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- MakaleAçık Erişim2023Scopus SJRQ2Adsorptive removal of Cr(VI) and Cu(II) ions from aqueous solutions by a natural moss
Ozeken, Sengul Tugba; Ozdes, Duygu; Duran, Celal
The aim of the present research is to develop a new, fast, and easily applicable adsorption method for the removal of hazardous Cr(VI) and Cu(II) ions from the polluted industrial wastewater by using Racomitrium ericoides (Brid.) Brid. (REB), a type of moss. Although there are studies in the literature in which different moss species were used for the removal of heavy metals (HMs), REB was used for the first time in this study. Adsorption experiments were carried out through a batch system. The impact of significant experimental parameters showed that the optimum values of initial pH were 2.0 for Cr(VI) retention and 5.0 for Cu(II), and 360 min was selected as the optimum contact time for both HMs. An artificial neural network (ANN) model was applied to create a predictive model for the uptake efficiency of HMs. Adsorption kinetics of Cr(VI) and Cu(II) ions followed the pseudo-second order model. The maximum adsorption capacities of REB identified through the Langmuir model were 41.2 mg g-1 for Cr(VI) and 22.7 mg g-1 for Cu(II) ions. The results of the study demonstrated that REB can be utilized as an abundant, low-cost, and effective adsorbent in removal of HMs from aqueous solutions.
AtıfScopus14WoS11
İncele - MakaleYalnız künye2013Scopus SJRQ3Heavy metal analysis by moss species in the Black Sea region of Turkey
Koz, Bahadir; Cevik, Ugur; Bulut, Volkan Numan; Kaya, Selim; Gundogdu, Ali; Celik, Necati
The heavy metal analysis of mosses in the Black Sea region of Turkey was determined using atomic absorption spectrometry method. The procedure was also validated by analysis of standard reference material (IAEA-336 Lichen). A qualitative analysis showed that the samples contained chromium, manganese, cobalt, nickel, copper, zinc, and lead. While the mean concentration values of Cr, Mn, Co, Ni, Cu, Zn, and Pb in the moss samples collected from city centers are 60.6, 820, 12.2, 18.8, 293, 181 and 39.8 mg.kg-1, the mean concentration values in the moss samples collected from the city intervals are 43.8, 761, 11.0, 15.6, 242, 170 and 38.4 mg.kg-1, respectively. Since this study was a heavy metal analysis along the highway, evaluation of these elements with their potential hazards for ecology and human was briefly discussed. A strong relationship was observed between Pb concentration and the traffic density.
AtıfScopus2WoS2İncele - MakaleYalnız künye2012Scopus SJRQ3Elemental and radioactivity analyses of mosses collected in hatila valley national park - Eastern black sea region of Turkey
Koz, Bahadir; Cevik, Ugur; Celik, Necati
This study was performed in one of the most important parks of Turkey, the Hatila national park, where a gold mining activity is planned to be conducted. For this purpose, 40 moss samples were collected for heavy metal and radioactivity measurements. A radioisotope excited Xray fluorescence analysis using the method of multiple standard additions was applied for the elemental analysis of mosses collected in Hatila valley national park in the Eastern Black Sea region of Turkey. An annular 50 mCi 241Am radioactive source and annular 50 mCi 55Fe radioactive sources were used for excitation of characteristic K-X rays. An Si(Li) detector which had a 147eV full width at half maximum for 5.9 keV photons was used for intensity measurements. A qualitative analysis of spectral peaks showed that the samples contained potassium, calcium, titanium, iron, tin and barium with average concentrations of 230, 5340, 450, 70, 4 and 33 mg.kg -1, respectively. 137Cs and 40K using gamma-ray spectroscopy were determined in 40 moss species collected from the Hatila valley national park. Average activity concentrations of 40K and 137Cs were found to be 103 and 272 Bq.kg -1, respectively. As the region was shown to be heavily contaminated by the Chernobyl accident, the high concentration of 137Cs could be due to this accident. The results are compared with those obtained in different parts of the world where gold mining activities are being conducted. The possible consequences of these results are briefly discussed from the point of potential hazards to ecology and human health.
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