Karsli, Orhan; Şengün, Fırat; Santos, José Francisco; Uysal, İbrahim; Dokuz, Abdurrahman; Aydin, Faruk; Kandemir, Raif

The Mesozoic geodynamic evolution of the Paleotethys Ocean is critical but a poorly known piece of the geological history of the Sakarya Zone, north Turkey. Here, we describe new integrated research of zircon U-Pb geochronology, bulk-rock major-trace element and Sr–Nd isotopes as well as Hf isotope of zircons from the granitic rocks of the Demirköy and Kızıldamlar plutons located in Bilecik area along the western Sakarya Zone, northwestern Turkey. Zircon U–Pb ages obtained by LA-ICP-MS reveal that the granitic magma intruded into the basement rocks during the Late Jurassic (ca. 162–157 Ma). The granites are tholeiitic and show slightly metaluminous to peraluminous geochemical affinities. The granite samples are adakitic, having relatively high Na2O (6.35–7.58 wt%) and Sr (172–580 ppm), and low K2O (0.39–1.13 wt%) and Y (3.2–5.3 ppm), and thus have high Sr/Y (70–250). The samples exhibit enrichment of light rare earth elements (REE) and large ion lithophile elements (LILE) and depletion in heavy REE and the high field strength elements (HFSE; e.g., Nb, Ti, Ta). The samples possess low 87Sr/86Sr(t) values of 0.70313 to 0.70372, and εNd(t) of −0.66 to +9.24. Zircon grains exhibit positive εHf (t) values of 5.0 to 12.8 and depleted mantle model ages of Hf (TDM1 = 0.24 to 0.68 Ga). These geochemical features and Sr–Nd–Hf radiogenic isotope systematics reveal that the adakitic rocks were likely formed by low degree melting (<10%) of the eclogitic part of an oceanic slab and subsequent melt fractionation and crustal contamination. An ongoing subduction scenario cannot explain the formation of the investigated adakitic rocks. We suggest that the adakitic plutons were generated through slab break-off after the final closure of the Paleotethys Ocean throughout the Late Jurassic (ca. 162–157 Ma). Considering the previous data, the continental back-arc basin system, leading to the opening of Neotethys Ocean at the southern margin of the continent, has been put forward to decipher the Late Jurassic tectonic evolution of the Paleotethys Ocean and the western Sakarya Zone.

Karsli, Orhan; İlhan, Mehdi; Kandemir, Raif; Dokuz, Abdurrahman; Aydin, Faruk; Uysal, İbrahim; Duygu, Levent

Late Mesozoic evolution of the Neotethys Ocean is critical and still remains unclear along the entire Sakarya Zone (SZ), Turkey, because previous interpretations of the Middle to Late Jurassic rifting of the SZ have not been consensually accepted. We identified, for the first time, the Early Cretaceous dykes intruded into the Late Jurassic and Late Carboniferous bodies in the Çamlıkaya (Erzurum) area in the SZ. Here, we present a data set of new field observations, 40Ar/39Ar geochronology, whole-rock geochemical and Sr–Nd isotopes to find out the tectonic setting of previously undated basic to intermediate igneous rocks. 40Ar/39Ar technique on the groundmass separations yielded the plateau ages of 128.78 ± 1.02 to 122.89 ± 0.82 Ma. The investigated dykes are compositionally divided into two sub-groups: calc-alkaline lamprophyres (CAL) and high-Nb alkaline basalts (HNB). They show enrichment in large ion lithophile elements (LILE: e.g., Rb, Ba, K) and depletion in high field strength elements (HFSE: Nb and Ti) as well as moderate fractionation of light rare earth elements relative to heavy rare earth elements. The HNB have high Mg# (47–66), and relatively unradiogenic Sr [87Sr/86Sr(t) = 0.70385 to 0.70510] and Nd [εNd(t) = +0.5 to +5.3] isotopic composition, whereas the CAL possess moderate to high Mg# (32–72), and relatively high Sr [87Sr/86Sr(t) = 0.70586 to 0.71379] and Nd [εNd(t) = +1.5 to −9.9] isotopic composition. Early Cretaceous high-angle subduction triggered upwelling of the asthenosphere at 126 Ma, which likely generated a heat anomaly. This anomaly has probably induced melting of the oceanic slab and the metasomatized mantle to form the CAL and HNB. The HNB were generated by low degrees of melting of mantle domain that was previously reacted by oceanic slab-related adakitic melts at the depths of the garnet stability field (≥70 km). However, the CAL were probably formed at shallower mantle levels within the garnet-amphibole field by a relatively higher degree of melting of the mantle, also modified by subducted slab sediments. A new field, age, and petrochemical data from the Early Cretaceous dykes, combined with the presence of Aptian deep-water sediments to the north and the Late Jurassic-Early Cretaceous platform carbonates deposited in the passive margin setting along the entire SZ, imply the initiation of active-margin magmatism in the SZ. We suggest that the coexistence of the Early Cretaceous CAL and HNB points to the formation of an Andean-type active margin above a north-dipping Neotethyan oceanic slab. Their emplacement ages are associated with the inception of the magmatic arc structure and refer to a significant geodynamic turnover from passive-margin to active-margin tectonics along the SZ.

Aydin, Faruk; Oğuz Saka, Simge; Şen, Cüneyt; Dokuz, Abdurrahman; Aiglsperger, Thomas; Uysal, İbrahim; Kandemir, Raif; Karslı, Orhan; Sarı, Bilal; Başer, Rasim

The Late Cretaceous Artvin volcanic rocks (LCAVs) from the eastern Sakarya zone (ESZ) of NE Turkey are composed of mafic/basaltic (S1-Çatak and S2-Çağlayan) and felsic/acidic (S1-Kızılkaya and S2-Tirebolu) rock types that occurred in two successive stages: (i) first stage (S1: Turonian–Early Santonian) and (ii) second stage (S2: Late Santonian–Campanian). Clinopyroxene thermobarometric results point that the S2-Çağlayan basaltic rocks have crystallised at higher temperatures and under deeper crustal conditions than those of the S1-Çatak basaltic rocks. The LCAVs show a wide compositional spectrum, ranging from tholeiite to calc-alkaline/shoshonite and are typically represented by a geochemical composition resembling subduction-related arc rocks although the 87Sr/86Sr(i) (0.7044–0.7071) and ɛNd(i) values (−0.63 to + 3.47) as well as 206Pb/204Pb(i) (18.07–18.56), 207Pb/204Pb(i) (15.57–15.62) and 208Pb/204Pb(i) (37.12–38.55) ratios show very limited variation. The parent magmas of the S1-Çatak and S2-Çağlayan mafic volcanic rocks were derived from underplated basaltic melts that originated by partial melting of metasomatised spinel lherzolite and spinel-garnet lherzolite, respectively. It is proposed that the compositions of the S1-Kızılkaya (mainly dacitic) and S2-Tirebolu (rhyolitic to trachytic) felsic rocks were particularly controlled by metasomatised mantle–crust interaction and MASH zone + shallow crustal fractionation processes. Our data, together with data from previous studies, suggest that the S1- and S2-mafic and felsic rocks of the LCAVs (~95–75 Ma) are the products of two-stage volcanic event that took place during the northward subduction of the northern Neotethys Ocean (NNO).

Dokuz, İbrahim; Uysal, İbrahim; Karsli, Orhan; Kandemir, Raif

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Uysal, İbrahim; Dokuz, Abdurrahman; Karsli, Orhan; Aydın, Faruk; Kandemir, Raif

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Wijbrans, Jan; Uysal, İbrahim; Chen, Bın; Karsli, Orhan; Erduran, Murat; Boztuğ, Durmuş; Kandemir, Raif

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