Sürdürülebilir Kalkınma Amaçları

Yazarlar

  • MakaleYalnız künye2020Scopus SJRQ3
    Comparative Investigation on Magnetic Behavior of Partial Rare Earth Element (Re: Lu, Yb, and Dy) Substituted Y0.5Re0.5BCO (123) Superconductors

    Öztürk, Ali; Düzgün, İbrahim; Başoğlu, Mehmet; Çelebi, Selahattin

    Partial Re (rare earth elements: Lu, Yb and Dy) substituted YBaCuO (123) superconductors synthesized by solid-state reaction (SSR) procedure have been investigated via x-ray diffraction, scanning electron microscopy, a.c. magnetic susceptibility, and d.c. magnetization, and calculations. The measurements of a.c. magnetic susceptibility have been carried out at constant a.c. field amplitude and constant frequency for the samples studied. The temperature dependence of intergranular critical current density (Jcm) has been estimated from the a.c. magnetic susceptibility data. The d.c. magnetization measurements were performed at the temperatures of 5 K, 20 K, and 77 K separately. The variation of critical current density (Jc) with magnetic field (μ0H) has been evaluated from the d.c. magnetization data by using upper and lower branch of the major hysteresis curve. Lu substituted Y0.5Lu0.5BCO (123) sample shows higher critical current density than Yb and Dy substituted samples at low-temperature (lower than 77 K) regions.

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  • MakaleYalnız künye2020
    A GENERAL OVERVIEW ON THE REGION-TIME BEHAVIORS OF THE RECENT EARTHQUAKE ACTIVITY IN THE MARMARA REGION OF TURKEY

    Öztürk, Serkan; Gerdan, Serpil

    The principal aim of this study is to make a general assessment of the regional and temporal behaviors of the seismicity in the Marmara region of Turkey. For this purpose, the well-known spatio-temporal tools such as Mc-value, b-value, Dc-value, Z-value, recurrence period and annual probability were evaluated. The data catalog is homogeneous for local magnitude, ML, and includes 18,662 events with 0.4≤ML≤5.7 between 2000 and 2020. Earthquake magnitudes change between 1.5 and 3.0 and hence, Mc-value was taken as 2.7. b-value was calculated as 1.14±0.07 and the earthquakes with small magnitude can be effective on this relatively large value. Dc-value was estimated as 1.57±0.03 with a scale invariance from 5.03 to 87.64 km. This moderate value means that distance between the epicenters approaches the diameter of cluster and, earthquake activity is more clustered in larger areas or at smaller scales. Time-magnitude estimations of annual probability and recurrence period indicate that the Marmara region has an intermediate/long terms hazard for the occurrence of strong/large earthquakes. Anomaly regions with low b-value and large Z-value observed at the beginning of 2019 can be considered as the most likely regions for strong/large earthquake occurrences in the next. As a remarkable fact, a correlation and combined interpretation of these seismotectonic parameters may supply a preliminary and essential perspective in the seismic hazard for strong/large earthquake occurrences in the Marmara region of Turkey in the intermediate/long terms.

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  • MakaleYalnız künye2020Scopus SJRQ2
    Moderating effect of optimum stimulation level on the relationship between satisfaction and revisit intention: the case of Turkish cultural tourists

    Evren, Savaş; Şimşek Evren, Emine; Çakıcı, A. Celil

    Purpose: The purpose of this study is to determine the optimum stimulation levels (OSLs) of cultural tourists within the context of their novelty seeking tendencies and to determine whether their OSLs have a moderating effect on the relationship between their satisfaction and revisit intentions. Design/methodology/approach: To collect data, an online survey was conducted for Turkish cultural tourists (n = 563) in May 2018, and the data were analysed with PROCESS by Hayes. Findings: The study’s findings demonstrated that Turkish cultural tourists were high-level novelty seekers and that novelty seeking has a moderating effect on the relationship between their satisfaction and short-term revisit intentions. Originality/value: This study contributes to the literature by revealing the moderator effect of novelty seeking tendency on the relationship between satisfaction and revisit intention within the scope of cultural tourism, which has not been examined before.

    AtıfScopus18WoS10OpenAlex23
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  • MakaleAçık Erişim2020Scopus SJRQ3
    Investigation of healthy living strategies in elderly who achieved to live long and healthy

    Sahinoz, Turgut; Sahinoz, Saime

    Objective: To determine the lifestyles, healthy living strategies and socio-cultural characteristics of elderly people who lived long and healthy. Methods: This study was a cross-sectional study. This study was conducted on 472 elderly patients, aged 80 years and over, selected by random sampling method. The socio-demographic characteristics and daily living activities of the elderly were determined by face to face interview technique using the “Elderly Questionnaire” developed by the researchers in 2018. Chi-square test was used for statistical analysis. Results: Based on the average age (84) of the elderly in the research group, it was seen that they were able to exceed the average life expectancy of their fathers (72) and mothers (73). It has been found that the participants live 11-12 years longer than their parents. It was also found that more than half (51.9%) of the elderly have the habit of walking regularly every day. It was determined that the elderly mostly consumed vegetables and fruits (88.5%), milk and dairy products and meat, respectively. Conclusion: The elderly stated that natural and healthy nutrition, working and staying away from stress in the top three places as the reason of their long and healthy life.

    • SDG 2 · Açlığa Son
    • SDG 3 · Sağlık ve Kaliteli Yaşam
    AtıfScopus6WoS5OpenAlex9
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  • MakaleAçık Erişim2020Scopus SJRQ3
    Effects of elevation on the aboveground biomass and carbon stock in the oriental beech (Fagus orientalis lipsky) forests of the Sinop region, Turkey

    Kahyaoğlu, N.; Kara, Ö.; Güvendi, E.

    In this study it was our aim to assess the amount of aboveground biomass and carbon stock of beech stands based on elevation. To achieve this, in the research area, 55 trial sites were chosen by selective sampling method depending on elevation climatic zones (400–600 m, 600–800 m, 800–1000 m). In these trial areas, 55 trees were cut down and the weights of their bark, leaves, stem and branches were determined. The carbon content of each component was calculated. The results of the study showed that, in all elevation zones, the stem wood had the highest average biomass and carbon stock values of all the tree components (for the 400–600 m, biomass was 199.19 kg and carbon stock was 95.82 kg; for the 600–800 m, biomass was 378.75 kg and carbon stock was 182.49 kg; for the 800–1000 m, biomass was 372.56 kg and carbon stock was 183.39 kg). This was followed by the branches, bark and leaves in descending order. The aboveground biomass in the single tree components of leaves, branches, stem and total biomass, all except the biomass of their bark varied with elevation in oriental beech stands, which are economically significant species in Turkey.

    • SDG 13 · İklim Eylemi
    • SDG 15 · Karasal Yaşam
    AtıfScopus4WoS3OpenAlex8
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  • MakaleYalnız künye2020Scopus SJRQ2
    Effects of voltage on the components of surface integrity of Al2O3 ceramic coatings on AA2024 by plasma electrolytic oxidation

    Matin, Reza; Totik, Yasar; Sukuroglu, Ebru Emine; Efeoglu, Ihsan; Santos, Telmo G.

    It is said that plasma electrolytic oxidation (PEO) is considered as an effective technique to boost the surface properties of light materials by means of forming ceramic films on their surfaces. In this study, three different voltage values were applied to the PEO process to AA2024 so that Al2O3 ceramic coatings were directly supplied for AA 2024 substrates by PEO and it is focused on the adhesion of interface between coating and substrate. All of the cases such as microstructure, phase composition, thickness, roughness and hardness of Al2O3 ceramic coatings were assayed by X-ray diffraction (XRD), scanning electron microscopy (SEM), Atomic-force microscopy (AFM), Eddy Current Non-destructive testing and microhardness test, respectively. The results showed that roughness, hardness and thickness of the coatings were increased as we increased the voltage. Therefore, it could be claimed that the voltage parameters have an important role in the unified coating on the metal surface as it is directly connected with the morphologies of the PEO coating.

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  • MakaleYalnız künye2020Scopus SJRQ2
    Source Identification Problem for a Parabolic Equation with Multipoint Nonlocal Boundary Condition

    Ashyralyyev, Charyyar; Akkan, Pinar

    We study a source identification problem for a parabolic equation with multipoint nonlocal boundary condition. Stability estimates for the solution of abstract source identification problem are established. In application, stability estimates for the solution of the overdetermined mixed boundary value problem for multidimensional parabolic equation are obtained. The first and second order of accuracy difference schemes for the approximate solution of this problem are constructed. Stability estimates for solutions of these difference schemes are proved. Numerical illustration for a simple test problem is presented.

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  • MakaleYalnız künye2020Scopus SJRQ2
    Series tuned mass dampers in vibration control of continuous railway bridges

    Araz, Onur; Kahya, Volkan

    This paper presents the applicability of series tuned mass dampers (STMDs) to reduce the multiple resonant responses of continuous railway bridges under high-speed train. The bridge is modeled by two-span Bernoulli-Euler beam with uniform cross-section, and a STMD device consisting of two TMD units installed on the bridge to reduce its multiple resonant vibrations. The system is assumed to be under the action of a high-speed train passage which is modeled as a series of moving forces. Sequential Programming Technique (SQP) is carried out to find the optimal parameters of the STMD that minimizes the maximum peak responses of the bridge. Comparisons with the results available in the literature are presented to demonstrate the effectiveness and robustness of STMD system in reducing the multiple resonant responses of the continuous railway bridges under high-speed trains.

    • SDG 9 · Sanayi, Yenilikçilik ve Altyapı
    AtıfScopus26WoS25OpenAlex14
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  • MakaleAçık Erişim2020Scopus SJRQ3
    Single production of composite electrons at future sppc-based lepton–hadron colliders

    Caliskan, A.

    We consider the production of excited electrons with spin-1/2 at future SPPC-based electron–proton colliders with center-of-mass energies of 8.4, 11.6, 26.6, and 36.8 TeV. These exotic particles are predicted in the composite models. We calculate the production cross sections and concentrate on the photon decay channel of the excited electrons with the process of ep → e*X → eγX. The pseudo rapidity and transverse momentum distributions of the electrons and photons in the final state have been plotted to determine the kinematical cutoffs best suited for discovery of the excited electrons. By applying these cutoffs we compute 2σ, 3σ, and 5σ contour plots of the statistical significance of the expected signal in the parameter space (L, m*), where L denotes the integrated luminosity of the collider and m* is the mass of the composite electrons.

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  • MakaleYalnız künye2020Scopus SJRQ2
    Determination of the environmental natural radioactivity and mapping of natural background radioactivity of the Gumushane province, Turkey

    Kaya, Selim; Kaya, Ali; Çelik, Necati; Kara, Rasim Taylan; Taşkın, Halim; Koz, Bahadır

    The aim of the study is to determine the ambient radiation level in Gumushane province. With this aim, the gamma dose ratios absorbed in the air were surveyed by a portable gamma detector. The activity concentrations of 226Ra, 232Th, 40K, and 137Cs in soil samples have been measured by the gamma spectrometric analysis system. The gross alpha and beta activity concentrations in drinking water were also determined by the alpha and beta counting system. By considering the geological structure, the soil samples have been obtained from 62 different spots. In addition, 77 samples of natural and tap water have been collected from different points of the province. The samples were analyzed at the Cekmece Nuclear Research and Training Center in Turkey. Absorbed gamma dose rates in the air were measured in 338 different points in the studied area.

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  • MakaleYalnız künye2020Scopus SJRQ1
    A novel billing approach for fair and effective demand side management: Appliance level billing (AppLeBill)

    Çakmak, Recep; Altaş, İsmail Hakkı

    Demand side management (DSM) is an important part of smart electrical grid studies due to high energy efficiency it provides. Effective DSM techniques are hinged on participation level of the customers and control manner of their loads so if there is no fair and appropriate management, customers will not embrace demand side management applications. Besides, the customers might not participate to the demand response process willingly if their comforts are not considered. Therefore, the DSM systems must consider fairness and customer's comfort as well as distribution system objectives. Multifarious DSM systems have been proposed in the literature, however, the fair billing has not included as a parameter in most of these studies. This paper introduces a novel billing approach based upon appliance level billing (AppLeBill) for fair and effective demand side management. The proposed AppLeBill idea offers a billing strategy such that time-shiftable appliances (TSAs) in a residence may have a separate billing rate rather than a single billing rate for total electricity usage. The proposed AppLeBill concept includes three different schemes which are explained and simulated in order to compare each other in terms of their potential benefits.

    • SDG 7 · Erişilebilir ve Temiz Enerji
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  • MakaleYalnız künye2020Scopus SJRQ2
    Comparison of sandstone and mudstone with different methods for assessing toxic element contamination in the Early–Middle Jurassic sediments of Gümüşhane (NE Turkey)

    Saydam Eker, Çiğdem; Arı, Uğur Volkan

    To investigate the vertical changes of toxic elements in Jurassic sediments, sampling was performed in four sites. Samples were collected from sandstones and mudstones/marls and analyzed for some toxic elements (Cu, Pb, Zn, As, Ni and V). Results exhibited that the sediment grain size played a significant role in controlling the concentrations of the toxic elements in the sediments. The mean toxic element contents of mudstones/marls were higher than those of sandstones (except Cu). The contamination level of toxic elements was detected by enrichment factor (EF), geo-accumulation index (Igeo), potential ecological risk index (Eir), pollution index (Pi) and united pollution index (PIn). The low EF, Igeo, Eir, Pi and PIn for Cu, Pb, Zn, Ni, V in the sandstones and Cu, Zn, Ni in the mudstones/marls exhibited an absence of clear these elements pollution. The high EF, Eir, Pi and PIn for As (9.7, 73, 7 and 29, respectively, as mean values) in the sandstones and for As (49.3, 222, 22 and 75, respectively, as mean values) Pb (8.8, 24, 5 and 19, respectively, as mean values), V (8.3, 15, 7 and 39, respectively, as mean values) in the mudstones/marls indicated significant contamination. Additionally, according to the potential ecological risk (RI) values, the sandstones had low potential ecological risk for the toxic elements (RI < 150) and the mudstones/marls had moderate potential ecological risk (150 ≤ RI ≤ 300). The potential ecological risk As, Pb, V (especially As) were higher in urban areas than in agricultural activities. Therefore, the source of As, Pb, V could be gasoline combustion, burning coal and vehicle exhausts. The contents of these elements generally increased from bottom to top of the measured stratigraphic sections, which indicated transported by atmospheric conditions.

    • SDG 6 · Temiz Su ve Sanitasyon
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  • MakaleYalnız künye2020Scopus SJRQ1
    Eocene tonalite–granodiorite from the Havza (Samsun) area, northern Turkey: adakite-like melts of lithospheric mantle and crust generated in a post-collisional setting

    Temizel, Irfan; Arslan, Mehmet; Yücel, Cem; Abdioğlu Yazar, Emel; Kaygusuz, Abdullah; Aslan, Zafer

    Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Taşlık Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO2 (67–68 wt%) and Al2O3 (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and LaN/YbN (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and YbN (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (LaN/LuN = 14.2–21.6) with insignificant negative Eu anomalies (EuN/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have 87Sr/86Sr ratios of 0.704767 to 0.704927, 143Nd/144Nd ratios of 0.512767–0.512774, εNd values of (+2.52)–(+2.65), and δ18O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.

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  • MakaleAçık Erişim2020Scopus SJRQ2
    In situ monitoring of sugar content in breakfast cereals using a novel ft-nir spectrometer

    Aykas, Didem Peren; Ball, Christopher; Menevseoglu, Ahmed; Rodriguez-Saona, Luis E.

    This research demonstrates simultaneous predictions of individual and total sugars in breakfast cereals using a novel, handheld near-infrared (NIR) spectroscopic sensor. This miniaturized, battery-operated unit based on Fourier Transform (FT)-NIR was used to collect spectra from both ground and intact breakfast cereal samples, followed by real-time wireless data transfer to a commercial tablet for chemometric processing. A total of 164 breakfast cereal samples (60 store-bought and 104 provided by a snack food company) were tested. Reference analysis for the individual (sucrose, glucose, and fructose) and total sugar contents used high-performance liquid chromatography (HPLC). Chemometric prediction models were generated using partial least square regression (PLSR) by combining the HPLC reference analysis data and FT-NIR spectra, and associated calibration models were externally validated through an independent data set. These multivariate models showed excellent correlation (Rpre ≥ 0.93) and low standard error of prediction (SEP ≤ 2.4 g/100 g) between the predicted and the measured sugar values. Analysis results from the FT-NIR data, confirmed by the reference techniques, showed that eight store-bought cereal samples out of 60 (13%) were not compliant with the total sugar content declaration. The results suggest that the FT-NIR prototype can provide reliable analysis for the snack food manufacturers for on-site analysis.

    • SDG 2 · Açlığa Son
    AtıfScopus15WoS14OpenAlex14
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  • MakaleAçık Erişim2020Scopus SJRQ3
    Effects of starter culture and storage on volatile profiles and sensory characteristicof yogurt or cream butter; [Utjecaj starter kulture i skladištenja na hlapive sastojke i senzorska svojstva maslaca od vrhnja i maslaca od jogurta]

    Gundogdu, Engin; Cakmakci, Songul; Hayaloglu, Ali Adnan

    In this study volatile compounds and sensory properties of butter produced from cream or yogurt using Lactococcus lactis subsp. lactis biovar. diacetylactis or Leuconostoc mesenteroides subsp. cremoris as well as a mixture of these two bacteria were investigated over 60 days. A total of 10 esters, 6 aldehydes, 11 ketones, 16 alcohols, 6 acids, 2 sulphides, 3 terpenes, and 3 miscellaneous compounds were detected. There were more volatile compounds in cream butter than in yogurt butter. While S-methyl thioacetate was only found in yogurt butter samples, hexanal, ethanol, 2-nonanone, 2-pentanone, 2-heptanone, acetic, butanoic (butyric) and hexanoic acid were the most abundant volatiles in both cream and yogurt butter. The results showed that the use of starter in the manufacturing of yogurt butter, which is traditionally produced without starters, affected the volatile compounds and sensory properties. The highest general acceptability scores were given to the butter samples containing mixed cultures at the end of storage.

    • SDG 2 · Açlığa Son
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  • MakaleYalnız künye2020Scopus SJRQ2
    Investigation of the relationship between rare earth elements, trace elements, and major oxides in soil geochemistry

    Vural, Alaaddin

    Investigation on the behavior of elements in the soil is important both in exploration and environmental geochemistry studies. Rare earth elements (REEs) are the most useful among all trace elements. REE studies have shown that they have important applications in igneous, sedimentary, and metamorphic petrology. This work aims to investigate the relationship of these elements with one another and the behavior of the major oxides and trace elements with REEs. Soil samples were obtained from the alteration site possibly related to mineralization and were analyzed for major oxides, trace elements, and REEs. The relationships between the major oxide–trace element/heavy metal and REE were investigated by statistical methods, such as descriptive statistics, correlation coefficient, and principle component analysis. According to the correlation coefficient matrix, light REEs (LREEs) showed weak to moderate negative correlation with MgO and MnO and moderately positive correlation with SiO2 and K2O. No association was detected between the heavy REEs (HREEs) and the main oxides, but a strong positive correlation with LREEs was observed. For the trace elements, LREE showed a weak positive correlation with Ba and Sn and moderate to strong positive correlation with As, Hf, Nb, Rb, Ta, Th, U, W, and Zr. They also displayed weak to moderate correlation with Sc, Co, Zn, Ni, and V. HREE showed weak to moderate positive correlation with Ni, Cs, Ga, Hf, Th, Zr, As, and LREE. Although REEs exhibited no direct correlation with Au and Ag, they showed a good correlation with some trace elements that are related to hydrothermally altered products. This study showed that REEs can also be used in exploration and environmental geochemistry studies by exploiting the relationship between REEs and other trace/heavy metal elements.

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  • MakaleYalnız künye2020Scopus SJRQ1
    Geochemistry of the Middle Jurassic sediments in Gümüşhane, north-eastern Turkey: Implications for weathering and provenance

    Saydam Eker, Çiğdem; Arı, Uğur V.

    The whole-rock geochemistry and Sr-Nd isotope data of Middle Jurassic sedimentary rocks in the Gümüşhane area (north-eastern Turkey) were analysed to reconstruct the provenance, chemical weathering, sediment recycling history, and tectonic setting of the source area. Based on trace element ratios and rare earth element (REE) patterns, it was interpreted that the sandstones were derived from a source area with felsic-mafic rocks as dominant contributors. The average chemical index of alteration (CIA) and weathering index (WIP) values are low with respect to Upper Continental Crust (UCC) in the studied sandstones and mudstones, but the index of compositional variability (ICV) values are high, thus revealing weak–moderate weathering conditions. The average Th/U ratios of the sandstones and mudstones indicate a relatively simple cycling history. The positive and low negative εNd values support the supposition that the source area did not undergo much sedimentary change. A model mixture composed of 60% granite, 5% granodiorite, and 35% gabbro could be deduced to be the potential source composition of Middle Jurassic sediments; this model was reinforced by the 87Sr/86Sr ratios and εNd(t) values of the sediments. The Middle Jurassic siliciclastic sedimentary rocks of the Gümüşhane region were likely deposited in a tectonic environment with a passive margin.

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  • MakaleAçık Erişim2020
    Political Polarization and Size of Government; [Politik Kutuplaşma ve Devletin Ekonomik Boyutu]

    Keyifli, Nazlı; Akdede, Sacit Hadi

    In this study, it empirically examines the impact of economic and political determinants on the economic size of the government. Political polarization is taken as the variable of interest, along with other control variables. Statistical analysis was carried out using the Ordinary Least Squares and Second Stage Least Squares methods. The scope of the paper includes 61 countries, and the time interval is between 1990 and 2015. The results of the regression analysis show that the share of public consumption spending in national income in countries where political polarization is high is declining. In addition, the increase in levels of ethnic fracturalization, democracy and government fractionalization has an increasing effect on the share of public consumption spending in national income. The study provides descriptive linkages among findings.

    • SDG 8 · İnsana Yakışır İş ve Ekonomik Büyüme
    • SDG 16 · Barış, Adalet ve Güçlü Kurumlar
    AtıfScopus1OpenAlex4TR Dizin5
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  • MakaleAçık Erişim2020
    A note on well-posedness of source identification elliptic problem in a Banach space; [Банах кеңiстiгiнде дереккөздi сәйкестендiруде эллипстiк есептiң корректiлiгi туралы ескерту]; [Замечание о корректности эллиптической задачи идентификации источника в банаховом пространстве]

    Ashyralyev, A.; Ashyralyyev, C.; Zvyagin, V.G.

    We study the source identification problem for an elliptic differential equation in a Banach space. The exact estimates for the solution of source identification problem in Hölder norms are obtained. In applications, four elliptic source identification problems are investigated. Stability and coercive stability estimates for solution of source identification problems for elliptic equations are obtained.

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  • MakaleAçık Erişim2020Scopus SJRQ2
    The effect of shape-controlled pt and pd nanoparticles on selective catalytic hydrodechlorination of trichloroethylene

    Sarıbıyık, Oğuz Yunus; Rupprechter, Günther; Weilach, Christian; Serin, Selahattin

    Tailoring the shape of nanoscale materials enables obtaining morphology-controlled surfaces exhibiting specific interactions with reactants during catalytic reactions. The specifics of nanoparticle surfaces control the catalytic performance, i.e., activity and selectivity. In this study, shape-controlled Platinum (Pt) and Palladium (Pd) nanoparticles with distinct morphology were produced, i.e., cubes and cuboctahedra for Pt and spheres and polyhedra/multiple-twins for Pd, with (100), (111 + 100), curved/stepped and (111) facets, respectively. These particles with well-tuned surfaces were subsequently deposited on a Zirconium oxide (ZrO2 ) support. The morphological characteristics of the particles were determined by high resolution transmission electron microscopy (HR-TEM) and X-ray diffraction (XRD), while their adsorption properties were investigated by Fourier transform infrared spectroscopy (FTIR) of CO adsorbed at room temperature. The effect of the nanoparticle shape and surface structure on the catalytic performance in hydrodechlorination (HDCl) of trichloroethylene (TCE) was examined. The results show that nanoparticles with different surface orientations can be employed to affect selectivity, with polyhedral and multiply-twinned Pd exhibiting the best ethylene selectivity.

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