Sürdürülebilir Kalkınma Amaçları
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- MakaleAçık Erişim2024Scopus SJRQ3The potential toxic element contents of Berriasian–Aptian carbonate rocks: distribution of elements in dolomite and limestone and possible sources (Gümüşhane/NE Türkiye)
Eker, Çiğdem Saydam; Arı, Uğur Volkan
The aim of this study is to determine the potential toxic element (PTE) content linked to the geochemical features of Berriasian–Aptian carbonate rocks commonly outcropping in Gümüşhane, along with the degree of pollution and possible sources of these toxic elements, and to compare dolomite with limestone in terms of toxic metal abundance. In the field, dolomite and limestone samples were collected by measuring stratigraphic sections around Yuvacık, Ünlüpınar, Çukutbaşı, Bağlarbaşı, Mescitli and Gülaçar (Gümüşhane). The samples were analyzed using inductively coupled plasma mass spectroscopy (ICP-MS). The mean values for Mo, Cu, Pb, Zn, Ni, As, and Co were 3.1, 23.8, 7.1, 14.5, 13.5, 30.9, and 8 mg/kg in Yuvacık; 6, 2.3, 1.1, 3.5, 8.1, 12.3 and 2.5 mg/kg in Ünlüpınar; 17.9, 1.8, 1.5, 8.6, 7.9, 13.9 and 1.7 mg/kg in Çukutbaşı; 3.7, 6.5, 31.7, 82.7, 9.5, 32.0 and 1.9 mg/kg in Bağlarbaşı; 0.7, 0.7, 7.1, 21.3, 2.6, 11.8 and 0.7 mg/kg in Mescitli; and 1.2, 1.1, 2.4, 5.2, 1.3, 4.0 and 0.2 mg/kg in Gülaçar, respectively. According to geochemical pollution parameters [geo-accumulation (Igeo), pollution index (Pi), and pollution load index (Pln)], the rocks were generally significantly polluted by Mo and As, without notable pollution by the other elements. Limestone samples from the Yuvacık, Ünlüpınar, and Çukutbaşı areas were more polluted in terms of Mo and As compared to dolomites. This pollution in Yuvacık and Ünlüpınar was identified to have geogenic sources (Pb–Zn–Cu mineralization) and in Çukutbaşı was identified to have lithogenic sources. Dolomites from the Bağlarbaşı area were more polluted in terms of As and less polluted in terms of Mo compared to limestones. In the Mescitli location, both dolomites and limestones were occasionally polluted in terms of As, while limestones were polluted in terms of Mo. In these two areas, the sources of As and Mo are geogenic (Pb–Zn mineralization), In Gülaçar, dolomites were more polluted in terms of Mo and less polluted in terms of As compared to limestones. In this locality, As and Mo are thought to have a geogenic source (Pb–Zn–Cu mineralization).
AtıfScopus6WoS6OpenAlex4
İncele - MakaleYalnız künye2015Scopus SJRQ1Assessment of metal pollution associated with an alteration area: Old Gümüşhane, NE Black Sea
Vural, Alaaddin
The objective of this study was to determine the potential environmental risks associated with the Kirkpavli (Old Gümüşhane in northern Turkey) alteration area by quantifying pollution in soil. The Kirkpavli (Old Gümüşhane) alteration area is situated at the south of the deposit with the same name of gold-silver-bearing lead, zinc, and copper in the southern part of the Black Sea Tectonic Unit (Eastern Pontides). In this study, 28 soil samples acquired from the alteration area were analyzed for contents of some main elements including lead (Pb), copper (Cu), zinc (Zn), cadmium (Cd), cobalt (Co), manganese (Mn), nickel (Ni), and arsenic (As). Contents of the elements in the area were determined, and high values were obtained such as 1,171 mg/kg for As, 12.4 mg/kg for Cd, 77.3 mg/kg for Co, 341 mg/kg for Cu, 1,172 mg/kg for Mn, 51.9 mg/kg for Ni, 3,725 mg/kg for Pb, and 880 mg/kg for Zn. Soil contamination was appraised on the basis of Geoaccumulation Index (Igeo), Enrichment Factor (EF), Pollution Index, and Integrated Pollution Index. The calculated results of Igeo, EF, and PI of the elements can be shown in descending order of parameters as As > Pb > Cd > Zn > Cu > Co > Mn. The parameters for some of these elements indicated extremely high contamination (Igeo > 5), extremely high enrichment (EF > 40), and high pollution (PI > 3). High Igeo, EF, and PI values of As, Pb, and Cd in the soil samples mean that soil pollution is typically associated with alteration area. Considering its location and the results of this study, the Kirkpavli alteration area is a significant source of pollution and may have ecotoxicological effects on terrestrial, groundwater, and aquatic ecosystems in the region.
AtıfScopus24WoS26OpenAlex30
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