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Synthesis and characterisation of new metallophthalocyanines containing four 12-membered diazadithia-macrocyclic moieties

MakaleYalnız künyeScopus SJRQ3

Özet

Tetrasubstituted zinc, cobalt, nickel, copper and lead phthalocyanines bearing four 12-membered diazadithia macrocyclic moieties on peripheral positions have been synthesised by cyclotetramerisation reaction of 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10] dithiadiazacyclododecine-12,13-dicarbonitrile and corresponding anhydrous metal salts under microwave irradiation. The thermal stabilities of the phthalocyanine compounds have determined by thermogravimetric analysis.

Anahtar Kelimeler

Macrocyclic compoundMetallophthalocyanineMicrowave irradiationMixed-donor macrocyclicPhthalocyanine
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Tam Kayıt
AlanDeğerDil
dc.contributor.authorKaya, Elif Çelenk
dc.contributor.authorKantekin, Halit
dc.contributor.authorKaya, Afşin Ahmet
dc.contributor.authorDakoǧlu, Asuman
dc.contributor.authorÖksüz, Sümeyra
dc.contributor.authorŞişik, Hanife
dc.date.accessioned2026-10-22T10:24:21.573513484Z
dc.date.available2026-10-22T10:24:21.573513484Z
dc.date.issued2012
dc.description.abstractTetrasubstituted zinc, cobalt, nickel, copper and lead phthalocyanines bearing four 12-membered diazadithia macrocyclic moieties on peripheral positions have been synthesised by cyclotetramerisation reaction of 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10] dithiadiazacyclododecine-12,13-dicarbonitrile and corresponding anhydrous metal salts under microwave irradiation. The thermal stabilities of the phthalocyanine compounds have determined by thermogravimetric analysis.
dc.description.sponsorshipThe Scientific Technological Research Council of Turkey (TUBITAK) [107T429]
dc.identifier.doi10.3184/174751912x13472922835683
dc.identifier.endpage659
dc.identifier.issn1747-5198
dc.identifier.issue11
dc.identifier.scopus2-s2.0-84871220384
dc.identifier.startpage657
dc.identifier.urihttps://rdlopen.rawdatalibrary.net/r/gumushane/15666
dc.identifier.volume36
dc.identifier.wosWOS:000313095100012
dc.language.isoen
dc.publisherScience Reviews 2000 Ltd
dc.relation.ispartofJournal of Chemical Research
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectMacrocyclic compound
dc.subjectMetallophthalocyanine
dc.subjectMicrowave irradiation
dc.subjectMixed-donor macrocyclic
dc.subjectPhthalocyanine
dc.subject.classificationChemistry, Multidisciplinary
dc.subject.classificationChemistry
dc.subject.otherSINGLET OXYGEN
dc.subject.otherMETAL-FREE
dc.subject.otherPHTHALOCYANINES
dc.subject.otherCHEMISTRY
dc.subject.otherFILMS
dc.subject.otherDNA
dc.titleSynthesis and characterisation of new metallophthalocyanines containing four 12-membered diazadithia-macrocyclic moieties
dc.typeArticle
rdl.citation.openalex1
rdl.citation.scopus1
rdl.citation.wos2
rdl.oa.statusclosed
rdl.scopus.quartileQ3
rdl.source.indexSCOPUS
rdl.source.indexWOS
rdl.wos.indexScience Citation Index Expanded (SCI-EXPANDED)
rdl.wos.indexIndex Chemicus (IC)