Gümüşhane ÜniversitesiGümüşhane ÜniversitesiAçık Erişim Arşivi · RDL Open

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  • MakaleAçık Erişim2011
    Early abyssal- and late SSZ-type vestiges of the Rheic oceanic mantle in the Variscan basement of the Sakarya Zone, NE Turkey: Implications for the sense of subduction and opening of the Paleotethys

    Dokuz, Abdurrahman; Uysal, Ibrahim; Kaliwoda, Melanie; Karsli, Orhan; Ottley, Chris J.; Kandemir, Raif

    The boundary between the Gondwana and Laurussia, or a terrane separated from it, is traced by a suture recording the closure of the Rheic ocean in the Pulur, Beyçam and Kurtoǧlu areas of the eastern Sakarya Zone of Turkey. Pulur lherzolite has a lower Cr# [100Cr/(Cr+Al)=5-37] of the spinel and slightly enriched flat medium-heavy rare earth element (M-HREE) whole-rock pattern typical for those of the fertile abyssal-type lherzolite. By contrast, the Beyçam harzburgite displays the mineralogical and geochemical features of a moderately depleted residue at a supra subduction zone (SSZ). Some of spinels from the Beyçam peridotites show TiO2 contents (0.15-0.48wt.%) identical to a later interaction with a melt of island-arc tholeiite (IAT) composition. Meta-basalt from the Beyçam area is the representative of such a melt and displays the whole-rock M-HREE pattern of a complementary product of the Beyçam harzburgite. Data presented in this study support the primarily northward directed closure of the Rheic ocean, but suggest that the Variscan basement in the eastern part of the Sakarya Zone consists of mantle peridotites formed in a south-vergent SSZ. This dual polarity of subduction in the Rheic ocean, at least in the second half of its closure, is also favored by the geological structure and lithological diversity of the Variscan rocks. These are: (1) spatial distribution of the peridotites, e.g., SSZ-type harzburgites to the north and abyssal-type lherzolites to the south, (2) lack of high-pressure metamorphic rocks, (3) decrease in the degree of Variscan metamorphism toward the north, and (4) emplacement of Variscan syn-collisional magmatism into the low grade metamorphic rocks to the north. Paleotethys was the other ocean of the region created in the Late Paleozoic. Northward subduction of the Rheic ocean from Early Devonian to Early Carboniferous appears to be the most plausible mechanism responsible for the opening of Paleotethys. In this scenario the Paleotethys is envisaged as a back-arc basin opened to the north in the wake of separated terranes from Laurussia. Onset of trench-Rheic mid-ocean ridge collision in the Early Devonian along the northern margin of Laurussia has been proposed to account for the initiation of SSZ-type subduction to the south. The short duration of this subduction appears insufficient to open a fully developed back-arc basin to the south because the elimination of Rheic mid-ocean ridge to the north accelerated the oceanic closure.

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  • MakaleYalnız künye2011
    Preconcentration of Cd(II) and Cu(II) ions by coprecipitation without any carrier element in some food and water samples

    Duran, Celal; Ozdes, Duygu; Sahin, Deniz; Bulut, Volkan Numan; Gundogdu, Ali; Soylak, Mustafa

    A simple, rapid, sensitive and environmentally friendly separation and preconcentration procedure, based on the carrier element free coprecipitation (CEFC) of Cu(II) and Cd(II) ions by using an organic coprecipitant, 2-{[4-(4-fluorophenyl)-5-sulphanyl-4H-1,2,4-triazol-3-yl]methyl}-4-{[(4-fluorophenyl) methylene]amino}-5-(4-methylphenyl)-2,4-dihydro-3H-1,2,4-triazol-3-one (MEFMAT) was developed. The analyte ions were determined by flame atomic absorption spectrometric (FAAS) determinations. The optimum conditions for the coprecipitation process were investigated on several commonly tested experimental parameters such as pH of the solution, amount of MEFMAT, sample volume, standing time, centrifugation rate and time. The influences of some anions, cations and transition metals on the recoveries of analyte ions were also investigated, and no considerable interference was observed. The preconcentration factor was found to be 50. The detection limits for Cu(II) and Cd(II) ions based on the three times the standard deviation of the blanks (N:10) were found to be 1.49 and 0.45μgL-1, respectively. The relative standard deviations were found to be lower than 3.5% for both analyte ions. The method was validated by analyzing two certified reference materials (CRM-TMDW-500 Drinking Water and CRM-SA-C Sandy Soil C) and spike tests. The procedure was successfully applied to sea water and stream water as liquid samples and tobacco, hazelnut and black tea as solid samples.

    • SDG 6 · Temiz Su ve Sanitasyon
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  • MakaleAçık Erişim2011
    Transition from shoshonitic to adakitic magmatism in the eastern Pontides, NE Turkey: Implications for slab window melting

    Eyuboglu, Yener; Chung, Sun-Lin; Santosh, M.; Dudas, Francis O.; Akaryali, Enver

    The formation of the eastern Pontides orogenic belt has been widely assigned to a northward subduction of the Neotethyan oceanic slab during the late Mesozoic-Cenozoic. Here we provide an alternate model based on new geological, geochemical and isotopic data. The magmatic activity in the far south of the belt started in the early Campanian with shoshonitic trachyandesites and associated pyroclastics. This sequence is covered by the late Campanian-early Maastrichtian reefal limestones and another stage of high-K volcanism represented by analcimized leucite-rich ultrapotassic rocks of the Maastrichtian-early Paleocene (?) ages. The shoshonitic and ultrapotassic rocks, with K2O contents ranging from 0.26 to 6.95 wt.%, display broadly similar rare earth and multi-element distribution patterns. Both rock types are enriched in LILE and LREE and depleted in HFSE (Nb,Ta and Ti), suggesting a subduction-enriched mantle source for the magma generation. Subsequently, during the late Paleocene, a stage of acidic magmatism (SiO2 of 53.25-73.61 wt.%) that shows adakitic geochemical characteristics including high Sr/Y (46-416) and La/Yb (11-51) and low Y (2.6-12.2 ppm), is documented characterized by melting of a mafic source such as the MORB crust with garnet in the residue. The adakitic magmatism began at similar to 56 Ma and migrated toward the north through time, culminating with porphyritic andesites (similar to 47 Ma) that were emplaced in the Gumushane-Bayburt line and its vicinity. North of this line, coeval magmas show typical calc-alkaline nature and continued to develop toward further north until the middle to late Eocene. Based on the spatial and temporal variations in the magmas generated in the eastern Pontides orogenic belt, we propose a new geodynamic model to explain the tectonomagmatic evolution of these rocks and correlate the adakitic magmatism to ridge subduction and slab window process within a south-dipping subduction zone. Our model is in contrast to the previous proposals which envisage partial melting or delamination of thickened lower continental crust due to the collision in the south during the Paleocene-Eocene. (C) 2010 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved.

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  • MakaleYalnız künye2011
    Adakite-like granitoid porphyries in the Eastern Pontides, NE Turkey: Potential parental melts and geodynamic implications

    Karsli, Orhan; Ketenci, Murat; Uysal, Ibrahim; Dokuz, Abdurrahman; Aydin, Faruk; Chen, Bin; Kandemir, Raif; Wijbrans, Jan

    The tectonic setting of the Eastern Pontides during the late Mesozoic to early Cenozoic remains a subject of debate. Petrogenesis of adakite-like granitoid porphyries plays a critical role in determining the nature of the lower continental crust and mantle dynamics during orogenic processes in the region. Here we describe, for the first time, the late Paleocene to early Eocene adakite-like granitoid porphyries from the northern part of the Eastern Pontides although their counterparts in the southern part have recently been found. The adakitic porphyries, which emplaced into the subduction-related Turonian-Santonian volcanics from northern part of the region, consist of I-type calc-alkaline quartz monzonite-tonalite (SiO2 = 62.89-65.07 wt.%) and high-k calc-alkaline granodiorite-granite associations (SiO2 = 69.06-70.43 wt.%). The former displays peraluminous to metaluminous signatures, whereas the latter shows peraluminous geochemical character. The granite-granodiorite porphyries have high K2O (3.32-3.84 wt.%), and low Na2O (3.48-4.61 wt.%) and MgO (0.91-1.04 wt.%) relative to the quartz monzonite-tonalite association (K2O = 1.50-1.92 wt.%; Na2O = 4.08-6.45 wt.%; MgO = 1.44-2.07 wt.%). Ar-Ar geochronology studies on the amphibole separates reveal that the adakite-like porphyries have a crystallization ages of 51.34 +/- 0.27 to 53.55 +/- 0.34 Ma. Here, we contend that these rocks were formed by partial fusion of a mafic lower continental crust in a collisional phase but not in a subduction setting. All the samples exhibit the typical geochemical characteristics of adakite, that is, high Sr (250-1141 ppm), high Sr/Y ratios (16-147), low Y (6.8-14.8 ppm) and low HREE concentrations; they are similar to adakites formed by slab melting associated with the subduction zone. However, the rocks exhibit heterogeneity in isotopic composition, with I-Sr ranging from 0.70554 to 0.70986, epsilon(Nd) (51 Ma) from -8.5 to -0.9 and Nd model ages from 0.72 to 1.26 Ga. The samples are characterized by relatively high Th, Th/U and no significant Eu anomalies, implying that garnet was stable in their source during partial melting. The compositional diversity between rock groups is probably related to partial melting of heterogeneous lower crustal source. All of the features are inconsistent with a slab-melting origin and slab-related petrogenetic model, but instead, they favor an origin by melting of heterogeneous lower continental crust due to a thermal anomaly that was induced by the upwelling of the asthenosphere through a slab break-off in a collisional setting. These interpretations argue against the evidence for the presence of an early Cenozoic arc setting in the Eastern Pontides. Instead, the early Cenozoic time in the region may be attributed to a geodynamic response to a post-collisional uplift phase that occurred along the continent-continent collision between the Pontide and the Anatolide-Tauride blocks. (C) 2011 Elsevier B.V. All rights reserved.

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  • MakaleYalnız künye2010
    Multiobjective optimization of angle-ply laminated plates for maximum buckling load

    Topal, Umut; Uzman, Ümit

    This paper deals with multiobjective optimization of symmetrically angle-ply square laminated plates subjected to biaxial compressive and uniform thermal loads. The design objective is the maximization of the buckling load for weighted sum of the biaxial compressive and thermal loads. The design variable is the fiber orientations in the layers. The performance index is formulated as the weighted sum of individual objectives in order to obtain optimal solutions of the design problem. The first-order shear deformation theory (FSDT) is used in the mathematical formulation of buckling analysis of laminated plates. The modified feasible direction (MFD) method is used for optimization routine. For this purpose, a program based on FORTRAN is used. Finally, the effect of different weighting factors, number of layers, aspect ratios, load ratios and boundary conditions on the optimal design is investigated.

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  • BildiriAçık Erişim2010
    Assessment of Turkish and class teacher candidate's attitudes towards children's literature and children's literature lesson

    Ulaş, A. Halim; Kolaç, Emine; Topal, Yakup; Sevim, Oǧuzhan; Keser, H; Ozcinar, Z; Kanbul, S

    Purpose of this research is to reveal class and Turkish teacher candidates' attitudes towards children's literature lesson, and works of children's literature. Study group of this research is comprised of students from Classroom Teaching and Turkish Teaching Departments of Faculty of Education of Atatürk University. Answers were sought for the level of classroom teaching and preschool teacher candidates' towards children's literature lesson, and works of children's literature, and whether there is any significant difference is seen in classroom teaching and pre-school teacher candidates' towards children's literature lesson, and works of children's literature in terms gender, and departments. Having the research conducted according to survey method (2007), "Attitude Scale towards Children's Literature, and Children's Literature Lesson", having been developed by ..., and comprised of 35 articles, was made use of. At the end of the research, it was concluded that teacher candidates had developed a positive attitude towards children's literature, and children's literature lesson, and neither gender, nor field differences had significantly affected that attitude.

    • SDG 4 · Nitelikli Eğitim
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  • MakaleYalnız künye2007
    The magnetic susceptibility of granitic rocks as a proxy for geochemical composition: Example from the Saruhan granitoids, NE Turkey

    Aydin, Ali; Ferré, Eric C.; Aslan, Zafer

    The magnetic susceptibility of rocks is determined by their bulk chemistry and magnetic mineralogy. In this case study of the Saruhan pluton in Turkey, a detailed survey based on 925 field measurements and 37 whole rock analyses, reveals a strong correlation between magnetic susceptibility and FeOt (R2 = 0.8). Petrographic observations and calculations based on whole-rock major element analyses indicate the presence of magnetite grains. Further calculations show that magnetite accounts for 88% of the magnetic susceptibility. The spatial correlation between FeOtotal and the magnetic susceptibility is particularly spectacular which suggests that Km is a proxy for geochemical differentiation. The zoning pattern of magnetic susceptibility across the pluton is concentric and reverse, with the highest values of magnetic susceptibility in the center. This type of zoning is consistent with a previously proposed petrogenetic model. The comparison of the Saruhan granites with a classic example of paramagnetic granites reveals two contrasted FeOt-Km trends. This suggests that these variations can be a useful tool to distinguish between leucocratic paramagnetic and leucocratic ferrimagnetic granites.

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  • Dergi
    NEW BIOTECHNOLOGY
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  • Dergi
    WORLD MULTIDISCIPLINARY EARTH SCIENCES SYMPOSIUM, WMESS 2015
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  • Dergi
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
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  • Dergi
    LITHOS
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