Kaygusuz, Abdullah; Güloğlu, Zikrullah Samet; Aydınçakır, Emre; Yücel, Cem; Vural, Alaaddin; Siebel, Wolfgang; Jeong, Youn-Joong

The Eastern Pontide Orogenic Belt (EPOB) hosts numerous plutonic bodies with different dimensions, compositions and ages ranging from Paleozoic to Late Eocene in NE Turkey. U-Pb zircon dating suggests that the Arslandede pluton crystallized at 44.50 ± 0.29 Ma, corresponding to the Lutetian (Middle Eocene) period. Rocks of this pluton have monzonitic character, with compositions ranging from monzodiorite to granite (SiO2 = 49˗71 wt%). The studied monzonitic rocks have I-type, metaluminous and shoshonitic character and are enriched in large-ion lithophile elements (LILEs). The rare earth elements (REEs) have concave up shape (LaN/YbN = 6.64–11.57) and show negative to slightly positive Eu anomalies (EuN/Eu* = 0.37–1.24). 87Sr/86Sr(i) values of 0.704801–0.705102 and εNd(i) values of 1.01–1.34 correspond to the mantle series on isotope ratio diagrams. Positive εHf(i) values (5.01–14.91) plot between the depleted mantle and the chondritic evolution lines. The petrological features of the rocks from the Arslandede pluton show that fractional crystallization with low rates of assimilation and/or magma mixing were effective during crystallization. All data show that the magma source of the pluton derived from an enriched lithospheric mantle and emplaced into the crust after differentiation in a deep seated magma chamber contaminated by relatively small proportions of crustal rocks.

Aydınçakır, Emre; Yücel, Cem; Ruffet, Gilles; Gücer, Mehmet Ali; Akaryalı, Enver; Kaygusuz, Abdullah

The debate about whether Eocene magmatism is considered to be post-collisional or subduction-related or not still continues. Here we offer new 40Ar-39Ar ad U-Pb zircon geochronology, mineral chemistry, bulk rock and Sr-Nd-Pb isotope geochemistry data obtained from the southern dike (SD) suite, in comparison with the northern dike (ND) suite, from the Eastern Pontides. The geochronological data indicate that the SD suite erupted between 45.89 and 45.10 Ma corresponding to the Lutetian (Middle Eocene). The magmas of the ND suite are characterised by slightly more alkaline affinity compared to the SD suite. The trace and rare earth element (REEs) content of the SD suite is characterised by large ion lithophile element (LILEs; Sr, K2O, Ba, Rb) enrichment and depletion of Nb, Ta, and TiO2 elements to different degree with high Th/Yb ratios, which indicate that the magmas forming the SD and ND suites were derived from lithospheric mantle sources enriched by mostly slab-derived fluids in the spinel stability field. The Sr, Nd and Pb radiogenic isotope ratios of the dikes support the view that the magma for the hydrous group (H-SD) was derived from a relatively more enriched mantle source than the other SD and ND suites. The ND suite and the anhydrous group (A-SD) display similar geochemical features characterised by moderate light earth element (LREE)/heavy rare earth element (HREE) ratios, while the H-SD group has respectively lower LREE/HREE ratios indicating higher melting degree. Detailed considerations of the alkalinity, enrichment and partial melting degree for the source of the studied volcanic rocks indicate that the magmas of the northern dike suite are characterised by slightly more alkaline affinity, whereas the magmas throughout the southern dike suite show increments in the enrichment rate and melting degree. In light of the obtained data and comparative interpretations, the geodynamic evolution and differences in petrogenetic character of the Lutetian magmas from both the northern and southern parts of the Eastern Pontides may be explained by different degrees of melting of a net veined mantle source initially metasomatized by mostly subduction fluids during asthenospheric upwelling due to fragmented asymmetric delamination in a post-collisional extensional tectonic environment.

Gücer, Mehmet Ali

Early Cenozoic magmatism in the eastern Sakarya Zone (NE Turkey) provides an important constraint on the regional tectono-magmatic evolution of the region. Early Eocene syn-collisional adakitic rocks are observed as small stocks with outcropping areas commonly less than 10 km2. This study presents petrography, whole-rock geochemistry and Sr-Nd-Pb isotope data, as well as in-situ 40Ar/39Ar age constraints on one of these adakitic andesites in the Altınpınar area of Gümüşhane, and discusses source region, petrological processes and geodynamic setting prevailed during their genesis. Andesites commonly show microlitic porphyric and vitrophyric porphyric textures, and include significant amounts of mafic microgranular enclaves (MMEs). Plagioclase, hornblende, Fe-Ti oxides and minor pyroxene are the main mineral phases. In-situ 40Ar-39Ar amphibole dating constrains the cooling age of andesites into a time span from 52.8 ± 1.3–48.8 ± 1.9 Ma. Andesites are medium to high-K calc-alkaline and display most of the signatures typical of those of the adakites. They are characterized by moderate MgO (1.7–4.1 wt%), low Y (9−14 ppm), Yb (0.9–1.5 ppm), and HREE and high Sr (325−964 ppm) contents, and high Sr/Y (36–76) ratios. 87Sr/86Sr(t) (0.704948−0.705100) and 143Nd/144Nd(t) (0.512588−0.512628) ratios are in the isotopic range of the adakites. All these geochemical and isotopic data suggest that the parental magma of adakitic andesites has been produced by partial melting of oceanic basalts under amphibole-eclogite facies conditions during the breakoff of the northern Neotethyan oceanic slab.

Sipahi, Ferkan; Sadiklar, M. Burhan; Şen, Cüneyt

The studied volcanic rocks are footwall and hanging wall dacites from the Murgul mine and the surrounding area. Moreover, the hanging wall dacites contain enclaves. Footwall dacite contains biotite, whereas hanging wall dacitic rocks contain hornblende as a ferromagnesian mineral. The enclaves in the hanging wall dacite have sizes that range from 1cm to 20cm and contain hornblende as a ferromagnesian mineral. The volcanic rocks show tholeiitic and transitional affinities. They are rich in large ion lithophile element and light rare earth element with pronounced depletion of high field strength elements. The chondrite-normalized rare earth element patterns (LaN/LuN=1.47-5.12) show low to medium enrichment, which reveal that the rocks were obtained from similar sources in Murgul volcanic rocks. The initial 87Sr/86Sr values range from 0.70442 to 0.70525, and the initial 143Nd/144Nd values range from 0.512741 to 0.512770. The main solidification processes involved in the evolution of the volcanic rocks consist of fractional crystallization with minor amounts of crustal contamination and magma mixing. All geochemical data support that these rocks originated from andesitic magma, and that the parental magma of the rocks were probably derived from an enriched upper mantle, previously modified by subduction-induced metasomatism in a geodynamic setting.

Eker, Cigdem Saydam; Sipahi, Ferkan; Kaygusuz, Abdullah

Trace elements and rare earth elements (REEs) of Lias-aged cherts in the Gumushane area were studied in order to understand their origin and depositional environment. Twenty three chert samples from five stratigraphic sections were analysed by inductively coupled plasma-mass spectrometry, X-ray diffraction, and mineralogical investigation. Lias cherts in the study area are microcrystalline, cryptocrystalline quartz, and megaquartz depending on mineralogical content. Trace elements of the cherts were compared with PAAS, Co, Y, and Th had stronger depletions in the five sections, whereas V, Ni, Zr, Nb, and Hf had smaller depletions. The distribution of Zr, Hf, and Ta yields Zr/Hf, Zr/Ta and Hf/Ta ratios (25/645, 37/665, and 0.18/3, respectively) that differ from those of chondrites and average upper continental crust, suggesting that these elements are likely non-detrital but are sourced from seawater. Th/U ratios range from 0.04 to 0.45 and are lower than those of the upper continental crust (average: 3.9). Lias-aged cherts have low total REE abundances and stronger depletions in five sections of the PAAS and chondrite-normalised plots. The cherts are characterised by a positive Eu anomaly (average: 4.9) and LREE-enrichment (LaN/YbN=average: 3.5). In addition, about one-half of the cherts exhibit positive Ce anomaly (range: 0.25-2.58), chondritic Y/Ho values (range: 3.3-60), and low (La/Ce)N values (average: 1.8). REE and trace element abundance in Lias cherts indicate that these elements were likely derived from hydrothermal solutions, terrigenous sources, and seawater. The REE patterns of the cherts show that they were probably deposited close to a continental margin.

Kaygusuz, Abdullah; Şen, Cüneyt

The Köprübaşi{dotless} intrusion from the eastern Pontides of NE Turkey consists of granodiorite and monzogranite, and contains a number of mafic microgranular enclaves (MMEs). We report here U-Pb zircon age, geochemical and Sr-Nd isotopic data for these rocks in order to determining magma sources and magma production processes. On the basis of U-Pb zircon sensitive high-resolution ion microprobe dating (SHRIMP), the magma emplacement age of the granodiorite is 79.3±1.4Ma. The rocks of the pluton are calc-alkaline, metaluminous to peraluminous characteristics, and display features of I-type granites. They are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE) with negative Eu anomalies (Eu/Eu*=0.60-0.76), but are depleted in high field strength elements (HFSE). They have small range of 87Sr/86Sr(i) (0.7067-0.7070) and e{open}Nd(i) (-3.2 to -4.4) values. Fractionation of plagioclase, hornblende and Fe-Ti oxides played an important role in the evolution of the Köprübaşi{dotless} intrusion. A relatively shallow intrusion depth (∼2-8km) was estimated from the Al-in-hornblende geobarometry. All these characteristics, combined with the low values of K2O/Na2O, SiO2, Al2O3/(FeOT+MgO+TiO2) and (Na2O+K2O)/(FeOT+MgO+TiO2), suggest an origin by dehydration melting from a metabasaltic lower crustal source.

Kaygusuz, Abdullah; Aydinçakir, Emre

Rocks of the Late Cretaceous Dagbasi Pluton (88-83 Ma), located in the eastern Pontides, include mafic microgranular enclaves (MMEs) ranging from a few centimetres to metres in size, and from ellipsoidal to ovoid in shape. The MMEs are composed of gabbroic diorite, diorite and tonalite, whereas the felsic host rocks comprise mainly tonalite, granodiorite and monzogranite based on both mineralogical and chemical compositions. MMEs are characterized by a fine-grained, equigranular and hypidiomorphic texture. The common texture of felsic host rocks is equigranular and also reveals some special types of microscopic textures, e.g., oscillatory-zoned plagioclase, poikilitic K-feldspar, small lath-shaped plagioclase in large plagioclase, blade-shaped biotite, acicular apatite, spike zones in plagioclase and spongy-cellular plagioclase textures and rounded plagioclase megacrysts in MMEs. Compositions of plagioclases (An33-An60), hornblendes (Mg#=0.77-1.0) and biotites (Mg#=0.61-0.63) of MMEs are slightly distinct or similar to those of host rocks (An12-57; hbl Mg#=0.63-1.0; Bi Mg#=0.50-0.69), which suggest partial to complete equilibration during mafic-felsic magma interactions. The felsic host rocks have SiO2 between 60 and 76 wt% and display low to slightly medium-K tholeiitic to calc-alkaline and peraluminous to slightly metaluminous characteristics. Chondrite-normalized rare-earth element (REE) patterns are fractionated (Lacn/Lucn=1.5-7.3) with pronounced negative Eu anomalies (Eu/Eu*=0.46-1.1). Initial εNd(i) values vary between -3.1 and 1.6, initial 87Sr/86Sr values between 0.7056 and 0.7067. Compared with the host rocks, the MMEs are characterized by relatively high Mg-number of 22-52, low contents of SiO2 (53-63 wt%), low ASI (0.7-1.1) and low to medium-K tholeiitic to calc-alkaline, metaluminous to peraluminous composition. Chondrite-normalized REE patterns are relatively flat [(La/Yb)cn=1.4-3.9; (Tb/Yb)cn=0.9-1.5] and show small negative Eu anomalies (Eu/Eu*=0.63-1.01). Isotope signatures of these rocks (87Sr/86Sr(i)=0.7054-0.7055; εNd(i)=-1.0 to 1.9) are largely similar to the host rocks. Gabbroic diorite enclaves have relatively low contents of SiO2, ASI; high Mg#, CaO, Al2O3, TiO2, P2O5, Sr and Nb concentrations compared to dioritic and tonalitic enclaves. The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, interacted with a crustal melt that originated from dehydration melting of the mafic lower crust at deep crustal levels. The existence of compositional and textural disequilibrium and the nature of chemical and isotopic variation in these rock types indicate that magma mixing/mingling between an evolved mafic and a granitic magma was involved in their genesis. Microgranular enclaves are thus interpreted to be globules of a more mafic magma probably from an enriched lithospheric mantle source. Al-in-amphibole estimates the pluton emplacement at ca. 0.3-3.8 kbar, and therefore, magma mixing and mingling must have occurred at 3.8 kbar or below this level.

Karsli, Orhan

Quaternary Erzincan Volcanics (QEVs) from the Erzincan Basin consist of mega- and pheno-cryst-bearing high-K calc-alkaline dome lavas. Fourteen nearly phenocrystic domes, with a range of basaltic-andesite, andesite, dacite and rhyolite compositions, were emplaced in the North Anatolian Fault Zone. The emplacement ages yielded by the unspiked K-Ar technique range from 102 to 140 ka. The andesitic domes (each less than 3 km in diameter) contain amphibole megacrysts. Amphibole compositions show a linear variation from ferro-edenite, edenite to pargasite from rhyolite to andesite. Pargasitic amphibole megacrysts scattered into the groundmass are very similar in composition to the microlites. All plagioclases are <An53 mol%. Oscillation types are An32-50 whose variations range from 10 to 16 mol% An and have 10-150 μm in thickness. Pre-eruptive conditions, calculated from mega- and pheno-cryst composition, using pyroxene and two oxide thermometers and the Al-in-hornblende barometer, ranged from 918 to 837 °C and 6.6 to 4.3 kbar for andesitic magma, 824-755 °C and 4.6-4.2 kbar for dacitic magma to 803-692 °C and 4.3-3.9 kbar for rhyolitic magma, which correspond to a depth of >10 km for storage region of the crust. The fO2 values vary from -14.25 to -15.35 log units which are plotted just below nickel-nickel oxide (NNO) buffers. The systematic decrease in thermobarometric results from andesite to rhyolite is consistent with a single magma reservoir moving upward through the crust followed by fractional crystallization. Textural and compositional relationships of mega- and pheno-crystic phases suggest that magma mixing, fluid input to the reservoir and fractional crystallization processes, with a small amount crustal contamination play key role in evolution of the QEVs.

Karsli, O.; Aydin, F.; Sadiklar, M.B.

Ikizdere Pluton consists of granite, granodiorite, tonalite, monzonite, quartz monzonite containing pinkish colored K-feldspar megacrysts (KFMs). The crystal sizes of the KFMs range from 1 to 4 cm. The lath-shaped megacrysts are uniformly (i.e., randomly) distributed in the host plutonic rocks and have mafic and felsic inclusions whose crystal sizes are smaller than 1 mm. The crystal inclusions are biotite, slightly annitic in composition with XMg[=Fetot/(Fetot+Mg)]=0.50-0.58, amphibole (magnesio-hornblende, XMg[=Mg/(Mg+Fetot) ]=0.70-0.79), iron-titanium oxide (low titanium magnetit and ilmenite), plagioclase (Ab75-25An65-35) and as minor quartz. The compositions of the KFMs range from Or95Ab5An0 to Or82Ab17An1. BaO contents of the megacrysts increase from core to rim. The mafic and felsic inclusions are compositionally similar those of the host rocks. The chemical and textural features of K-feldspar are typical for megacrysts that grew as phenocrysts in dynamic granitoidic magma systems. The overgrowth of KFMs and mafic magma injections (magma mixing) may be related to temperature, pressure and compositional fluctuations in the magma chamber. Remnant of earlier formed K-feldspar crystals remain in the felsic magma system, while the mafic injection can decompose some earlier precipitated KFMs. The remnant of K-feldspar remaining after mafic injection are overgrown by rapid diffusion of Ba, K and Na elements in liquid phase, during the later stages of crystallization of the host magma.

Aydin, F.; Karsli, O.; Sadiklar, M.B.

The Eocene Zigana Granitoid in the northern zone and the Middle-Upper Eocene Dolek and Saricicek Plutons in the southern zone of the Eastern Pontides (NE-Turkey) consist of different rock series ranging in composition from intermediate to felsic compositions containing from <1% to 9% of biotite. The biotites are Mg-rich (XFe = Fe2+/Fe2+ + Mg) = 0.28 - 0.49) in the southern zone plutons and Mg- to Fe-rich (XFe = Fe2+/Fe2+ + Mg) = 0.33 - 0.78) in the northern zone pluton. They coexist with K-feldspar, plagioclase, quartz, amphibole, pyroxene, low titanium magnetite, minor ilmenite titanite. Biotites have been buffered by the Ni-NiO. The plutons equilibrated under low oxygen fugacities (LogfO2) ranging from -16.01 to -20.23 bars for Dolek and Saricicek, and -16.70 to -17.90 bars for Zigana. EPMA indicate that the composition of biotite is related to the mineral assemblages of Dolek, Saricicek and Zigana biotites as a consequence of chemistry of the magma and the physical conditions during crystallization. The biotite compositions were used to discriminate the tectonic setting of the plutons. The intrusions appear to be related to calc-alkaline to high-K calc-alkaline orogenic suites. Furthermore, Mg(6)-Fetot substitution has played a significant role during the crystallization of the biotites.