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- MakaleYalnız künye20265-Hydroxymethylfurfural and furfural levels in non-alcoholic beverages: a survey of product types
Arslan Burnaz, Nesibe; Baltacı, Cemalettin; İlyasoğlu, Huri
Toxic furanic compounds such as 5-hydroxymethylfurfural (HMF) and 2-furfural (F) can form during the processing and storage of non-alcoholic beverages (NABs). This study aimed to determine the levels of HMF and F in a wide range of NAB categories, including fruit juices and nectars, carbonated soft drinks, non-carbonated soft drinks, energy drinks, and coffee with milk drinks. The levels of HMF and F were determined using a validated analytical method. The HMF and F levels of the studied samples varied depending on the type of product. The coffee with milk drinks exhibited the highest levels, while the carbonated soft drinks exhibited the lowest. Notably, the HMF levels of most of the coffee with milk drinks exceeded 10 mg L−1. The findings provide novel insights into the presence of furanic compounds in NABs and emphasise the importance of raising consumer awareness regarding potential dietary exposure to furanic compounds, particularly from coffee drinks.
- MakaleAçık Erişim2025A strategy for the one-pot direct production of 5-hydroxymethylfurfural (HMF) from sucrose using organic weak acid in situ as a catalyst
Gül, Abdulkadir; Tanyıldızı, Muhammet Şaban
5-Hydroxymethylfurfural (HMF), which can be produced in high yields by acid-catalyzed dehydration of carbohydrates, is used as a feedstock in biofuel and biopolymer production. However, these acidic catalysts are usually added externally, which increases HMF production costs. Furthermore, other important parameters for high yields of HMF production are raw material selection, reaction medium, and separation-purification processes. The aim of this study is to produce HMF in one-pot without the addition of any exogenous catalyst by evaluating the fructose remaining in the production medium in which the glucose from sucrose hydrolysis is microbially fermented into gluconic acid (GA). HMF production from fructose in a biphasic system consisting of a fermentation liquid containing GA and fructose and 2-Methyltetrahydrofuran (2-MeTHF) was optimized using Central Composite Design (CCD). The variables examined included reaction time, reaction temperature, solvent type, salt type, and organic/aqueous phase ratio. In the study, by chelating GA and calcium ions, the low degree of ionization of GA was increased, and HMF was produced in high yields without the addition of a catalyst. Under optimum conditions, using 2-MeTHF/ fermentation liquid (6:1) and 7.56 wt% CaCl2, the yield of HMF produced in pressurized (hydrothermal) vessels at about 147 °C for 158 min reached 77.6 % of the theoretical yield. The amount of GA in the production medium was 92.64 % preserved from degradation. GA and HMF in different phases of the biphasic system were purified from the production medium in high yields. Furthermore, 2-MeTHF, which constitutes the organic phase of the biphasic system, was recovered at approximately 95 % by vacuum evaporation. As a result, HMF production from sucrose, which is a more economical and abundant raw material compared to glucose and fructose, was realized in one-pot without the addition of any catalyst.