Sürdürülebilir Kalkınma Amaçları
Yazarlar
- Uzun, Sevda(62)
- Merdan, Mehmet(58)
- Duran, Celal(50)
- Ozdes, Duygu(47)
- Kaygusuz, Abdullah(43)
- Ashyralyyev, Charyyar(38)
- Karsli, Orhan(33)
- Öztürk, Serkan(32)
- Araz, Onur(31)
- Demir, Selim(29)
- Kulakaç, Nurşen(29)
- Dokuz, Abdurrahman(28)
- Arslan, Mehmet(27)
- Baltacı, Cemalettin(27)
- Maden, Nafiz(27)
- Sipahi, Ferkan(27)
- Topal, Fevzi(27)
- Turan, Ibrahim(27)
- Kandemir, Raif(25)
- Kurt, Kemal(24)
- Ozturk, Samet(24)
- Peker, Iskender(24)
- Vural, Alaaddin(24)
- Reis, Hatice Catal(23)
- Yücel, Cem(23)
- Aydin, Faruk(22)
- Baltaci, Cemalettin(22)
- Gücer, Mehmet Ali(22)
- Günen, Mehmet Akif(22)
- Kankal, Murat(22)
- Topal, Meryem(22)
- Karimullah, Suud Sarim(21)
- Uysal, Ibrahim(20)
- Kurnaz, Muammer(19)
- Tuncer, Metin(19)
- Yolcu, Halil(19)
- Çelik, Necati(19)
- Ürkek, Bayram(19)
- Şan, Murat(19)
- Aliyazicioglu, Yuksel(18)
Yayınlar
- MakaleAçık Erişim2014Scopus SJRQ1The effect of cooking on total polyphenolic content and antioxidant activity of selected vegetables
Şengül, Memnune; Yildiz, Hilal; Kavaz, Arzu
The aim of this study to investigate the effect of different cooking methods (boiling, steaming, stir-frying, and microwaving) on the total polyphenolic content and total antioxidant activity of selected vegetables (beet, red cabbage, broccoli, white cabbage, black radish, kale, turnip, and red radish) from Turkey. A wide variation on total phenolic content was observed in raw vegetables, ranging from 44.94 ± 0.47 (beet, Beta vulgaris L. subsp. vulgaris) to 350.94 ± 5.18 (red radish, Raphanus sativus L.) μg gallic acid equivalent/mg of sample. Considering uncooked vegetables, the order of total antioxidant activity determined by β-carotene bleaching assay was beet > red cabbage > broccoli > white cabbage > black radish > kale > turnip > red radish. In DPPH• assay, kale had an exceptionally high antioxidant activity followed by red cabbage, broccoli, turnip, black radish, beet, white cabbage, and red radish.
AtıfScopus58WoS50OpenAlex66
İncele - EditoryalYalnız künye2014Preface
Christiansen, Bryan; Yildiz, Salih; Yildiz, Emel
AtıfScopus4İncele - MakaleAçık Erişim2014Scopus SJRQ2Kinetics, thermodynamics, and equilibrium evaluation of adsorptive removal of methylene blue onto natural illitic clay mineral
Ozdes, Duygu; Duran, Celal; Senturk, Hasan Basri; Avan, Hilal; Bicer, Burcin
The natural illitic clay mineral (NICM) has been used as a low cost and highly effective adsorbent in the removal of a toxic cationic dye, methylene blue (MB), from aqueous solution by a batch adsorption technique. The effects of experimental parameters such as initial pH of the aqueous solution, contact time, initial MB concentration, adsorbent concentration, ionic strength, and temperature were studied in detail upon the adsorption process. The process was found to be independent of initial solution pH and the adequate equilibrium time for the adsorption of MB onto NICM was only 60 m. The experimental data were analyzed by the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models and showed a good fit with both the Langmuir and Freundlich isotherm models. The monolayer adsorption capacity of NICM was found to be 24.87 mg g-1 by using Langmuir isotherm model. The kinetics of the adsorption were tested using pseudo-first-order, pseudo-second-order, and intraparticle diffusion models. The results showed that the adsorption of MB onto NICM proceeds according to the pseudo-second-order model. Thermodynamic parameters indicated that the present adsorption process was feasible, spontaneous, and endothermic in nature.
AtıfScopus45WoS39OpenAlex51İncele - MakaleYalnız künye2014Scopus SJRQ1Synthesis of cyclohexane derivatives including Br, Cl, N, O, and S at 1,2,4,5-positions: Selectivity in addition reactions Dedicated to Professor Dr. Metin Balci on the occasion of his 65th anniversary
Kaya, Afşin Ahmet; Menzek, Abdullah; Şahin, Ertan
Brominations of mono addition products of 1,4-cyclohexadiene with 2,4-dinitrobenzenesulfenyl chloride (RSCl) selectively gave 1R(S),2R(S),4R(S), 5R(S)-4,5-dibromo-2-(2,4-dinitrophenylthio)cyclohexyl acetate and 1R(S),2R(S),4R(S),5R(S)-4,5-dibromo-2-chlorocyclohexyl)(2,4-dinitrophenylthio) sulfane. From series reactions 7-oxabicyclo[4.1.0]hept-3-ene with reagents, such as RSCl, NaN3, and H2SO4/Ac2O, six 1,2,4,5-tetrasubstituted cyclohexane derivatives including S, O, N, Cl, and Br were selectively obtained. Formations and structures of the products were discussed.
AtıfScopus6WoS5OpenAlex10İncele - MakaleYayıncıda açık erişim2014Scopus SJRQ1Characterization of rosehip (Rosa canina L.) seed and seed oil
Ilyasoǧlu, Huri
In this study, the nutritional composition and phytochemical composition of the rosehip seed, and the fatty acid and sterol compositions of the seed oil were investigated. The rosehip seed contained valuable phytochemicals such as phenolic compounds (2554 μg/g), carotenoids (2.92 μg/g), and ascorbic acid (1798 μg/g). Furthermore, the rosehip-seed oil was rich in polyunsaturated fatty acids, linoleic acid (54.05%), linolenic acid (19.37%), and phytosterols, mainly β-sitosterol (82.1%). The rosehip seed and seed oil were found to have antioxidant activity measured by trolox equivalent antioxidant capacity assay. It can be concluded that the rosehip seed and seed oil may be utilized as a source of phytonutrients.
AtıfScopus106WoS96OpenAlex111İncele - Derleme MakaleYalnız künye2014Scopus SJRQ1Mineral chemistry and thermobarometry of Eocene monzogabbroic stocks from the Bafra (Samsun) area in Turkey: Implications for disequilibrium crystallization and emplacement conditions
Temizel, İrfan; Arslan, Mehmet; Abdioğlu, Emel; Yücel, Cem
Monzogabbro stocks including felsic enclaves (monzosyenite) around the Bafra (Samsun) area at the western edge of the Eastern Pontides cut Eocene-aged volcanic and sedimentary units. The monzogabbros contain plagioclase, alkali feldspar, clinopyroxene, olivine, hornblende, biotite, apatite, and iron-titanium oxides, whereas the felsic enclaves contain alkali feldspar, plagioclase, hornblende, biotite, clinopyroxene, and iron-titanium oxides. Mineral chemistry data suggest that magmas experienced hydrous and anhydrous crystallization in deep and shallow crustal magma chambers. Several thermobarometers were used to estimate temperatures of crystallization and emplacement for the mafic and felsic magmas. Clinopyroxene thermobarometry yielded 1100-1232 C and 5.9-8.1 kbar for monzogabbros, and 931-1109 C and 1.8-6.9 kbar for felsic enclaves. Hornblende thermobarometry and oxygen fugacity estimates reveal 739-971°C, 7.0-9.2 kbar and 10−9.71 for monzogabbros and 681-928°C, 3.0-6.1 kbar and 10−11.34 for felsic enclaves. Biotite thermobarometry shows elevated oxygen fugacity varying from 10−18.9-10−11.07 at 632-904°C and 1.29-1.89 kbar for monzogabbros, to 10−15.99 -10−11.82 at 719-873°C and 1.41-1.77 kbar for felsic enclaves. The estimated zircon and apatite saturation temperatures are 504-590°C and 693-730°C for monzogabbros and 765-775°C and 641-690°C for felsic enclaves, respectively. These data imply that several phases in the gabbroic and syenitic magmas did not necessarily crystallize simultaneously and further indicate that the mineral compositions may register intervals of disequilibrium crystallization. Besides, thermobarometry contrasts between monzogabbro and felsic enclave may be partly a consequence of extended interactions between the mafic and felsic magmas by mixing/mingling and diffusion. Additionally, the hot felsic magma was close to liquidus conditions (crystallinity < 30%) when injected into cooler mafic magma (crystallinity > 50%), and thus, the monzogabbro stocks reflect hybrid products from the mingling and incomplete mixing of these two magmas.
AtıfScopus32WoS29OpenAlex30İncele - MakaleYalnız künye2014Scopus SJRQ2Preparation and characterization of biodegradable rigid polyurethane foams from the liquefied eucalyptus and pine woods
Ertaş, Murat; Fidan, M. Said; Alma, Mehmet Hakki
In this study, eucalyptus (Eucalyptus camaldulensis L.) and pine (Pinus sylvestris L.) woods were liquefied using the the blended solvents mixture of polyethylene glycol PEG-400/glycerin in the presence of sulfuric acid as a catalyst at 140-160°C for 120 min. The insoluble parts in the liquefied eucalyptus and pine were found as 17.8 and 5.5 wt. %, respectively. The acid and hydroxyl numbers of the liquefied eucalyptus and pine were determined and compared with each other. Polyurethane-type rigid foams (RPUFs) were successfully prepared by a co-polymerization of the liquefied woods (LWs) and polymeric methylene diphenylene diisocyanate (PMDI). The compressive strength (120 to 250 kPa), the modulus of elasticity (1 to 6 MPa), the density (20 to 50 kg.nr-3) and thermal conductivity (0.0352 to 0.0374 W.mK -1) of the RPUFs prepared from the LWs were found to be almost comparable to those of the synthetic foams. Furthermore, the biodegradability of the biomass-based foams was higher than that of the synthetic ones.
AtıfScopus36WoS30İncele - MakaleYalnız künye2014Scopus SJRQ3The effect of Saccharomyces cerevisiae on milk yield, milk compositions and body condition score raised organically in dairy cows
Bayram, Bahri; Aksakal, Vecihi; Karaalp, Musa; Mazlum, Halit
The objective of this study was to evaluate the effect of Saccharomyces cerevisiae (SC) on milk yield, milk compositions and the body condition score raised organically in dairy cattle. For this aim, 120 lactating Holstein Friesian dairy cows were randomly divided into group control (n = 60) and treatment (n = 60) in a private organic dairy farming in the Kelkit District of the Gumushane Province in Turkey. The diet of group treatment each cow was supplementation with 6 g SC per day. The experimental was started after 30 days of calving and lasted 45 days after. The average daily milk yield production (p<0.01) was higher in the SC group (34.6±0.31 vs. 31.8±0.44kg day-1 in the treated and control group, respectively). The effect of SC on some milk compositions as non-fat solids (%), milk fat (%), protein (%) and lactose were statistically non-significant. Body condition score in the treated group (2.74±0.016) was higher than control group (2.58±0.017) (p<0.01). It was concluded that milk yield capacities in organic dairy cattle farming in case that the similar results are confirmed with additional studies can be substantially increased.
AtıfScopus1OpenAlex1İncele - MakaleYalnız künye2014Scopus SJRQ1Attitudes towards HIV/AIDS patients and empathic tendencies: A study of Turkish undergraduate nursing students
Özakgül, Aylin Aktaş; Şendir, Merdiye; Atav, A. Serdar; Kiziltan, Belkiz
Background: Studies indicate that the attitudes of nurses, nursing students, and other health care professionals towards Human Immunodeficiency Virus (HIV) and Acquired Immune Deficiency Syndrome (AIDS) patients are affected by cultural differences and the fear of HIV/AIDS infection, resulting in both negative attitudes and reluctance to care for these patients. Empathy is critical for all health professionals in the delivery of effective care. Research indicates that as empathic tendencies develop, so do better communication skills, better attitudes, and better quality of care. Objectives: The purpose of this study was to examine the relationships among demographic factors, familiarity with HIV/AIDS, attitudes towards HIV/AIDS, and empathic tendencies in a Turkish sample of nursing students. Design and Methods: Using a non-experimental, correlational design, data on demographics, HIV/AIDS Attitude Scale (AAS) and the Scale of Empathic Tendency (SET) were collected. Participants: The study sample consisted of 614 undergraduate nursing students in two universities located in different geographic regions of Turkey. Results: The results of this study indicated that attitudes and empathic tendencies are related to knowledge and exposure to patients. As well, those students with more positive attitudes had higher empathic tendencies towards HIV/AIDS patients. Conclusions: It is important to adopt strategies to improve the empathic tendencies and attitudes of nursing students. These strategic changes would increase the quality of care provided to all patients.
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İncele - MakaleYalnız künye2014Scopus SJRQ2Effects of lichen extracts on haematological parameters of rats with experimental insulin-dependent diabetes mellitus
Çolak, Suat; Geyikoğlu, Fatime; Aslan, Ali; Deniz, Gülşah Yıldız
The prevalence of diabetes mellitus in the world is steadily increasing. Oxidative stress contributes to the development of diabetic complications, including diabetic haematological changes. Lichens are used as food supplements and are also used as possible natural antioxidant, antimicrobial and anticancer agents. We hypothesized that antioxidant activity of lichens may decrease hyperglycaemia-induced oxidative stress and prevent the development of diabetic complications, including abnormality in haematological condition. Therefore, the effects of Cetraria islandica water extract (CIWE) and Pseudevernia furfuracea water extract (PFWE) on the haematological parameters of rats with type 1 DM were investigated for the first time in the present study. Control Sprague-Dawley or streptozotocin (STZ)-induced diabetic rats were either untreated or treated with water lichen extracts (5–500 mg/kg body weight (bw)/day) for 2 weeks, starting at 72 h after STZ injection. On day 14, animals were anaesthetized and haematological and metabolic parameters were determined between control and experimental groups. In addition, the total oxidative stress (TOS), a specific indicator of oxidative stress, and the total antioxidant capacity (TAC) were measured by biochemical studies. In diabetic rats, CIWE of 250–500 mg/kg bw dose showed more prominent results when compared with doses of PFWE for TAC. The results obtained in the present study suggested that the antioxidant activities of lichens might be the possible reason behind the observed antihaematological status. However, the protective effect of lichen extracts were inadequate on diabetes-induced microcytic hypochromic anaemia. In addition, the extracts have no effect on metabolic complications. Our experimental data showed that high doses of CIWE and PFWE alone have no detrimental effect on blood cells and TOS status of plasma. Hence, they are safe and suitable for different administration routes.
AtıfScopus18WoS12OpenAlex23İncele - MakaleAçık Erişim2014Scopus SJRQ1Physicochemical, bioactive, and sensory properties of persimmon-based ice cream: Technique for order preference by similarity to ideal solution to determine optimum concentration
Karaman, Safa; Toker, Ömer Said; Yüksel, Ferhat; Çam, Mustafa; Kayacier, Ahmed; Dogan, Mahmut
In the present study, persimmon puree was incorporated into the ice cream mix at different concentrations (8, 16, 24, 32, and 40%) and some physicochemical (dry matter, ash, protein, pH, sugar, fat, mineral, color, and viscosity), textural (hardness, stickiness, and work of penetration), bioactive (antiradical activity and total phenolic content), and sensory properties of samples were investigated. The technique for order preference by similarity to ideal solution approach was used for the determination of optimum persimmon puree concentration based on the sensory and bioactive characteristics of final products. Increase in persimmon puree resulted in a decrease in the dry matter, ash, fat, protein contents, and viscosity of ice cream mix. Glucose, fructose, sucrose, and lactose were determined to be major sugars in the ice cream samples including persimmon and increase in persimmon puree concentration increased the fructose and glucose content. Better melting properties and textural characteristics were observed for the samples with the addition of persimmon. Magnesium, K, and Ca were determined to be major minerals in the samples and only K concentration increased with the increase in persimmon content. Bioactive properties of ice cream samples improved and, in general, acetone-water extracts showed higher bioactivity compared with ones obtained using methanol-water extracts. The technique for order preference by similarity to ideal solution approach showed that the most preferred sample was the ice cream containing 24% persimmon puree.
AtıfScopus123WoS109OpenAlex168İncele - MakaleYalnız künye2014Scopus SJRQ3Geochemistry of dacitic volcanics in the Eastern Pontides (NE Turkey)
Sipahi, Ferkan; Sadıklar, M.Burhan
Dacitic rocks that crop out around the Zigana Mountain (Gümüşhane) in the eastern Pontide (NE Turkey), are mainly composed of quartz, plagioclase, sanidine, amphibole, muscovite, and biotite as the main minerals. Zircon and rutile are the accessory minerals. Pyrite, chalcopyrite, and covellite are the opaque components. On the basis of trace-element data, dacites have been classified as Dacite-I and Dacite-II. Dacite-I is tholeitic-transitional, whereas Dacite-II is transitional-calc-alkaline. The geochemical variation can be explained by the fractionation of the common mineral phases, such as plagioclase, hornblende, magnetite, and apatite. Dacites also show island-arc properties, with negative Nb, Sr, P, and Ti anomalies. The trace-element distrubitions of the dacitic rocks reflect the typical characteristics of rocks from the subduction-related tectonic setting, with enrichment of large-ion lithofile elements and light rare-earth element, but depletion in high-field-strength elements. The dacitic rocks are developed through plagioclase ± hornblende-controlled fractionation from the same parental magma that settled in two successive stages and are derived from an enriched source, probably by the mixing of slab-derived and lithospheric melts.
AtıfScopus18WoS15İncele - MakaleYalnız künye2014Scopus SJRQ1Separation and preconcentration of lead, chromium and copper by using with the combination coprecipitation-flame atomic absorption spectrometric determination
Bahadır, Zekeriyya; Bulut, Volkan Numan; Ozdes, Duygu; Duran, Celal; Bektas, Hakan; Soylak, Mustafa
A coprecipitation method was developed for the quantitative separation and preconcentration of Pb(II), Cr(III) and Cu(II) ions. Analytes were coprecipitated using a triazole derivative (2-{4-[2-(1H-indol-3-yl)ethyl]-3-(4-chlorobenzyl)-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl}. N-aryl methylidene acetohydrazid). The analytes were analyzed by flame atomic absorption spectrometry. The parameters such as sample pH, amount of reagent, sample volume, matrix effects etc. were investigated. The enrichment factor for the analyzed metal ions was obtained as 50. The relative standard deviations (RSD) were in the range of 2.8-4.1%. The accuracy of the proposed procedure was checked by the analysis of the CRM-C-Sandy Soil C. The method was successfully applied to real samples.
AtıfScopus73WoS66OpenAlex65İncele - MakaleYalnız künye2014Scopus SJRQ1Attitudes Toward Ethically Questionable Negotiation Tactics: A Two-Country Study
Banai, Moshe; Stefanidis, Abraham; Shetach, Ana; Özbek, Mehmet Ferhat
Current research has identified five discrete US negotiation tactics, a traditional one considered to be ethical, and four considered to be ethically questionable. Scholars have independently used culture to explain how the endorsement of these five negotiation tactics varies across nations. They have also independently used interpersonal trust and ethics propensity to explain antecedents of the endorsement of those five negotiation tactics. This research combines all those variables into one model that investigates the influence of horizontal and vertical individualism–collectivism, ethical idealism, and trust propensity on employees’ attitudes toward ethically questionable negotiation tactics in Israel and Kyrgyzstan. A survey questionnaire was translated from English to Hebrew and Kyrgyz, and 615 responses were collected from employees in various industries in the two countries. We empirically confirmed three types of questionable negotiation tactics discovered in previous one-nation studies, namely, pretending, deceiving, and lying. Vertical individualism was found to be positively, and horizontal collectivism was found to be negatively, related to pretending, deceiving, and lying. Ethical idealism was found to be negatively related to the endorsement of the lying tactics, while trust propensity was negatively related to the pretending tactics. Compared with Israel, employees’ endorsement of ethically questionable negotiation tactics was significantly higher in Kyrgyzstan. Contribution to theory and practice is discussed.
AtıfScopus21WoS18OpenAlex23İncele - MakaleYayıncıda açık erişim2014Scopus SJRQ3Effect of rootstock on grafted grapevine quality
Köse, B.; Karabulut, B.; Ceylan, K.
As the home of numerous grape genotypes, Turkey is one of the major centers of viniculture genetic material in the world. 'Merzifon Karasi' (Vitis vinifera L.) is one of the most valuable red wine grape cultivars in Turkey. However, despite the variety's relative age, 'Merzifon Karasi' has yet to be tested on different rootstocks. Therefore, this study was conducted to determine the effects of different rootstocks on the growth characteristics of 'Merzifon Karasi' scion. Growth parameters (shoot length (cm), shoot diameter (mm), internode length (cm), total and unit leaf area (cm2), root length (cm), root scale (0-4) and root number) were calculated and carbohydrate content (%) of the grafted grapevine shoots, trunk and roots analysed for 9 different rootstocks. Significant differences (P < 0.01) were found among rootstocks. 8B and Rupestris du Lot rated best in terms of root length, root scale and root number (P < 0.01). Highest shoot length, shoot diameter (P < 0.01) and internode length were obtained, respectively, with the 110R, 8B and Rupestris du Lot rootstocks (P < 0.05). Rupestris du Lot also produced the grapevines with the highest total leaf area per plant and main shoot, whereas the grapevines grafted on 8B had the highest unit leaf area (P < 0.01). Sugar, starch and carbohydrate contents (%) of the different plant parts also varied significantly by rootstock (P < 0.01), with the highest root carbohydrate content measured in the 5C (22.4 %) rootstock, and the highest trunk and shoot carbohydrate content measured in the 110R (12.1 and 13.4 %, respectively). In sum, the study found the best rootstocks for 'Merzifon Karasi' to be 8B, Rupestris du Lot and 110R in terms of root and shoot growth, whereas 'Merzifon Karasi' grape grafted onto 110R and 5C rootstock had the highest carbohydrate contents.
AtıfScopus23WoS24İncele - MakaleYalnız künye2014Scopus SJRQ1Prediction of wave parameters by using fuzzy inference system and the parametric models along the south coasts of the Black Sea
Akpinar, Adem; Özger, Mehmet; Kömürcü, Murat Ihsan
Forecasting of sea-state characteristics has a great importance in coastal and ocean engineering studies. Therefore, the purpose of this study was to investigate performances of Adaptive-Network-Based Fuzzy Inference System (ANFIS) and several parametric methods in the Black Sea. For this purpose, different fuzzy models with different input combinations were developed for two different wind data sources (TSMS and ECMWF) at two offshore buoy stations. It also aimed to apply several approaches to event-based data sets for wave predictions. Generally, in literature the tendency is to use time series data for wave predictions. In this kind of prediction approach, lagged time series data are taken as inputs and current or future variables are taken as output. In this study, event-based data for each independent storm were extracted from time series data. Simultaneous or concurrent data of wind speed, blowing duration, fetch length and wave characteristics were detected for each single storm. These event data were then used to set up models. The hindcast results were validated with significant wave height and mean wave period data recorded in Hopa and Sinop buoy stations. The performance of developed fuzzy models were also compared with that of four different parametric methods (Wilson, SPM, Jonswap, and CEM methods) applied for two wind data sources at both buoy stations. Finally, it was determined that in the prediction of both wave parameters (H s and T z) the ANFIS models (R = 0.66, squared correlation coefficient, and MAE = 0.37 m, mean absolute error, for the best model in prediction of H s) were more accurate than the parametric methods (R = 0.63 and MAE = 0.75 m for the best model in prediction of H s).
AtıfScopus31WoS27OpenAlex30İncele - MakaleYalnız künye2014Scopus SJRQ1Simultaneous separation and preconcentration of Ni(II) and Cu(II) ions by coprecipitation without any carrier element in some food and water samples
Duran, Celal; Tumay, Sureyya O.; Ozdes, Duygu; Serencam, Huseyin; Bektas, Hakan
A simple and highly sensitive separation and preconcentration procedure, which has minimal impact on the environment, has been developed. The procedure is based on the carrier element-free coprecipitation of Ni(II) and Cu(II) ions by using 2-{4-[2-(1H-Indol-3-yl)ethyl]-3-(4-chlorobenzyl)-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl}-N′-(pyrrol-2-ylmethyliden)acetohydrazide (ICOTPA), as an organic coprecipitant. The levels of analyte ions were determined by flame atomic absorption spectrometry. The detection limits for Ni(II) and Cu(II) ions were found to be 0.27 and 0.58 μg L-1, respectively, and the relative standard deviations for the analyte ions were lower than 4.0%. Spike tests and certified reference material analyses were performed to validate the method. The method was successfully applied for the determination of Ni(II) and Cu(II) ions levels in sea and stream water as liquid samples and red lentil and rice as solid samples.
AtıfScopus26WoS23OpenAlex25İncele - MakaleYalnız künye2014Scopus SJRQ1Geochemical fingerprints of Late Triassic calc-alkaline lamprophyres from the Eastern Pontides, NE Turkey: A key to understanding lamprophyre formation in a subduction-related environment
Karsli, Orhan; Dokuz, Abdurrahman; Kaliwoda, Melanie; Uysal, Ibrahim; Aydin, Faruk; Kandemir, Raif; Fehr, Karl-Thomas
The Eastern Pontides in NE Turkey is one of the major orogenic belts in Anatolia. In this paper, we report our new 40Ar/39Ar dating, mineral chemistry, major and trace elements and Sr-Nd-Pb isotopic analyses of the lamprophyre intrusions in this region. The lamprophyres are widely scattered and intrude Late Carboniferous granitoid rocks. The lamprophyres exhibit fine-grained textures and are mineralogically uniform. Hornblende 40Ar/39Ar dating yielded a plateau age of 216.01±10.64Ma. Based on their geochemistry, mineral compositions and paragenesis, the lamprophyres are classified as calc-alkaline lamprophyres in general and spessartites in particular, which are rich in large ion lithophile elements (e.g., Rb, Ba, K) but depleted in Nb and Ti. Our samples exhibit moderate fractionation in LREE patterns approximately 100 times that of chondrite but HREE abundances less than 10 times that of chondrite. These calc-alkaline lamprophyres display a range of ISr (216Ma) values from 0.70619 to 0.71291 and εNd (216Ma) values from -1.4 to 4.1, with TDM=1.11 to 2.20Ga. Their Pb isotopic ratios indicate an enriched mantle source. The enrichment process is related to metasomatism of a subcontinental lithospheric mantle source, which is caused by a large quantity of H2O-rich fluids, rather than sediments released from oceanic crust at depth during the closure of the Paleotethys Ocean in Triassic times. All of the geochemical data and the trace element modeling suggest that the primary magma of the calc-alkaline to high-K calc-alkaline spessartites was generated at depth by a low degree of partial melting (~1-10%) of a previously enriched lithospheric mantle wedge consisting of phlogopite-bearing spinel peridotite. The ascendance of a hot asthenosphere triggered by extensional events caused partial melting of mantle material. The rising melts were accompanied by fractional crystallization and crustal contamination en route to the surface. All of the geochemical features combined with regional data suggest that the Eastern Pontides calc-alkaline lamprophyres originated in an extensional environment along an active continental margin throughout the Late Triassic. Such an extensional event, causing upwelling of hot asthenosphere, led to the opening of the northern branch of the Neotethys as a back-arc basin farther south of the Eastern Pontides.
AtıfScopus81WoS79OpenAlex89İncele - MakaleYalnız künye2014Scopus SJRQ4Origin of analcimes in the Tertiary volcanic rocks from the Eastern Pontides (NE Turkey): A textural, mineralogical and geochemical approach
Yücel, Cem; Temizel, Irfan; Abdioʇlu, Emel; Arslan, Mehmet; Yaʇcioʇlu, Ufuk Celal
Silica-undersaturated mafic volcanic rocks of Tertiary age in form of lava flows, dikes and sills of tephritic compositions extend along the northern part of the Eastern Pontides. These rocks typically contain Ca-clinopyroxene (Wo32-53En26-54Fs8-24), analcime, Fe-Ti oxides, apatite and minor olivine, plagioclase (An49 - 94), K-feldspar (Or29 - 66), hornblende and phlogopite in microgranular porphyritic, hyalo-microlitic porphyritic and glomeroporphyritic textures. Petrochemical features of the studied rocks, such as enrichment in LILE, depletion in Nb, Ta and Ti and moderate or high LREE/HREE ratios, provide strong evidence for melt production from a subduction-metasomatized lithospheric mantle. Besides, the rocks are characterized by their low K2O contents and low K2O/Na2O ratios as a result of analcimization. Analcime detected in these rocks appears to have formed by pseudomorphic mineral replacement reactions. Euhedral or anhedral analcime crystals, 100 - 600 um in diameter, are set in groundmass and display six-sided polygon or rounded shape and irregular cracks. The analcime pseudomorphs are colourless, milky white to grey and occur in clinopyroxene or in the groundmass. Based on the electron microprobe results, analcimes contain a minor amount of cations other than Na and probably represent the remnants of leucite as marked by K-zoning. X-ray diffraction studies of the analcime-bearing samples confirm the presence of cubic and tetragonal analcime crystals in addition to tetragonal leucite. The presence of Ca-clinopyroxene and plagioclase rather than their sodic equivalents, presence of anhydrous mineral phases and lack of Na differentiation trend as well as partial alteration of the rocks likely supports the secondary growth of analcime either during cooling or after magma solidification.
AtıfScopus16WoS17OpenAlex17İncele - MakaleYalnız künye2014Scopus SJRQ3New desmid records of Karagöl Lake in Karagöl-Sahara National Park (Şavşat-Artvin/Turkey); [Karagöl-Sahara Milli Parki{dotless}'ndaki (Şavşat-Artvin/Türkiye) karagöl'den yeni desmid kayi{dotless}tlari{dotless}]
Akar, Bülent; Şahin, Bülent
The benthic algal flora of Karagöl Lake (Şavşat, Artvin) was investigated between October 2008 and September 2010. Actinotaenium diplosporum var. americanum, Cosmarium pseudoexiguum, Gonatozygon kinahanii, Staurastrum boreale var. quadriradiatum, S. hantzschii and Staurodesmus dejectus var. apiculatus were recorded for the first time for the desmid flora of Turkey.
AtıfScopus13WoS12OpenAlex2İncele