Synthesis, characterization, and thermal-magnetic evaluation of novel triazine-derived polyamides and their metal complexes

In this work, novel triazine-containing polyamide derivatives possessing thermal stability and magnetic properties were synthesized. The synthesis process involves two steps: first, the chlorination of adipic acid and succinic acid using thionyl chloride; and second, the amidation of triazine. As a result of these procedures, two different triazine-containing polyamides were synthesized. The synthesized polyamides formed complexes with Ag, Cu, and Zn ions to enhance their thermal stability and magnetic properties.The structures of the synthesized polyamides were elucidated primarily by FTIR analysis, focusing on distinctive bands corresponding to the carbonyl group. The molecular structures of the polyamides were confirmed using 1H NMR and 13C NMR spectroscopy. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDX) was employed to obtain information on the morphology and elemental composition of the samples. In addition, X-ray diffraction (XRD) analysis was performed to characterize the crystal structures, unit cell parameters, and orientations of the solid-state metal complexes. The thermal stability of both the polyamides and their metal complexes was investigated using thermogravimetric analysis (TGA). The magnetization of the synthesized compounds was measured as a function of temperature under zero-field-cooled (ZFC) and field-cooled (FC) conditions using a physical property measurement system (PPMS).