Pre-eruptive conditions revealed by mega- and pheno-cryst compositions from the Quaternary Erzincan Volcanics, Eastern Turkey: Insights into the magma processes

Quaternary Erzincan Volcanics (QEVs) from the Erzincan Basin consist of mega- and pheno-cryst-bearing high-K calc-alkaline dome lavas. Fourteen nearly phenocrystic domes, with a range of basaltic-andesite, andesite, dacite and rhyolite compositions, were emplaced in the North Anatolian Fault Zone. The emplacement ages yielded by the unspiked K-Ar technique range from 102 to 140 ka. The andesitic domes (each less than 3 km in diameter) contain amphibole megacrysts. Amphibole compositions show a linear variation from ferro-edenite, edenite to pargasite from rhyolite to andesite. Pargasitic amphibole megacrysts scattered into the groundmass are very similar in composition to the microlites. All plagioclases are <An53 mol%. Oscillation types are An32-50 whose variations range from 10 to 16 mol% An and have 10-150 μm in thickness. Pre-eruptive conditions, calculated from mega- and pheno-cryst composition, using pyroxene and two oxide thermometers and the Al-in-hornblende barometer, ranged from 918 to 837 °C and 6.6 to 4.3 kbar for andesitic magma, 824-755 °C and 4.6-4.2 kbar for dacitic magma to 803-692 °C and 4.3-3.9 kbar for rhyolitic magma, which correspond to a depth of >10 km for storage region of the crust. The fO2 values vary from -14.25 to -15.35 log units which are plotted just below nickel-nickel oxide (NNO) buffers. The systematic decrease in thermobarometric results from andesite to rhyolite is consistent with a single magma reservoir moving upward through the crust followed by fractional crystallization. Textural and compositional relationships of mega- and pheno-crystic phases suggest that magma mixing, fluid input to the reservoir and fractional crystallization processes, with a small amount crustal contamination play key role in evolution of the QEVs.