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- MakaleAçık Erişim2022Scopus SJRQ1Late Jurassic Paleotethyan oceanic slab break-off revealed by Sr-Nd-Hf isotopes of Na-rich adakitic granites from northwestern Turkey
Karsli, Orhan; Şengün, Fırat; Santos, José Francisco; Uysal, İbrahim; Dokuz, Abdurrahman; Aydin, Faruk; Kandemir, Raif
The Mesozoic geodynamic evolution of the Paleotethys Ocean is critical but a poorly known piece of the geological history of the Sakarya Zone, north Turkey. Here, we describe new integrated research of zircon U-Pb geochronology, bulk-rock major-trace element and Sr–Nd isotopes as well as Hf isotope of zircons from the granitic rocks of the Demirköy and Kızıldamlar plutons located in Bilecik area along the western Sakarya Zone, northwestern Turkey. Zircon U–Pb ages obtained by LA-ICP-MS reveal that the granitic magma intruded into the basement rocks during the Late Jurassic (ca. 162–157 Ma). The granites are tholeiitic and show slightly metaluminous to peraluminous geochemical affinities. The granite samples are adakitic, having relatively high Na2O (6.35–7.58 wt%) and Sr (172–580 ppm), and low K2O (0.39–1.13 wt%) and Y (3.2–5.3 ppm), and thus have high Sr/Y (70–250). The samples exhibit enrichment of light rare earth elements (REE) and large ion lithophile elements (LILE) and depletion in heavy REE and the high field strength elements (HFSE; e.g., Nb, Ti, Ta). The samples possess low 87Sr/86Sr(t) values of 0.70313 to 0.70372, and εNd(t) of −0.66 to +9.24. Zircon grains exhibit positive εHf (t) values of 5.0 to 12.8 and depleted mantle model ages of Hf (TDM1 = 0.24 to 0.68 Ga). These geochemical features and Sr–Nd–Hf radiogenic isotope systematics reveal that the adakitic rocks were likely formed by low degree melting (<10%) of the eclogitic part of an oceanic slab and subsequent melt fractionation and crustal contamination. An ongoing subduction scenario cannot explain the formation of the investigated adakitic rocks. We suggest that the adakitic plutons were generated through slab break-off after the final closure of the Paleotethys Ocean throughout the Late Jurassic (ca. 162–157 Ma). Considering the previous data, the continental back-arc basin system, leading to the opening of Neotethys Ocean at the southern margin of the continent, has been put forward to decipher the Late Jurassic tectonic evolution of the Paleotethys Ocean and the western Sakarya Zone.
AtıfScopus14WoS14OpenAlex13
İncele - MakaleAçık Erişim2020Scopus SJRQ1Tracking the timing of Neotethyan oceanic slab break-off: Geochronology and geochemistry of the quartz diorite porphyries, NE Turkey
Karsli, Orhan; Dokuz, Abdurrahman; Aydin, Faruk; Uysal, Ibrahim; Sengün, Firat; Kandemir, Raif; Santos, Jose Francisco; Andersen, Tom
The initiation of the break-off of the northern branch of the Neotethyan oceanic lithosphere is an important but poorly understood event in the geology of the Sakarya Zone (SZ) in northeastern Turkey. Although it is wellknown that Latest Cretaceous intrusives (-70 Ma) and early Eocene adakitic magmatic rocks are present in the eastern SZ, the outcrops of the early Eocene non-adakitic rocks are very limited, and their tectono-magmatic evolution has not been studied. We describe a small outcrop of non-adakitic quartz diorite porphyry in the Kov area of the Gumushane region in northeastern Turkey. The genesis of these porphyries is significant in evaluating the syn-to post-collision-related magmatism. The LA-ICP-MS zircon U-Pb dating revealed that the Kov quartz diorite porphyries (KQDP) formed at ca. 50 Ma, coeval with adakitic rocks, and-20 Myr later than the slab rollback-related intrusive rocks. The KQDPs are calc-alkaline in composition and enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depleted in high field strength elements (HFSEs; e.g., Nb, Ta, Ti), with significant negative anomalies of Nb, Ta, and Ti but positive anomalies of Th, U, and Pb. Isotopic compositions of the samples show limited range of variation and slight enrichment of 87Sr/86Sr(t) (0.70489 to 0.70555), epsilon Nd(t) (-1.4 to -1.2) with TDM of 1.11 to 1.61 Ga. Pb isotopic ratios of the samples point to an enriched mantle source. They were likely crystallized from the melt that originated from an EM2-type spinel-facies subcontinental lithospheric mantle (SCLM), followed by the fractionation with insignificant crustal assimilation. The SCLM was metasomatically enriched, and the metasomatic agent was likely H2O-rich fluids rather than sediments released from subducting oceanic crust during the Late Cretaceous closure of the Neotethyan oceanic lithosphere. In conjunction with the geological background and previous data, we propose that the generation of the KQDPs resulted from a slab break-off event that caused ascending or infiltration of hot asthenosphere, triggering mantle melting. Such sporadic occurrences of the KQDPs, with coeval adakitic rocks in the SZ, are likely associated with the onset of extensional tectonics due to the earlier stage of slab break-off along the region during the early Eocene period.
AtıfScopus6WoS6OpenAlex7İncele - MakaleYalnız künye2014Scopus SJRQ1The petrogenesis of Early Eocene non-adakitic volcanism in NE Turkey: Constraints on the geodynamic implications
Aydinçakir, Emre
Whole-rock geochemistry, mineral chemistry, the 40Ar-39Ar age, and Sr-Nd isotopic data are presented for the Early Eocene non-adakitic volcanic rocks on the eastern corner of the Eastern Pontides orogenic belt (NE Turkey). The tectonic setting of the Eastern Pontides during the Late Mesozoic to Early Cenozoic remains a topic of debate. Here, for the first time, we describe the Early Eocene non-adakitic volcanic rocks from the Eastern Pontides. These rocks contain plagioclase, hornblende phenocrysts, and magnetite/titanomagnetite and apatite microphenocrysts. Geochronology studies based on the 40Ar-39Ar ratio of the amphibole separates reveal that the non-adakitic porphyritic volcanic rocks have a crystallization age of 50.04±0.10 to 50.47±0.22Ma (Ypresian). The volcanic rocks show tholeiitic to calc-alkaline affinities and have low-to-medium K contents. They are also enriched in large-ion lithophile elements (LILE), light rare-earth elements (LREE), and depleted in high field strength elements (HFSE), with a no negative Eu anomaly (Eun/Eu*=1.03-1.08) in mantle-normalized trace element spidergrams. The samples (Lacn/Lucn=2.60-4.28) show low-to-medium enrichment in LREEs relative to HREEs, in chondrite-normalized REE patterns indicating similar sources for the rock suite. These rocks display a range of ISr (50Ma) values from 0.70451 to 0.70485, and E{open}Nd (50Ma) 2.9 and 3.7. The main solidification processes involved in the evolution of these volcanics consist of fractional crystallization, with minor amounts of crustal contamination. All of our evidence supports the conclusion that the parental magma of the rocks probably derived from an enriched mantle, previously metasomatized by fluids derived from the subducted slab, in a post-collisional, geodynamic setting.
AtıfScopus58WoS53OpenAlex55İncele - MakaleYalnız künye2010Scopus SJRQ1Late Cretaceous high-K volcanism in the eastern Pontide orogenic belt: Implications for the geodynamic evolution of NE Turkey
Eyüboǧlu, Yener
High-K volcanics were produced in two different Late Cretaceous cycles during the infilling of back-arc basins of the eastern Pontides. The first cycle, represented by shoshonitic trachyandesites and associated pyroclastics, containing high K2O (2.74-4.81 wt-%) and NaK2O (3.60-5.51 wt-%), overlies a mid-Cretaceous ophiolitic-olistostromal melange formed during the rifting stage of a back-arc basin (Neotethys). 40Ar39Ar dating of biotite from trachyandesite at the base of the first cyle indicates that shoshonitic volcanism in the far south of the eastern Pontides started in the early Campanian. Volcanic rocks of this cycle are overlain by upper Campanian-Maastrichtian rudist-bearing reefal limestones. The second cycle of high-K volcanism is represented by analcime-bearing volcanic rocks erupted in a Neotethyan lagoonal environment. These volcanic rocks, intercalated with continental detritus, are characterized by high a2O (3.22-7.16 wt-%), now concentrated in secondary analcime crystals. Their K2O contents also range between 0.83 and 6.05 (wt-%). All of these units are disconformably overlain by Eocene turbidites with a basal conglomerate. Volcanic rocks belonging to both cycles show various enrichment degrees in LILE, HFSE, LREE, and HREE with respect to primitive mantle and chondrite [(La/Lu) cn=11.10-25.89]. Negative Nb, Ta, Zr, Hf, and Ti anomalies are typical of these subduction-related arc magmas. Geochemical similarities between the two volcanic cycles suggest that trachyandesites and analcime-bearing volcanics were derived from similar enriched mantle sources, and that they formed in the same geotectonic setting of a back-arc basin environment of the eastern Pontide magmatic arc during the Late Cretaceous. In addition, Nd-Sr and Pb isotope ratios of the investigated volcanic units indicate that their mantle melt sources were similar. The new geological, geochemical and isotopic data suggest that southward subduction of the Palaeotethyan oceanic crust can be separated into two main stages for the late Mesozoic Pontide orogenic belt. Early southward subduction ended by slab break-off during the mid-Cretaceous, resulting in upwelling and injection of asthenospheric mantle that caused the opening of the eastern Pontide back-arc basin (Neotethys). Resumption of southward subduction began with intense TH-CA bimodal volcanism in the northern front of the arc during the Turonian-Coniacian. The intensity of this Late Cretaceous magmatism in the north decreased towards the south, and a transition to monogenic calcalkaline-alkaline (CA-A) Campanian andesitic volcanism developed in the southern zone. Yet farther south, andesitic igneous activity graded into the Campanian-Maastrichtian shoshonitic and ultrapotassic volcanism in the Bayburt-Maden, Tokat, Amasya, and Gümüshaciköy areas. This zoning of the Late Cretaceous arc magmatism (TH-CA, CA-A and shoshonitic-ultrapotassic, from north to south) also supports the concept of southward subduction during late Mesozoic evolution of the eastern Mediterranean region.
AtıfScopus120WoS110OpenAlex117İncele