Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleYalnız künye2012Performance and emission studies of castor bean (Ricinus Communis) oil biodiesel and its blends with diesel fuel
Özcanli, M.; Serin, H.; Saribiyik, O.Y.; Aydin, K.; Serin, S.
An experimental study was conducted to evaluate the use of various blends of castor (Ricinus Communis) oil methyl ester with diesel fuel. Performance and exhaust emissions of castor oil biodiesel with diesel fuel in a commercial compression ignition engine were presented in this study. Biodiesel produced from castor oil was blended with diesel fuel at the volumetric ratios of 5% (B5), 10% (B10), 25% (B25), 50% (B50), and 100% (B100). Fuel properties of castor oil methyl ester and its blends with diesel fuel were stated. The performance results showed that blends of castor oil methyl ester with diesel provided an increase on brake specific fuel consumption and a small decrease on brake power output. Compared with diesel fuel, diesel-castor oil methyl ester blends showed that while the carbon monoxide and carbon dioxide emissions became reduced; the oxides of nitrogen emissions observed higher than diesel fuel emission characteristics. Test results showed that B25 was determined as a suitable alternative fuel for diesel engines.
- MakaleAçık Erişim2011Mild conditions for oxidation/epoxidation of styrene
Kazanci, A.; Saribiyik, O.Y.; Serin, S.
In this study, in order to obtain novel support materials for immobilization of transition metals, polymeric Schiff bases were synthesized using a poly-condensation reaction between ortho(o-)phthalaldehyde tere(t-)phthalaldehyde, oxaldehyde and diamines like, e.g., ethylene-p- phenylene- and o-phenylenediamine. Additionally, catalytic activity of polymeric Schiff base metal on oxidation/epoxidation of styrene complexes were investigated. The products have been characterized on the basis of analytical and spectral method, Fourier transform infrared spectroscopy, 1H- and 13C-nuclear magnetic resonance, gel-permeation chromatography, elemental analysis, thermogravimetric analysis, atomic adsorbtion spectrometry, gas chromatography and gas chromatography mass spectrometry.
- MakaleAçık Erişim2011Synthesis, characterization and catalytic investigation of novel polymeric thiourea
Saribiyik, O.Y.; Serin, S.
In this study, in order to obtain polymeric thiourea compounds which have unsolubulity properties and higher metal content, new reaction pathways based on the use of the template effect were investigated. For this purpose, the reactions between different diamines, such as ethylendiamine, ortho (o-) and para (p-) phenylenediamine, and carbon disulfide (CS2) were investigated and optimized by using the template effect of Ni(II). Catalytic activity of the polymeric structure on oxidation of styrene was also investigated in terms of different parameters such as heat (25 and 80° C), time (4 and 8 h), oxidant hydrogen peroxide (H2O2), tert-butyl hydroperoxide (TBHP), di-tert-butyl peroxide (DtBP) and solvent (acetonitrile and benzene). The products have been characterized on the basis of analytical and spectral method, Fourier transform infrared spectroscopy, 1H- and 13C-nuclear magnetic resonance, gel-permeation chromatography, elemental analysis, thermogravimetric analysis, atomic adsorbtion spectrometry, gas chromatography and gas chromatography mass spectrometry.