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- MakaleAçık Erişim2025Zircon U-Pb geochronology and Sr-Nd-Pb-Hf-O isotope signatures of Middle Eocene high-K plutons from the Eastern Pontides Orogenic Belt, NE Turkey: implications for parental magma sources and magmatic processes
Kaygusuz, Abdullah; Güloğlu, Zikrullah Samet; Aydınçakır, Emre; Yücel, Cem; Vural, Alaaddin; Saydam Eker, Çiğdem; Cicerali, Derya
The Eastern Pontides Orogenic Belt (EPOB) in northeastern Turkey is a well-preserved continental magmatic arc in the Alpine-Himalayan Orogenic Belt and contains many Eocene I-type high-K plutons. Employing LA-ICP-MS U-Pb zircon geochronology, the crystallization ages of the investigated Yaylalıköy and Taşbaşı plutons were established to be Lutetian (Middle Eocene), ranging from 47 Ma to 46 Ma. These plutons exhibit a compositional spectrum ranging from diorite to granodiorite, characterized by I-type, metaluminous, and high-K geochemical signatures. Notably, they are enriched in large-ion lithophile elements (LILEs) and light rare earth elements (LREEs), displaying pronounced negative Eu anomalies (EuN/Eu* = 0.58–0.96). Isotopic signatures reveal homogeneous and moderately low initial 87 Sr/86 Sr(i) ratios (0.704643–0.705034) and positive εNd(i) values (0.24 to 1.67) for the investigated plutons. These isotopic signatures are consistent with mantle origin, as evidenced by their position within the mantle array on isotope ratio diagrams. Lead isotope compositions exhibit limited variations, with initial ratios of 206 Pb/204 Pb(i) (18.55–18.64), 207 Pb/204 Pb(i) (15.61–15.64), and 208 Pb/204 Pb(i) (38.46–38.75). Zircon εHf(i) values are positive (2.32–6.20), plotting between the depleted mantle and chondritic evolution lines. Additionally, these rocks display low zircon δ18 O values (+4.54 to + 6.53‰), comparable to mantle composition. The petrographic characteristics of the investigated plutons suggest that fractional crystallization with minimal assimilation and/or magma mixing played a dominant role during their solidification. The integration of geochemical and isotopic data, alongside regional geological constraints, advocates for enriched lithospheric mantle as the source for the parental magmas of the studied plutons. These magmas subsequently underwent differentiation within a deep-seated magma chamber, followed by emplacement into the crust.
- MakaleAçık Erişim2025Petrochemistry and geochronology of Middle Eocene high-K calc-alkaline I-type Kazıkbeli pluton, NE Turkey: implications from zircon U-Pb ages and Sr-Nd-Pb-Lu-Hf isotope data
Güloğlu, Zikrullah Samet; Kaygusuz, Abdullah
The Kazıkbeli pluton, located in the Kürtün (Gümüşhane) region of the Eastern Pontides, NE Turkey, was studied by employing zircon U-Pb geochronology, whole-rock geochemistry, Sr-Nd-Pb and zircon Lu-Hf isotope geochemistry. LA-ICP-MS U-Pb zircon dating revealed that the gabbroic diorite and granodiorite components of the pluton solidified during the Lutetian epoch of the Middle Eocene, at approximately 46.10 ± 0.26 Ma and 45.37 ± 0.29 Ma, respectively. The pluton is composed of calc-alkaline rocks, ranging from gabbroic diorite to granite (SiO2 = 55.3 to 72.4 wt%). These I-type rocks are typically metaluminous but exhibit peraluminous tendencies in some cases. They are enriched in large ion lithophile elements and display concave chondrite-normalized rare earth element patterns (LaN/YbN = 4.39 to 6.67) with negative Eu anomalies (EuN/Eu* = 0.45 to 0.80). The initial εNd values ranged from 1.85 to 2.24, and the initial 87Sr/86Sr(i) ratios ranged from 0.70458 to 0.70484, consistent with a mantle source in the isotope ratio diagram. The initial 206Pb/204Pb(i), 207Pb/204Pb(i), and 208Pb/204Pb(i) ratios ranged from 18.505 to 18.571, 15.595 to 15.601, and 38.560 to 38.590, respectively. They have positive εHf(i) values (5.75 to 8.03), located between depleted mantle and chondrite evolution values. Fractional crystallization of plagioclase, hornblende, and Fe-Ti oxide minerals played a significant role in the magma evolution, while assimilation and magma mixing may have had a minor influence. Collectively, the evidence suggests that the primary magma source for these plutonic rocks was an enriched lithospheric mantle. Subsequent differentiation within crustal magma chambers, with limited crustal contamination, shaped the final magmatic evolution.
- MakaleAçık Erişim2020Nature of clays in late cretaceous dacitic rocks in the eastern sakarya zone (Ne turkey): A geochemical and isotopic approach
Sipahi, Ferkan; Gücer, Mehmet Ali; Sadiklar, Münür Burhan
Late Cretaceous felsic rocks are common in the eastern Pontides (NE Turkey). These rocks developed as an island arc from the Jurassic to the Miocene; they also host numerous volcanogenic massive sulfide deposits. The Late Cretaceous dacites that outcrop around Zigana Mountain (Gümüşhane, NE Turkey) were exposed to intensive hydrothermal alteration. Widespread hydrothermal alteration of Late Cretaceous dacite in Zigana Mountain has led to the formation of well-developed clay minerals. Their main alteration products are sericite, chlorite, and carbonates (ankerite and calcite). The clay minerals identified by X-ray diffraction and differential thermal analysis include illite, chlorite, small amounts of kaolinite, and smectite. The polytype of illite is 2M1. Illites formed as a result of hydrothermal alteration of feldspars; they are also Fe-and Mg-poor. Chlorite is characterized by decreasing Fe/(Fe+ Mg) ratio with increasing alteration grade and has a trioctahedral structure. Chlorite geothermometer calculations (100–300°C) reflect the activities of hydrothermal solutions. Chlorite forms in more alkaline conditions compared with illite, as its formation is associated with the presence of carbonates. Oxygen and hydrogen stable isotope values, K-Ar dating of illites, and textural and chemical evidence suggest that clays might have formed mainly by alteration of minerals in dacitic rocks with hydrothermal fluids of magmatic origin during the Campanian under acidic–weak alkaline conditions.