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- MakaleAçık Erişim2014Trace/heavy metal accumulation in soil and in the shoots of acacia tree, Gümüşhane-Turkey
Vural, Alaaddin
In this study, heavy metal/trace element accumulation was investigated in soils along the road passing through Gümüshane city center and shoots of 1-2 years of acacia trees (Robinia pseudoacacia L.) grown in these soils. Heavy metal contents in soils and plants were analyzed by Enrichment Factor (EF), Geo-accumulation index (Igeo) parameters, and by Bio Accumulation Factor (BAF), respectively. According to geo-accumulation index (Igeo) data, it is seen that the soil was unpolluted in terms of Cr, Co, Cu, Rb, Sr; unpolluted to moderately polluted in terms of V, Ni and Zn; moderate to excessively polluted in terms of As, and moderate to excessively polluted in terms of Pb. According to EF parameters, on the other hand, it is observed that the soil was non to slightly enriched in terms of Cr, Co, Sr and Ba; non to moderately enriched in terms of Ni and Cu; slightly to significantly enriched in terms of Zn; significant to very highly enriched in terms of As and slightly to over excessively enriched in terms of Pb. Although trace/heavy metal contents of acacia shoots were usually within normal values for acacia, it was determined that Cu, Fe, Mo, Ni, Sr and Zn concentrations were within and/or above upper limits of normal values in certain sampling points.
AtıfScopus11OpenAlex11İncele
- MakaleYalnız künye2012Scopus SJRQ2Trace and rare earth elements as indicators of provenance and depositional environments of Lias cherts in Gumushane, NE Turkey
Eker, Cigdem Saydam; Sipahi, Ferkan; Kaygusuz, Abdullah
Trace elements and rare earth elements (REEs) of Lias-aged cherts in the Gumushane area were studied in order to understand their origin and depositional environment. Twenty three chert samples from five stratigraphic sections were analysed by inductively coupled plasma-mass spectrometry, X-ray diffraction, and mineralogical investigation. Lias cherts in the study area are microcrystalline, cryptocrystalline quartz, and megaquartz depending on mineralogical content. Trace elements of the cherts were compared with PAAS, Co, Y, and Th had stronger depletions in the five sections, whereas V, Ni, Zr, Nb, and Hf had smaller depletions. The distribution of Zr, Hf, and Ta yields Zr/Hf, Zr/Ta and Hf/Ta ratios (25/645, 37/665, and 0.18/3, respectively) that differ from those of chondrites and average upper continental crust, suggesting that these elements are likely non-detrital but are sourced from seawater. Th/U ratios range from 0.04 to 0.45 and are lower than those of the upper continental crust (average: 3.9). Lias-aged cherts have low total REE abundances and stronger depletions in five sections of the PAAS and chondrite-normalised plots. The cherts are characterised by a positive Eu anomaly (average: 4.9) and LREE-enrichment (LaN/YbN=average: 3.5). In addition, about one-half of the cherts exhibit positive Ce anomaly (range: 0.25-2.58), chondritic Y/Ho values (range: 3.3-60), and low (La/Ce)N values (average: 1.8). REE and trace element abundance in Lias cherts indicate that these elements were likely derived from hydrothermal solutions, terrigenous sources, and seawater. The REE patterns of the cherts show that they were probably deposited close to a continental margin.
AtıfScopus60WoS58OpenAlex62İncele

