with heading date (r=-0.746). PWV was positively associated with grain yield and negatively associated with heading date (p<0.01; r=0.804 and r=-0.860, respectively). The observed differences in grain weight between spikelet positions have important implications for drought tolerance in wheat and can be used as a new parameter for predicting drought tolerance.

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  • MakaleYalnız künye2013Scopus SJRQ1
    Petrogenesis of the post-collisional volcanic rocks from the Borçka (Artvin) area: Implications for the evolution of the Eocene magmatism in the Eastern Pontides (NE Turkey)

    Aydinçakir, Emre; Sen, Cüneyt

    Whole-rock geochemistry, 40Ar-39Ar data, and Sr-Nd isotopes are presented for the Eocene Borçka volcanic rocks on the eastern corner of the eastern Pontide orogenic belt (NE Turkey). Borçka (Artvin) volcanic rocks are divided into three suites-basic dyke, Borçka basalt, and Civanköy suite. These rocks contain plagioclase (An49-88), clinopyroxene (Wo38-49En38-54Fs8-25), hornblende (Mg#=0.57-0.74) phenocrysts, and magnetite/titanomagnetite and apatite microphenocrysts. 40Ar-39Ar ages on hornblendes, ranging from 46.9±0.1 to 39.9±0.5Ma, within the middle Eocene. The volcanic rocks show tholeiitic-calc-alkaline affinities and have low-to-medium K contents. They are enriched in large ion lithophile (LILE) and light rare earth elements (LREE), with pronounced depleted high field strength elements (HFSE). The chondrite-normalized REE patterns (Lacn/Lucn=1-19) show low-to-medium enrichment, indicating similar sources for the rock suite. Initial 87Sr/86Sr values [(87Sr/86Sr)46Ma] vary between 0.70423 and 0.70495, while initial 143Nd/144Nd values [(143Nd/144Nd)46Ma] lie between 0.51263 and 0.51285. The main solidification processes involved in the evolution of the volcanics consist of fractional crystallization, with minor amounts of crustal contamination. All our evidences support the conclusion that the parental magma of the rocks probably derived from an enriched mantle, previously metasomatized by fluids derived from subducted slab, in a post-collisional, extension-related geodynamic setting.

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