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- MakaleYalnız künye2020Scopus SJRQ2Mineralogy, chemistry, and genesis of zeolitization in Eocene tuffs from the Bayburt area (NE Turkey): Constraints on alteration processes of acidic pyroclastic deposits
Cicerali, Derya; Arslan, Mehmet; Yazar, Emel Abdioglu; Yücel, Cem; Temizel, Irfan; Park, Sohyun; Schroeder, Paul A.
Eocene vitric tuffs in the Bayburt area (NE Turkey) possess a dacite-rhyodacite composition and contain abundant altered glass shards and flattened fibrous pumice with lesser amounts of pyrogenic minerals (plagioclase, quartz, biotite, and sanidine). Zeolitization is common and generally develops in the glassy components. The main zeolite mineral found in the tuffs is clinoptilolite, with lesser amounts of analcime and mordenite (?). Smectite is the dominant clay mineral, with lesser amounts of kaolinite also present. Opal-CT, calcite, and dolomite occur as secondary minerals. Scanning electron microscopy studies reveal the dissolution of glass, with the development of popcorn-textured smectites and tabular clinoptilolites developed. The opal-CT spheres found on the clinoptilolite crystals appear to have crystallized simultaneously and are due to excess silica in the environment. Fibrous mordenite (?) also developed on the clinoptilolites. In the clinoptilolites R-r = 0.81-0.82, Si/Al = 4.20-4.70, and K+ is the dominant exchangeable cation (0.65-3.30) seen, together with lesser amount of Ca2+ (0.39-2.25) and Na+ (0.02-2.16). The degree of zeolitization increases with the content of glassy component in the tuffs. The formation of K-clinoptilolite is controlled by the SiO2/Al2O3 (4.9-7.0) and K2O/Na2O (0.8-10.8) ratios in the zeolitized tuffs. delta O-18(V-SMOW) and delta DV-SMOW values of clinoptilolite-rich tuffs range from 22 to 25.6960 and from -96 to -111 parts per thousand, respectively, which suggests that zeolitization occurred at low temperatures (30-55 degrees C) via fluid-rock interactions. Smectite was initially formed from the devitrification of glassy components and is associated with the increase in (Na+ +K+ +Ca2+)/H+ activity and the presence of high pH similar to-9-10) fluids. The zeolites subsequently developed within a saline-alkali shallow marine environment.
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İncele - MakaleYalnız künye2014Scopus SJRQ4Origin of analcimes in the Tertiary volcanic rocks from the Eastern Pontides (NE Turkey): A textural, mineralogical and geochemical approach
Yücel, Cem; Temizel, Irfan; Abdioʇlu, Emel; Arslan, Mehmet; Yaʇcioʇlu, Ufuk Celal
Silica-undersaturated mafic volcanic rocks of Tertiary age in form of lava flows, dikes and sills of tephritic compositions extend along the northern part of the Eastern Pontides. These rocks typically contain Ca-clinopyroxene (Wo32-53En26-54Fs8-24), analcime, Fe-Ti oxides, apatite and minor olivine, plagioclase (An49 - 94), K-feldspar (Or29 - 66), hornblende and phlogopite in microgranular porphyritic, hyalo-microlitic porphyritic and glomeroporphyritic textures. Petrochemical features of the studied rocks, such as enrichment in LILE, depletion in Nb, Ta and Ti and moderate or high LREE/HREE ratios, provide strong evidence for melt production from a subduction-metasomatized lithospheric mantle. Besides, the rocks are characterized by their low K2O contents and low K2O/Na2O ratios as a result of analcimization. Analcime detected in these rocks appears to have formed by pseudomorphic mineral replacement reactions. Euhedral or anhedral analcime crystals, 100 - 600 um in diameter, are set in groundmass and display six-sided polygon or rounded shape and irregular cracks. The analcime pseudomorphs are colourless, milky white to grey and occur in clinopyroxene or in the groundmass. Based on the electron microprobe results, analcimes contain a minor amount of cations other than Na and probably represent the remnants of leucite as marked by K-zoning. X-ray diffraction studies of the analcime-bearing samples confirm the presence of cubic and tetragonal analcime crystals in addition to tetragonal leucite. The presence of Ca-clinopyroxene and plagioclase rather than their sodic equivalents, presence of anhydrous mineral phases and lack of Na differentiation trend as well as partial alteration of the rocks likely supports the secondary growth of analcime either during cooling or after magma solidification.
AtıfScopus16WoS17OpenAlex17İncele - MakaleYalnız künye2010Scopus SJRQ1Late Cretaceous high-K volcanism in the eastern Pontide orogenic belt: Implications for the geodynamic evolution of NE Turkey
Eyüboǧlu, Yener
High-K volcanics were produced in two different Late Cretaceous cycles during the infilling of back-arc basins of the eastern Pontides. The first cycle, represented by shoshonitic trachyandesites and associated pyroclastics, containing high K2O (2.74-4.81 wt-%) and NaK2O (3.60-5.51 wt-%), overlies a mid-Cretaceous ophiolitic-olistostromal melange formed during the rifting stage of a back-arc basin (Neotethys). 40Ar39Ar dating of biotite from trachyandesite at the base of the first cyle indicates that shoshonitic volcanism in the far south of the eastern Pontides started in the early Campanian. Volcanic rocks of this cycle are overlain by upper Campanian-Maastrichtian rudist-bearing reefal limestones. The second cycle of high-K volcanism is represented by analcime-bearing volcanic rocks erupted in a Neotethyan lagoonal environment. These volcanic rocks, intercalated with continental detritus, are characterized by high a2O (3.22-7.16 wt-%), now concentrated in secondary analcime crystals. Their K2O contents also range between 0.83 and 6.05 (wt-%). All of these units are disconformably overlain by Eocene turbidites with a basal conglomerate. Volcanic rocks belonging to both cycles show various enrichment degrees in LILE, HFSE, LREE, and HREE with respect to primitive mantle and chondrite [(La/Lu) cn=11.10-25.89]. Negative Nb, Ta, Zr, Hf, and Ti anomalies are typical of these subduction-related arc magmas. Geochemical similarities between the two volcanic cycles suggest that trachyandesites and analcime-bearing volcanics were derived from similar enriched mantle sources, and that they formed in the same geotectonic setting of a back-arc basin environment of the eastern Pontide magmatic arc during the Late Cretaceous. In addition, Nd-Sr and Pb isotope ratios of the investigated volcanic units indicate that their mantle melt sources were similar. The new geological, geochemical and isotopic data suggest that southward subduction of the Palaeotethyan oceanic crust can be separated into two main stages for the late Mesozoic Pontide orogenic belt. Early southward subduction ended by slab break-off during the mid-Cretaceous, resulting in upwelling and injection of asthenospheric mantle that caused the opening of the eastern Pontide back-arc basin (Neotethys). Resumption of southward subduction began with intense TH-CA bimodal volcanism in the northern front of the arc during the Turonian-Coniacian. The intensity of this Late Cretaceous magmatism in the north decreased towards the south, and a transition to monogenic calcalkaline-alkaline (CA-A) Campanian andesitic volcanism developed in the southern zone. Yet farther south, andesitic igneous activity graded into the Campanian-Maastrichtian shoshonitic and ultrapotassic volcanism in the Bayburt-Maden, Tokat, Amasya, and Gümüshaciköy areas. This zoning of the Late Cretaceous arc magmatism (TH-CA, CA-A and shoshonitic-ultrapotassic, from north to south) also supports the concept of southward subduction during late Mesozoic evolution of the eastern Mediterranean region.
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