Sürdürülebilir Kalkınma Amaçları
Yazarlar
Yayınlar
- MakaleAçık Erişim2025Scopus SJRQ2Investigation of Tensile and Fatigue Behavior of Cr/CrN/TiCrN/TiCrCN Multilayer Films Coated on AA6063 and AZ91 Alloys by Closed-Field Unbalanced Magnetron Sputtering Process
Yeşildal, Ruhi; Sezer, Sadberk; Karabudak, Filiz
Despite the widespread use of Mg and Al alloys among light metals in the automobile and aviation industries, they have low tensile and fatigue strength. Therefore, in the present work, AZ91 Mg and AA6063 Al alloys were coated with a multilayer transition metal nitride film (Cr/CrN/TiCrN/TiCrCN) to increase fatigue and tensile strength. Films with Cr/CrN/TiCrN/TiCrCN microstructure architecture were synthesized on the surfaces of AZ91 Mg and AA6063 Al alloys using the CFUBMS (closed-field unbalanced magnetron sputtering) system, one of the PVD (physical vapor deposition) techniques. Films’ structural properties were analyzed by XRD, SEM, and EDAX, whereas mechanical properties were investigated using tensile and rotary bending fatigue testing machines. According to the SEM examination, the Cr, CrN, TiCrN, and TiCrCN multilayer nitride films on the two alloys have a columnar and dense microstructure. The XRD analysis detected Cr (211), CrN (111) and (200), TiN (111), (200) and (222), and TiCN (200) and (311) diffraction peaks. The Cr/CrN/TiCrN/TiCrCN multilayer coating increased the fatigue limit value of AZ91 by 11.22% from 70.26 MPa to 78.15 MPa. The fatigue limit value of AA6063 decreased by 9.79% from 79.71 MPa to 71.9 MPa. After coating, the tensile strength value of AZ91 increased from 137.89 MPa to 139.65 MPa, while the tensile strength of AA6063 decreased from 129.35 MPa to 118.16 MPa.
AtıfScopus2WoS2OpenAlex2
İncele - MakaleYayıncıda açık erişim2022Scopus SJRQ1Technical potential of rooftop solar photovoltaic for Ankara
Kutlu, Elif Ceren; Durusoy, Beyza; Ozden, Talat; Akinoglu, Bulent G.
Turkey, which has immense solar potential, has recently shifted towards solar energy and new renewable energy deployment regulations, including implementation and commercializing rooftop PV technologies. Thus, these require a detailed assessment to determine the power source's capability and convince the policymakers. To the authors' best knowledge, there is no available data or a city-based study for the rooftop PV potential in Turkey. Here, we present the first city-based rooftop PV potential study in Ankara. The technical PV potential calculations are sensitive to the suitable area ratio, module efficiency, and module area assumptions. This study proposes a new, free, reliable, and open-source model for estimating the rooftop PV potential, and it is adaptable to every roof type. The suitable roof area for PV panels is calculated using Helioscope software. Five different modules with different efficiencies and module sizes are modelled in Helioscope. The results showed that Ankara's total technical PV potentials for residential, public, and commercial buildings are 1.15 TWh/year, 55 GWh/year, and 26.8 GWh/year, respectively. Best results are obtained by Mono-Si Halfcut (M2) and Thin Film (M5) modules in residentials, M2 and Mono-Si Bifacial Modules (M3) in Public and Commercial Buildings.
AtıfScopus31WoS28OpenAlex33İncele - MakaleAçık Erişim2014Scopus SJRQ3Synthesis and spectral and thermal characterization of new metal-free and metallophthalocyanines: Investigation of their photophysical, photochemical, and thin film properties
Kaya, Elif Çelenk; Durmuş, Mahmut; Yanmaz, Ekrem; KantekiN, Halit
Novel tetrasubstituted metal-free (2), zinc (II) (3), cobalt (II) (4), and copper (II) (5) phthalocyanines bearing 2-phenylethanolate groups on the peripheral positions were synthesized by the cyclotetramerization reaction of the phthalonitrile derivative 1. The new compounds were characterized by a combination of IR, 1H NMR, 13 C NMR, UV-Vis, elemental analysis, and MS spectra data. The thermal stabilities of the phthalocyanine compounds were determined by thermogravimetric analysis. For metal-free (2) and zinc (3) phthalocyanines, photochemical (photodegradation and singlet oxygen quantum yields) and photophysical (fluorescence quantum yields and fluorescence lifetimes) properties were analyzed in dimethylsulfoxide (DMSO). The cobalt (4) and copper (5) phthalocyanines were not evaluated for this purpose because of their paramagnetic behavior. The metal-free (2) and zinc (3) phthalocyanines' fluorescence quenching behaviors were also investigated. The new phthalocyanine compounds' fluorescence emissions were effectively quenched by 1,4-benzoquinone in DMSO. The thin films of the cobalt phthalocyanine compound (4) were grown by electron beam evaporation technique. Crystalline CoPc (4) thin films were investigated by X-ray diffraction spectroscopy. Surface morphology of the CoPc (4) thin films was characterized by SEM.
AtıfScopus13WoS11OpenAlex15
İncele