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Mild conditions for oxidation/epoxidation of styrene

MakaleAçık Erişim

Özet

In this study, in order to obtain novel support materials for immobilization of transition metals, polymeric Schiff bases were synthesized using a poly-condensation reaction between ortho(o-)phthalaldehyde tere(t-)phthalaldehyde, oxaldehyde and diamines like, e.g., ethylene-p- phenylene- and o-phenylenediamine. Additionally, catalytic activity of polymeric Schiff base metal on oxidation/epoxidation of styrene complexes were investigated. The products have been characterized on the basis of analytical and spectral method, Fourier transform infrared spectroscopy, 1H- and 13C-nuclear magnetic resonance, gel-permeation chromatography, elemental analysis, thermogravimetric analysis, atomic adsorbtion spectrometry, gas chromatography and gas chromatography mass spectrometry.

Anahtar Kelimeler

catalytic activityoxidationSchiff basestyrene
RDL Kalıcı Bağlantı (PID)
https://rdlopen.rawdatalibrary.net/r/gumushane/15548Resmi atıflarda kullanılan kalıcı adres
DOI
https://doi.org/10.1163/156855511x598641Yayıncı resmi DOI adresi
Tam Kayıt
AlanDeğerDil
dc.contributor.authorKazanci, A.
dc.contributor.authorSaribiyik, O.Y.
dc.contributor.authorSerin, S.
dc.date.accessioned2026-10-22T10:24:10.451135246Z
dc.date.available2026-10-22T10:24:10.451135246Z
dc.date.issued2011
dc.description.abstractIn this study, in order to obtain novel support materials for immobilization of transition metals, polymeric Schiff bases were synthesized using a poly-condensation reaction between ortho(o-)phthalaldehyde tere(t-)phthalaldehyde, oxaldehyde and diamines like, e.g., ethylene-p- phenylene- and o-phenylenediamine. Additionally, catalytic activity of polymeric Schiff base metal on oxidation/epoxidation of styrene complexes were investigated. The products have been characterized on the basis of analytical and spectral method, Fourier transform infrared spectroscopy, 1H- and 13C-nuclear magnetic resonance, gel-permeation chromatography, elemental analysis, thermogravimetric analysis, atomic adsorbtion spectrometry, gas chromatography and gas chromatography mass spectrometry.
dc.identifier.doi10.1163/156855511x598641
dc.identifier.eissn1568-5551
dc.identifier.endpage570
dc.identifier.issn1568-5551
dc.identifier.issue6
dc.identifier.scopus2-s2.0-80055073239
dc.identifier.startpage559
dc.identifier.urihttps://rdlopen.rawdatalibrary.net/r/gumushane/15548
dc.identifier.volume14
dc.identifier.wosWOS:000297806300003
dc.language.isoen
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofDesigned Monomers and Polymers
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectcatalytic activity
dc.subjectoxidation
dc.subjectSchiff base
dc.subjectstyrene
dc.subject.classificationPolymer Science
dc.subject.otherAtomic spectroscopy
dc.subject.otherCatalyst activity
dc.subject.otherCatalytic oxidation
dc.subject.otherCondensation reactions
dc.subject.otherEthylene
dc.subject.otherFourier transform infrared spectroscopy
dc.subject.otherFunctional groups
dc.subject.otherMass spectrometry
dc.subject.otherNuclear magnetic resonance spectroscopy
dc.subject.otherPolymers
dc.subject.otherResonance
dc.subject.otherStyrene
dc.subject.otherThermogravimetric analysis
dc.subject.otherTransition metals
dc.subject.otherGas chromatography-mass spectrometry
dc.subject.otherO-Phenylenediamine
dc.subject.otherPhthalaldehyde
dc.subject.otherSchiff Base metals
dc.subject.otherSchiff basis
dc.subject.otherSchiff-base
dc.subject.otherSpectral methods
dc.subject.otherSupport materials
dc.subject.otherGas chromatography
dc.titleMild conditions for oxidation/epoxidation of styrene
dc.typeArticle
dspace.entity.typePublication
rdl.citation.openalex2
rdl.citation.scopus3
rdl.citation.wos3
rdl.oa.statusbronze
rdl.oa.urlhttps://www.tandfonline.com/doi/pdf/10.1163/156855511X598641?needAccess=true&role=button
rdl.source.indexSCOPUS
rdl.source.indexWOS
rdl.wos.indexScience Citation Index Expanded (SCI-EXPANDED)