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- MakaleYalnız künye2024Scopus SJRQ4INVESTIGATION OF THE EFFECTS OF VARIOUS OPERATING PARAMETERS ON GEOPOLYMER MORTARS MADE FROM NATURAL MINERALS AND INDUSTRIAL WASTE MATERIALS
Temizer, Hülya; Çavdar, Özlem
In this study, fly ash (FA) from Sivas/Kangal thermal power plant and blast furnace slag (BFS) from Bolu cement industry were used as the main binder materials. Based on both the literature and preliminary tests, samples were prepared with 85% blast furnace slag and 15% fly ash (85BFS15FA) as the main binder. In addition, the effect of geopolymer main binders and different additives such as mine waste, marble powder, and titanium dioxide were evaluated under various working conditions. The aim was to observe the effect of three different levels and 6 different parameters on the geopolymer samples using the Taguchi optimization method. Accordingly, the L27 orthogonal matrix was created. Three different molar ratios (8M, 10M, 12M) of sodium hydroxide (NaOH) solution and sodium silicate (Na2SiO3) solution were used as alkaline activators. Physical and some mechanical tests such as flexural strength, compressive strength, water absorption, and void ratio were performed on the 7, 28, 56, and 90-day samples, and Taguchi and ANOVA statistical analyses were performed on the 90-day samples. The highest compressive strength observed among 108 samples reached 65.75 MPa in the S20 samples (90-day). Taguchi and ANOVA statistical analyses identified curing temperature as the most significant parameter influencing the geopolymer samples. Additionally, the Signal to Noise ratio data indicated that the optimal curing temperature, determined to be the most effective based on the 'Larger is better' criterion, was found to be 75 ̊C.
- MakaleYalnız künye2023Scopus SJRQ3Evaluation of Pozzolanic Activity of Two Different Types of C and F Fly Ashes with Fineness Factor
Sahin, Demet Demir; Cavusoglu, Ibrahim; Yilmaz, Ali Osman
Today, energy produced from coal is economical compared to other sources but it faces a very serious waste problem. However, these wastes are evaluated by using them as mineral additives in cement, which leads to lower cement costs, saving resources, producing environmentally friendly cement, reducing CO2 gas, and producing high-strength cement. In this work, the pozzolanic properties of different types of fly ash (Afşin Elbistan C type and Çayırhan F type) are investigated. The fly ashes used in the study are first subjected to the milling process (10, 20, 30, 45, and 60 minutes), and then the 28 and 90-day pozzolanic activity index tests of the milled and unmilled ashes are performed. The results obtained show that the 28-day pozzolanic activity value of the ashes subjected to 20-, 30-, 45-, and 60-minute milling times are higher than the value specified in the standard, compared to the unmilled and 10 min milled fly ash. In addition, for all fly ash samples, the 90-day pozzolanic activity index results show that while the pozzolanic activity index value of Çayırhan (ÇYH) fly ash is higher than the standard value, that of Afşin Elbistan (AE) fly ash is lower than standard. The outcomes of the present study show that the mechanical properties of the fly ash are generated by the burning of coal increase after milling process, and thus can be used as a mineral additive. With the effect of grinding, both fly ash increase the pozzolanic activity. The results are determined with the experimental results obtained.
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İncele - MakaleYalnız künye2023Scopus SJRQ2Effect of Reduced Fineness of Fly Ash Used on the Alkali–Silica Reaction (ASR) of Concrete
Eker, Hasan; Demir Şahin, Demet; Çullu, Mustafa
This study aimed to determine the effect of fly ash added to concrete with high calcium content (C class) and different fineness on durability properties such as the alkali–silica reaction (ASR). By substituting ultra-fine fly ash for cement at specific proportions in concrete mixes and increasing the fly ash fineness, fly ash filled the spaces between cement grains or aggregates in concrete and accelerated the hydration process. Thus, the mechanism of ASR development was reduced. Class C Afşin Elbistan ash was used and was ground in a ball mill for 0, 10, 20, 30, and 45 min, and Blaine fineness values of 1555, 1632, 2347, 2589, and 2766 cm2/g were obtained, respectively. For each fly ash fineness, the effect of mixtures with 10%, 30%, and 50% replacement of cement on the ASR mechanism was observed during curing periods of 3, 7, 14, and 28 days compared to concrete without fly ash admixture. Furthermore, the effect of the increased fineness and substitution rate of fly ash with high calcium content in cement on the microstructure was revealed by microscopic mineralogical images. The prepared fine fly ash added to concrete mixes at different replacement ratios showed ASR reducing properties compared to the concrete mix without additions. The fly ash fineness and the substitution rate in the concrete had a reducing effect on the ASR, and this effect resulted in values lower than the reference concrete value.
AtıfScopus21WoS21OpenAlex24İncele - MakaleAçık Erişim2022Scopus SJRQ2Investigation of gamma ray absorption levels of composites produced from copper mine tailings, fly ash, and brick dust
Külekçi, Gökhan
To date, heavyweight concretes have been produced from various heavy aggregates as radiation insulation materials, and their gamma ray absorption levels have been investigated. Many of the studies have used heavy aggregates instead of cement or coarse aggregates from composite material components. The present study prepared lightweight concretes using copper mine tailings, clay brick dust, and fly ash instead of fine aggregates. Some mechanical tests (density, compressive strength, and ultrasonic pulse velocity) were performed on composite blocks with dimensions of 5*5*5 cm, and radiation interaction parameters [linear absorption coefficient (cm−1), mass attenuation coefficient (cm2/gr), HVL (half-value layer) (cm), MFP (cm), and permeability (%)] were measured. Radiation interaction parameters were obtained using a HPGe gamma detector. Radiation measurements were performed at five different photon energies: 583 keV (133Ba), 609 keV (133Ba), 662 keV (137Cs), 911 keV (133Ba), 1173 keV (60Co), and 1332 keV (60Co). Additionally, the compressive strength and UPV values of composite materials were associated with their gamma ray permeability. Tests revealed that samples with the addition of copper mine tailings yielded the best energy absorption at all energy levels and that absorption decreased as the energy level increased. For example, with the increasing of the energy level, mass attenuation coefficients decreased. The highest mass attenuation coefficients were obtained as 0.128 cm2/g at an energy level of 583 keV in composites produced from copper mine tailings. On the other hand, it was measured at the same energy level as 0.069 cm2/g (a 46% decrease) in the composites produced with fly ash. In addition, it was observed that fly ash used as a fine aggregate did not have a significant effect on mass attenuation coefficient and could be used as a gamma shield if the material thickness was increased to an average of 14 cm. This study revealed that tailings materials could be used as radiation shields. This study also demonstrated that not using heavy aggregates and producing lightweight concrete in radiation shield production significantly reduced shield production cost.
AtıfScopus10WoS8OpenAlex11İncele - MakaleYalnız künye2021Scopus SJRQ3Investigation of fly ash added light concretes with respect to gamma radiation transmission properties of 133Ba and 137Cs
Külekçi, Gokhan
With the help of the developing concrete technology, light concrete and fly ash may be used in several concrete-related fields. To provide protection from radiation, which is one of the current problems of the world, several researchers have used fly ash, but very few researchers have worked on light concrete. To be protected from the effects of radiation, researchers have examined gamma radiation absorption properties by using heavy concrete and heavy aggregates. In this study, by using Class C fly ash at the doses of 30-50-100% instead of cement, three different light concretes were prepared. Density and compressive strength experiments were conducted on the composite blocks prepared with dimensions of 50*50*50 mm, and linear absorption coefficients (cm(-1)), mass attenuation coefficients (MAC) and Tenth value layer (TVL) radiation interaction parameters were measured. Radiation interaction parameters were obtained using an HP Ge gamma detector. For radiation measurements, four different photon energies as 583 keV (Ba-133), 609 keV (Ba-133), 661 keV (Cs-137) and 911 keV (Ba-133) were used. As a result of the analyses, it was determined that compressive strength decreased as the fly ash content increased, the lowest compressive strength values were obtained in the samples containing 100% fly ash among the prepared composites, and density increased as the fly ash content decreased. It was observed that, in the prepared composites, as the energy levels increased, the linear absorption coefficients also increased, and the samples containing 30% fly ash provided the best TVL value on the energy level of 911 keV. With this study, it was revealed that fly ashes that are used in many fields could be used as a radiation shield. Additionally, with this study, due to not using heavy aggregates and due to the production of light concrete in the production of radiation shields, the cost of shield production will significantly decrease.
AtıfWoS9OpenAlex12İncele - MakaleYalnız künye2021Scopus SJRQ1Sodium silicate effect on setting properties, strength behavior and microstructure of cemented coal fly ash backfill
Cavusoglu, Ibrahim; Yilmaz, Erol; Yilmaz, Ali Osman
Representing an engineered mixture of coal fly ash, cement and water, cemented coal fly ash backfill (CCB) is typically employed for filling the openings created after coal excavation in the earth. A high rate of productivity for coal mines requires a high early-age strength backfill design. Therefore, the use of admixtures in CCB is key for accelerating the backfill setting time and augmenting short-and long-term strength. This study offers the effect of sodium silicate (SS) as an accelerator on early age mechanical and microstructure properties of CCB. SS-based admixture was used for a dosage of 0.5, 1 and 1.5 wt% in CCB that contains 25 wt% ordinary Portland cement OPC and 75 wt% coal fly ash. Backfill setting time was done by using the Vicat system while its strength and pore structure were measured by using the uniaxial compressive strength test, and scanning electron microscopy and Hg intrusion porosimetry. Results display that use of SS in CCB increases its short-term strength gain up to 14% and shortens the mining cycle by cutting its setting time up to 58%. The microstructure analyses also indicate that CCB formulated with SS has a finer pore structure than that without admixture. The outcomes of the present study will be advantageous to evaluate both setting time and strength behavior of CCB used in coal mines, thereby causing the effective backfill plan in terms of money saving and easy operation.
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