Temizel, Irfan; Arslan, Mehmet; Yücel, Cem; Abdioğlu Yazar, Emel; Kaygusuz, Abdullah; Aslan, Zafer

Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Taşlık Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO2 (67–68 wt%) and Al2O3 (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and LaN/YbN (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and YbN (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (LaN/LuN = 14.2–21.6) with insignificant negative Eu anomalies (EuN/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have 87Sr/86Sr ratios of 0.704767 to 0.704927, 143Nd/144Nd ratios of 0.512767–0.512774, εNd values of (+2.52)–(+2.65), and δ18O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.

Cicerali, Derya; Arslan, Mehmet; Yazar, Emel Abdioglu; Yücel, Cem; Temizel, Irfan; Park, Sohyun; Schroeder, Paul A.

Eocene vitric tuffs in the Bayburt area (NE Turkey) possess a dacite-rhyodacite composition and contain abundant altered glass shards and flattened fibrous pumice with lesser amounts of pyrogenic minerals (plagioclase, quartz, biotite, and sanidine). Zeolitization is common and generally develops in the glassy components. The main zeolite mineral found in the tuffs is clinoptilolite, with lesser amounts of analcime and mordenite (?). Smectite is the dominant clay mineral, with lesser amounts of kaolinite also present. Opal-CT, calcite, and dolomite occur as secondary minerals. Scanning electron microscopy studies reveal the dissolution of glass, with the development of popcorn-textured smectites and tabular clinoptilolites developed. The opal-CT spheres found on the clinoptilolite crystals appear to have crystallized simultaneously and are due to excess silica in the environment. Fibrous mordenite (?) also developed on the clinoptilolites. In the clinoptilolites R-r = 0.81-0.82, Si/Al = 4.20-4.70, and K+ is the dominant exchangeable cation (0.65-3.30) seen, together with lesser amount of Ca2+ (0.39-2.25) and Na+ (0.02-2.16). The degree of zeolitization increases with the content of glassy component in the tuffs. The formation of K-clinoptilolite is controlled by the SiO2/Al2O3 (4.9-7.0) and K2O/Na2O (0.8-10.8) ratios in the zeolitized tuffs. delta O-18(V-SMOW) and delta DV-SMOW values of clinoptilolite-rich tuffs range from 22 to 25.6960 and from -96 to -111 parts per thousand, respectively, which suggests that zeolitization occurred at low temperatures (30-55 degrees C) via fluid-rock interactions. Smectite was initially formed from the devitrification of glassy components and is associated with the increase in (Na+ +K+ +Ca2+)/H+ activity and the presence of high pH similar to-9-10) fluids. The zeolites subsequently developed within a saline-alkali shallow marine environment.

Kaygusuz, Abdullah; Yücel, Cem; Arslan, Mehmet; Sipahi, Ferkan; Temizel, Irfan; Çakmak, Gökhan; Güloglu, Z. Samet

The Eastern Pontides comprise many intrusive bodies varying in composition, size and age from Palaeozoic to Cenozoic. Especially Cenozoic aged bodies are commonly observed in the southern part, while they are rarely exposed in the northern part of the Eastern Pontides. In this study, the petrography and mineral chemistry of the Cenozoic aged Çiçekli, Somarova, Sorkunlu, Şaşurluk, Aydintepe, Kemerlikdagi and Pelitli plutons located to the north of Bayburt are determined, and the crystallisation conditions of the studied bodies were estimated by means of thermobarometer calculations. The studied plutons extend mostly in NE-SW directions and are approximately ellipsoid in shape. The contacts between the plutons and surrounding rocks are sharp, and plutons commonly contain mafic microgranular enclaves (MMEs) of different sizes. Petrographic and mineral chemistry studies reveal some disequilibrium textures reflecting the magma mixing process. Based on modal mineralogy, the plutonic rocks are gabbroic diorite, diorite, tonalite, granodiorite and monzogranite in composition. The rocks have fine to medium granular, porphyric, monzonitic, poikilitic, occasionally myrmekitic and micrographic textures. The main minerals are labradorite and albite (An68-02), magnesiohornblende and actinolite (Mg# = 0.6-0.9), diopside and augite (Wo44-46), clinoenstatite (En53-57) and Fe-Ti oxide minerals. Crystallization temperatures calculated from amphibole, biotite, clinopyroxene, magnetite and ilmenite minerals are 405°C to 1161°C, pressure values are 0.1 to 2.7 kbar, and oxygen fugacity (log10 fO2) is -20 to -12. Estimation of water content calculated by using amphiboles is between 2.9 and 6.8%. Based on obtained data, it is suggested that the studied plutons were emplaced at shallow depths (∼ 1-8 km).

Temizel, Irfan; Abdioǧlu Yazar, Emel; Arslan, Mehmet; Kaygusuz, Abdullah; Aslan, Zafer

The Eocene intermediate to felsic plutons are widespread in varying sizes and compositions throughout the Eastern Pontides Orogenic Belt in NE Turkey. Of these, two monzonitic bodies (namely the Eriko Tepe and Göl Tepe Plutons) in the Gölköy (Ordu) area, extend nearly in the orientation of NWSE and E-W and were emplaced into the Upper Cretaceous and/or Eocene volcanic and sedimentary rocks. Petrographically, the studied monzonitic plutons are compositionally fine to medium grained monzonite, monzodiorite and subordinate quartz-monzonite. They consist of plagioclase (An35-67), K-feldspar (Or61-96), quartz, clinopyroxene (Wo28-49En35-51Fs10-25), biotite (Mg#: 0.53-0.73) ± hornblende (Mg#: 0.65-0.82), Fe-Ti oxide with monzonitic, poikilitic, perthitic, rare antirapakivi and graphic textures. Mineral thermobarometer estimations imply that the plutons were crystallized in P-T conditions of mid to shallow crustal levels. Petrochemically, these monzonitic plutons show post-collisional, I-type, metaluminous (A/CNK=0.76-0.93) and shoshonitic features. The wholerock major oxide and trace element variations suggest that fractionational crystallization played a significant role in the evolution of these monzonitic plutons. The primitive mantle-normalized trace element patterns of the studied plutons are similar to each other with enrichment in large ion lithophile elements, Th, Ce and negative Nb and Ti anomalies. Moreover, the chondrite-normalized rare earth element plots of the plutons show moderately enriched concave-shaped patterns (LaN/LuN=9.3-12.6) with negative Eu anomalies (EuN/Eu∗=0.69-0.84), all of which imply plagioclase and clinopyroxene ± hornblende fractionations during their evolution. The geochemical data suggest that the monzonitic plutons have evolved from parental magmas derived from the melts of enriched lithospheric mantle, in a post-collisional setting.

Temizel, Irfan; Arslan, Mehmet; Yücel, Cem; Abdioğlu, Emel; Ruffet, Gilles

40Ar-39Ar age, whole-rock chemical, and Sr-Nd isotope data are presented for the post-collisional, Eocene (51.3-44.1 Ma)-aged volcanic rocks from the Bafra (Samsun) area in the western part of the Eastern Pontides (N Turkey) aiming to unravel their sources and evolutionary history. The studied Eocene volcanic rocks can be divided into two groups: analcime-bearing (tephritic lava flows and dykes) and analcime-free (basaltic to trachytic lava flows and basaltic dykes). The analcime-bearing volcanic rocks have a fine-grained porphyritic texture with clinopyroxene phenocrysts, whereas analcime-free volcanic rocks show a variety of textures including hyalo-microlitic microgranular porphyritic, intersertal, trachytic, fluidal, and glomeroporphyritic. The volcanic rocks also show evidence of mineral-melt disequilibrium textures such as sieved, rounded, and corroded plagioclases, partially melted and dissolved clinopyroxenes and poikilitic texture. Petrochemically, the parental magmas of the volcanic rocks evolved from alkaline to calc-alkaline lava suites and include high-K and shoshonitic compositions. They display enrichments in light rare earth and large ion lithophile elements such as Sr, K, and Rb, as well as depletions in high field strength elements such as Nb, Ta, Zr, and Ti, resembling subduction-related magmas. The analcime-bearing and -free volcanic rocks share similar incompatible element ratios and chondrite-normalised rare rearth element patterns, indicating that they originated from similar sources. They also have relatively low to moderate initial 87Sr/86Sr (0.7042-0.7051), high positive εNd(t) values (+0.20 to +3.32), and depleted mantle Nd model ages (TDM1 = 0.63-0.93 Ga, TDM2 = 0.58-0.84 Ga). The bulk-rock chemical and Sr-Nd isotope features as well as the high Rb/Y and Th/Zr, but low Nb/Zr and Nb/Y ratios, indicate that the volcanic rocks were derived from a lithospheric mantle source that had been metasomatised by slab-derived fluids. Trace element modelling suggests that the parental magma(s) of the volcanic rocks represent mixtures of melts derived by low-degree (~5-10%) partial melting of spinel-lherzolite (40-85%) and garnet-lherzolite (15-60%) mantle sources. Sr-Nd isotopic modelling also suggests that a 25-35% lower crustal component was added in the parental magmas; AFC modelling additionally indicates minor upper crustal contamination during the evolution of the volcanic rocks. In conclusion, integration of the geochemical, petrologic, and isotopic data with regional geology suggests that the analcime-bearing and -free volcanic rocks evolved from parental magma(s) derived from melts of a subcontinental lithospheric mantle and lower crustal sources.

Aslan, Zafer; Arslan, Mehmet; Temizel, Irfan; Kaygusuz, Abdullah

Volcanic rocks from the Gümüşhane area in the southern part of the Eastern Pontides (NE Turkey) consist mainly of andesitic lava flows associated with tuffs, and rare basaltic dykes. The K-Ar whole-rock dating of these rocks range from 37.62 ± 3.33 Ma (Middle Eocene) to 30.02 ± 2.84 Ma (Early Oligocene) for the andesitic lava flows, but are 15.80 ± 1.71 Ma (Middle Miocene) for the basaltic dykes. Petrochemically, the volcanic rocks are dominantly medium-K calc-alkaline in composition and show enrichment of large ion lithophile elements, as well as depletion of high field strength elements, thus revealing that volcanic rocks evolved from a parental magmas derived from an enriched mantle source. Chondrite-normalized rare-earth element patterns of the volcanic rocks are concave upwards with low- to-medium enrichment (LaCN/LuCN = 3.39 to 12.56), thereby revealing clinopyroxene- and hornblende-dominated fractionations for andesitic-basaltic rocks and tuffs, respectively. The volcanic rocks have low initial 87Sr/86Sr ratios (0.70464 to 0.70494) and εNd(i) values (+1.11 to +3.08), with Nd-model ages (TDM) of 0.68 to 1.02 Ga, suggesting an enriched lithospheric mantle source of Proterozoic age. Trace element and isotopic data, as well as the modelling results, show that fractional crystallization and minor assimilation played an important role in the evolution of the volcanic rocks studied. The Eocene to Miocene volcanism in the region has resulted from lithospheric delamination and the associated convective thinning of the mantle, which led to the partial melting of the subduction-metasomatized lithospheric mantle.

Kaygusuz, Abdullah; Arslan, Mehmet; Siebel, Wolfgang; Sipahi, Ferkan; Ilbeyli, Nurdane; Temizel, Irfan

Late Cretaceous I-type plutons are widespread in the Eastern Pontides, NE Turkey. The studied Camiboǧazi pluton is a composite pluton consisting of diorite, tonalite, monzodiorite, monzonite, quartz monzonite, granite, and mafic microgranular enclaves (MMEs). Laser ablation ICP-MS U-Pb dating of zircon yielded crystallization ages of 76.21±0.79Ma, 75.65±0.50Ma, 75.04±0.83Ma, and 74.73±0.86Ma for diorite, monzodiorite, monzonite, and granite, respectively. The rocks of the pluton have I-type, high-K to shoshonitic and metaluminous character, displaying whole-rock geochemical features of arc-related granites. They are enriched in large-ion lithophile and light rare-earth elements, and depleted in high-field-strength elements. Major element variations can be attributed to fractionation of plagioclase, clinopyroxene, hornblende, and Fe-Ti oxides. The rocks show considerable variation in 87Sr/86Sr(i) (0.70498 to 0.70622), εNd(i) (-2.79 to -0.36), δ18O values (+6.3 to +11.4) and Nd model ages (TDM) (0.81Ga to 1.26Ga). Besides, they have (206Pb/204Pb)=18.44-19.09, (207Pb/204Pb)=15.64-15.69, and (208Pb/204Pb)=38.37-38.89. Although isotope signatures of the mafic microgranular enclaves (MMEs) (87Sr/86Sr(i)=0.70551 to 0.70622; εNd(i)=-2.9 to -1.23; δ18O=+8.3 to +9.7) are largely similar to the host rocks, MMEs are characterized by relatively high Mg-numbers (32-36), low contents of SiO2 (52-56wt.%) and low ASI (0.7-0.9). Estimated crystallization temperatures for the rocks of the pluton range from 735±58°C to 844±24°C and a shallow intrusion depth (<10km) is estimated from Al-in-hornblende thermobarometry. Whole-rock geochemical and isotopic data suggest magma generation by dehydration melting of an amphibolite-type lower crustal component with additional input of a subcontinental lithospheric mantle component. Furthermore, Sr-Nd isotope mixing model reveals ~30% to 40% lower crustal magma contribution to the mantle component.

Yücel, Cem; Temizel, Irfan; Abdioʇlu, Emel; Arslan, Mehmet; Yaʇcioʇlu, Ufuk Celal

Silica-undersaturated mafic volcanic rocks of Tertiary age in form of lava flows, dikes and sills of tephritic compositions extend along the northern part of the Eastern Pontides. These rocks typically contain Ca-clinopyroxene (Wo32-53En26-54Fs8-24), analcime, Fe-Ti oxides, apatite and minor olivine, plagioclase (An49 - 94), K-feldspar (Or29 - 66), hornblende and phlogopite in microgranular porphyritic, hyalo-microlitic porphyritic and glomeroporphyritic textures. Petrochemical features of the studied rocks, such as enrichment in LILE, depletion in Nb, Ta and Ti and moderate or high LREE/HREE ratios, provide strong evidence for melt production from a subduction-metasomatized lithospheric mantle. Besides, the rocks are characterized by their low K2O contents and low K2O/Na2O ratios as a result of analcimization. Analcime detected in these rocks appears to have formed by pseudomorphic mineral replacement reactions. Euhedral or anhedral analcime crystals, 100 - 600 um in diameter, are set in groundmass and display six-sided polygon or rounded shape and irregular cracks. The analcime pseudomorphs are colourless, milky white to grey and occur in clinopyroxene or in the groundmass. Based on the electron microprobe results, analcimes contain a minor amount of cations other than Na and probably represent the remnants of leucite as marked by K-zoning. X-ray diffraction studies of the analcime-bearing samples confirm the presence of cubic and tetragonal analcime crystals in addition to tetragonal leucite. The presence of Ca-clinopyroxene and plagioclase rather than their sodic equivalents, presence of anhydrous mineral phases and lack of Na differentiation trend as well as partial alteration of the rocks likely supports the secondary growth of analcime either during cooling or after magma solidification.