Sürdürülebilir Kalkınma Amaçları
Yazarlar
Yayınlar
- MakaleAçık Erişim2026Physicochemical properties of fifteen flower honey samples from five districts in Türkiye
Ucuncu, Osman; Kul, Merve Kalafat; Baltaci, Cemalettin; Aykoc, Ayse Muslu
This study analyzed the physicochemical characteristics, mineral composition, and antioxidant potential of fifteen floral honey samples collected from five districts of Gümüşhane, Türkiye. The average values for moisture (17.44 g/100 g), insoluble solids (0.04 g/100 g), conductivity (0.35 mS/cm), diastase activity (54.15 DN), free acidity (38.18 meq/kg), and fructose + glucose content (68.95 g/100 g) were mostly within the acceptable limits defined by national honey standards. Proline content ranged from 562.66 to 1466.15 mg/kg, while hydroxymethylfurfural (0.37–18.89 mg/kg) confirmed the freshness of all samples. Potassium, calcium, sodium, and magnesium were identified as the major mineral elements in the analyzed honey samples, with considerable variation observed among samples collected from different districts. Antioxidant activity (Total phenolic content (mg GAE/100 g): 9.21–98.25; SC₅₀ (mg/mL): 5.23–41.29) revealed a strong antioxidant potential of Gümüşhane honeys. This work provides the first detailed characterization of Gümüşhane honeys, confirming their high physicochemical quality, rich mineral profile, and notable antioxidant potential, and underscores their value as a distinctive regional product with functional and commercial significance.
- MakaleAçık Erişim2025MODELING THE KINETICS OF HYDROXYMETHYLFURFURAL (HMF) FORMATION IN POMEGRANATE SOUR PRODUCED BY DIFFERENT EVAPORATION METHODS
Erdoğdu, Esma Gülbahar; Akar, Bülent; Baltacı, Cemalettin
Pomegranate sour is a traditional functional food that is widely consumed in Türkiye. The aim of this study is to determine the most convenient evaporation method to keep the amount of HMF, a carcinogenic substance formed as a result of high temperatures in the production of pomegranate sour, at low levels. The pomegranate sours were produced using five different evaporation methods (atmospheric pressure (AP), freeze-drying (FD), open air (OA), vacuum assisted (VA) and fan assisted (FA)) and the amount of HMF formed during the process was determined. Kinetic calculations showed that VA and FA methods followed first-order reaction kinetics at 60, 70 and 80 °C, while OA, FD and AP methods followed zero-order reaction kinetics at 80, 90 and 100 °C. The mean Q10 value was 1.0006, while the activation energy (Ea) ranged from 72.56 to 126.38 kJ/mol. It was found that the amount of HMF formed varied according to the method, temperature and production time and that the reaction rates increased with increasing temperature, especially for the OA method. In addition, pH, titratable acidity, invert and total sugar content, color, Brix and browning index were analyzed and a kinetic model including all these factors was developed.
- Derleme MakaleAçık Erişim2024Production of 5-Hydroxymethylfurfural from Non-edible Lignocellulosic Food Wastes
Muslu, Ayşe; Üçüncü, Osman; Baltacı, Cemalettin
The compound 5-(hydroxymethyl)furfural (HMF) has emerged as a versatile intermediate with the ability to undergo conversion into both fuel and a variety of platform chemicals. Lignocellulosic biomass, such as hazelnut shells and tea processing residues, was employed in this study for HMF production through two distinct methods. In the first method, cellulose from biomass was converted to sugars using a 4% acid solution, followed by catalytic conversion with NaCl/CrCl3.6H2O. After a 1-h reaction at 131 °C in a high-pressure system, HMF was obtained from tea processing waste and hazelnut shells with yields of 8.6% (82.3 mg/g) and 6.7% (66.7 mg/g), respectively. The second method involved LiCl/NaCl-doped N,N-dimethylacetamide (DMA) as an ionic solvent system for HMF production. After a 2-h reaction at 131 °C in the DMA-NaCl/[EMIM]Cl ionic solvent system, HMF was obtained from tea processing waste and hazelnut shell celluloses with yields of 5.7% (57.5 mg/g) and 3.1% (31.3 mg/g), respectively. This study contributes to the economic conversion of various food wastes into valuable chemicals, highlighting the potential of lignocellulosic biomass in sustainable chemical production.