Sürdürülebilir Kalkınma Amaçları

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• MakaleYalnız künye2025/r/gumushane/12314
  Origin and tectonic setting of the carbonate-hosted Kopuz Fe skarn Deposit, Sakarya Zone, NE Türkiye

  Sipahi, Ferkan; Akpınar, İbrahim; Gücer, Mehmet Ali; Kaygusuz, Abdullah; Vural, Alaaddin; Saydam Eker, Çiğdem

  The Kopuz Fe skarn deposit in the eastern Sakarya Zone is genetically associated with the 44–45 Ma Kopuz granitoid. The Fe ores are hosted within the contact zone between this granitoid and Jurassic Lower Cretaceous limestone. The deposit is characterized by both endo- and exoskarn zones, which exhibit a diverse range of minerals including clinopyroxene, plagioclase, amphibole, biotite, garnet, epidote, phlogopite, magnetite, hematite, pyrite, quartz, calcite, actinolite, limonite, and goethite. Magnetite and hematite, accompanied by small amounts of pyrite, are primarily ore minerals. Pyroxene types observed in the mineralization include diopsidic hedenbergite in the endoskarn zone and diopside in the exoskarn zone. Plagioclase in the endoskarn zone vary from oligoclase to Labrador in composition, which transition towards Na-rich plagioclase and orthoclase in the ore-bearing exoskarn zone. Amphiboles, primarily calcic in nature, are classified as Mg-hornblende and actinolite, with low F and Cl contents, indicating minimal F enrichment during Fe-skarn formation. Garnet is characterized by andradite in the exoskarn zone close to the endoskarn and grossular-andradite in the distal exoskarn zone. The increase of Ad/Gr ratios in zoned garnet indicate an increasing ƒO2 value outward from it. Considering that rare pyrite occur together with magnetite and hematite, we suggest that the deposit formed under conditions of low ƒS2 and high ƒO2 conditions. The homogenization temperature and salinity of the fluid inclusions in quartz from the exoskarn zone vary from 224 °C to 349 °C and 4.18 % (wt% NaCl equiv.), respectively. The oxygen isotope composition (5.10 ‰ to 7.86 ‰) of the fluids in equilibrium with magnetite and quartz minerals in the exoskarn zone supports a magmatic fluid origin. The oxygen isotopic signatures of epidote and amphibole further indicate a minor interaction with an additional source, likely meteoric waters. The sulfur isotope composition of pyrite (2.3 ‰) is consistent with a magmatic sulfur source. In summary, the middle Eocene-aged Kopuz Fe skarn deposit occurred a shallow depth within a magmatic arc, where oxidized conditions predominated.

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• MakaleYalnız künye2022/r/gumushane/14949
  Eocene magmatism and associated Fe-Cu mineralization in northeastern Turkey: a case study of the Karadağ skarn

  Sipahi, Ferkan; Saydam Eker, Çiğdem; Akpınar, İbrahim; Gücer, Mehmet Ali; Vural, Alaaddin; Kaygusuz, Abdullah; Aydurmuş, Tanju

  The metallogenic belt containing numerous skarn mineralized systems starting from Eastern Europe continues through Turkey and Iran. The study area in the Eastern Pontides is within this metallogenic belt. The 44.39 ± 0.53 Ma Karadağ Intrusion sourced skarn mineralization is located along the granitoid-to-limestone contact. The Karadağ Intrusion is an arc-like pluton with medium–high K calc-alkaline and peraluminous–metaluminous affinity. The Karadağ Fe–Cu skarn mineralization (Gümüşhane, Turkey), an exoskarn, is hosted by Late Cretaceous limestone and consists of early garnet, clinopyroxene, and orthoclase with late epidote and chlorite. Primary ore minerals are magnetite and haematite, accompanied by minor amounts of chalcopyrite and pyrite. Pyroxene comprises mostly diopside and less hedenbergitic diopside and johannsenite. Wollastonite is very rare. Garnet is andradite and grossular–andradite. Thus, all these results imply that the Karadağ Fe–Cu skarn mineralization formed under relatively oxidized and Fe-rich conditions. The homogenization temperatures of the fluid inclusions vary from 189°C to 405°C for quartz and 186°C to 430°C for calcite. The salinity contents in the fluid inclusions are within 0.2–9 wt% NaCl equivalent for quartz and 0.4–14.8 wt% NaCl equivalent for calcite. First melting temperatures between −36.5 and −47.4°C were attained with the presence of NaCl–FeCl2± CaCl2 in the initial phase of fluid inclusions. The first melting in the later stage of fluid inclusions is between −3.8 and −17.2°C, thereby, supporting the existence of NaHCO3-Na2CO3-KCl-type salt composition. The δ18O values of minerals are 1.7–10.3‰ for garnet, 11.1–14.6‰ for quartz, 6.4 to 6.8‰ for epidote, and 2.8–3.8‰ for magnetite in the Karadağ skarn mineralization. The δ18O value of epidote indicates magmatic fluid, whereas those of garnet, magnetite, and quartz suggest magmatic fluids together with less meteoric effect. The δ18O values in limestone (18.7 to 22.3‰), marble (8.7‰), and calcite (10.5 to 12.2‰) were depleted relative to typical δ18O contents of marine carbonates (20 to 30‰). Moreover, the C isotope values of calcite (−5.4 to −1.4‰), marble (−2.1‰), and limestone (1.0 to 1.2‰) reflect those of metamorphic rocks and skarns (−4.0 to 3‰ and −18 to 2‰). Mineral paragenesis, fluid inclusion, and stable isotopic signatures are consistent with ore mineralization caused by the interaction of magmatic fluids with carbonate host rocks. Karadağ Fe-Cu skarn mineralization, associated with Karadağ postcollisional magmatism, is an example of skarn mineralized system in the Eastern Pontides.

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• MakaleYalnız künye2021/r/gumushane/14706
  Mineralogical and Chemical Characteristics of Clay Areas, Gümüşhane Region (NE Turkey), and Their Detection Using the Crósta Technique with Landsat 7 and 8 Images

  Vural, Alaaddin; Akpinar, İbrahim; Sipahi, Ferkan

  The clay areas in Gümüşhane (NE Turkey) were examined in mineralogical and geochemical terms, and by remote sensing methods. X-ray diffraction, scanning electron microscope and chemical analysis were completed on samples from 11 selected clay areas in the region. Within the scope of remote sensing, Landsat 7 and 8 satellite images of the region were processed with the Crósta technique to assess the clay areas. The Kale and Tamzı clays are contained within a Late Cretaceous turbiditic series. The clays in Canca, Refene and Çamlıca occur in intensively hydrothermally altered volcanic rocks of the Eocene Alibaba Formation. The other clay areas are in the Liassic Şenköy Formation consisting of a volcano-sedimentary series. The clays in the Şenköy Formation are generally below the coal levels. While mainly illite and lesser kaolinite were determined in Dörtkonak, Alemdar, Yukarı Kov and Çamlıca, the clays in Tahnis and Kabantaşı are smectite. Tekke, Canca and Refene clays are kaolinite with smaller amounts of illite, whereas Kale and Tamzı clays are mainly chlorite with lower content of illite–smectite interlayers. Illites in Dörtkonak, Alemdar, Yukarı Kov and Çamlıca are poor in iron and magnesium and formed by hydrothermal alteration of feldspars in the host rocks. Findings of the remote sensing studies using Landsat 7 and 8 datasets were compatible with the results obtained from field observations and general geological studies, and so it is concluded that the Crósta technique provided good results for exploration of clay occurrences and their determination in the region.

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• MakaleYalnız künye2021/r/gumushane/13267
  Assessment of the concentration and environmental impacts of potential hazardous elements in coalfields in Northeastern Turkey

  Saydam Eker, Ç.; Sipahi, F.; Akpınar, I.

  To investigate the impact of potential hazardous element (PHE) contamination on environmental and human health, the coaly shale, coal and shale coal outcrops of four sites, namely Ozyurt, Tarhanas, Kayadibi (Gümüşhane), and Manas (Bayburt), were selected as sampling areas for this study. The samples were analyzed using inductively coupled plasma (ICP) emission spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS) and a Rock–Eval 6 analyzer with a total organic carbon module. The enrichment factor (EF), potential ecological risk index (RI), and potential health risk index (HI) assessment models were used to evaluate the environmental and health risks in the vicinity of the coals. Results indicated that the mean concentrations of PHEs extensively changed and even exceeded the upper continental crust and world average values of low-rank coal concentrations. The assessment of the EF, RI and HI models revealed that the contamination levels of As, Hg, and Cd were higher than those of Pb, Co, Ni, V, and Mo. The evaluation of the EF revealed that the largest and lowest contamination levels of As, Hg, and Cd were observed in Ozyurt (29) and Kayadibi (1.8), Manas (9.6) and Kayadibi (1), and Kayadibi (5.6) and Tarhanas (1.9), respectively. A high-potential ecological risk was present in Ozyurt and Manas, whereas a considerable risk exists in Kayadibi and Tarhanas. The potential health risk values of As for children in Ozyurt, Tarhanas, and Manas and adults in Ozyurt were excessively high. This finding suggested the possibility of transferring the contamination from the coal, shale coal, and coaly shale outcrops

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• Kitap BölümüAçık Erişim2019/r/gumushane/12988
  Ore Mineralogical Study of Cerattepe Au-Cu (±Zn) VMS Deposit (Artvin-Turkey)

  Akpınar, I.; Çiftçi, E.

  The Cerattepe mine, one of the volcanogenic massive sulfide deposits in northeastern Turkey, is hosted within the late Cretaceous volcanic, intrusive and sedimentary rocks. Deposit’s main ore body contains high-grade massive copper sulfides and a gold-silver and barium rich oxide zone, characterized by dense alteration stages, is situated on top of it. Replacement, cataclastic, breccia, dissemination, dendritic, concentric growth, colloform, and framboidal textures were identified. Pyrite, sphalerite, marcasite, chalcopyrite, bornite, galena, tennantite-tetrahedrite, gold, covellite, digenite, chalcocite, cuprite and cubanite constitute the mineral paragenesis where quartz, calcite and barite account for the gangue minerals. Limonite, hematite, lepidocrocite, malachite, azurite and jarosite developed in the oxidation zone.

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• Derleme MakaleAçık Erişim2018/r/gumushane/15240
  Late Cretaceous arc igneous activity: the Eğrikar Monzogranite example

  Sipahi, F.; Kaygusuz, A.; Saydam Eker, Ç.; Vural, A.; Akpınar, İ.

  The geochemical and Sr–Nd–Pb isotope properties, as well as the Laser Ablation Inductively Coupled Plasma and Mass Spectrometry (LA-ICP-MS) U–Pb zircon age, of Eğrikar Monzogranite in the eastern Pontides, are primarily investigated in this study with the aim of determining its magma source and geodynamic evolution. The U–Pb zircon age obtained from Eğrikar Monzogranite is 78 ± 1.5 Ma, thereby reflecting the age of monzogranite. The I-type Eğrikar Monzogranite comprises quartz, plagioclase (An35–45), orthoclase, muscovite, and biotite. The geochemical analyses of the Eğrikar Monzogranite indicate being medium K calc-alkaline, peraluminous, and resembling magmatic arc granite. The Eğrikar Monzogranite is enriched in large ion lithophile elements and light rare earth elements relative to high field strength elements. Chondrite-normalized rare earth element patterns have concave upward shapes (LaN/YbN 2.47–8.58) with pronounced negative Eu anomalies (EuN/Eu* = 0.29–0.65). Initial εNd(i) values vary between 1.85 and 2.18 and initial 87Sr/86Sr values between 0.7048 and 0.7067. Fractionation of plagioclase, hornblende, and apatite played an important role in the evolution of Eğrikar Monzogranite. The crystallization temperatures of the melts ranged from 770°C to 919°C based on zircon and apatite saturation temperatures. The geochemical and isotopic data suggest being generated by the partial melting of mafic lower crustal sources.

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• MakaleYalnız künye2017/r/gumushane/13392
  Environmental impact of Gümüşhane City, Turkey, waste area in terms of heavy metal pollution

  Vural, Alaaddin; Gundogdu, Ali; Akpinar, Ibrahim; Baltaci, Cemalettin

  The aim of this study is to investigate the occurrence of a heavy metal contamination in a solid waste site of Gümüşhane City, Turkey, to examine the dimensions of the risk of contamination, and to present suggestions for possible solutions. For this purpose, heavy metal contents of soil and leachate samples taken from a Gümüşhane waste site were determined by a new method, microwave plasma-atomic emission spectrometry (MP-AES). When the obtained results are compared with background and control values, it can be seen that the region carries contamination risks, especially in terms of heavy metals such as Zn, Cd, Pb, Cu, Ni, and Co. To examine the environmental effects of the landfill area in more detail, geodeposition index (Igeo), enrichment factor (EF), contamination index (PI), and combined contamination index (IPI) parameters are used. In addition, the samples taken from an area supposed to be free of pollution risk were also analyzed as control samples, and the obtained data were statistically compared with the results of the waste area. It is determined that the results of landfill waste site are dissimilar to those of comparison samples in terms of investigated metals, and that they contained higher values in general.

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• MakaleYalnız künye2017/r/gumushane/12963
  Formation of the Eğrikar (Gümüşhane) Fe–Cu skarn type mineralization in NE Turkey: U–Pb zircon age, lithogeochemistry, mineral chemistry, fluid inclusion, and O-H-C-S isotopic compositions

  Sipahi, Ferkan; Akpınar, İbrahim; Eker, Çiğdem Saydam; Kaygusuz, Abdullah; Vural, Alaaddin; Yılmaz, Meltem

  The Eğrikar Fe–Cu skarn type mineralization is located approximately 100 km NW of Gümüşhane in NE Turkey. Geochemical analyses of diorite, which is thought to cause skarn, indicate medium K calc-alkaline (1.3 to ~ 2.3 wt% K2O), metaluminous to peraluminous (A/CNK = 0.76 to 1.13) and resembles a continental arc granite. The age of U–Pb zircon obtained from diorite is 42.3 ± 1.0 Ma, which reflects the age of skarn metasomatism after intrusion into Late Cretaceous sandy carbonates. Skarn formation zones are recognized as endo- and exoskarn. The endoskarn zone mainly consists of pyroxene with hedenbergite (Di4.31–28.14Hd59.29–80.82Jo5.0–35.55) at prograde stage. Mn content of pyroxene increases a slight from endo to exoskarn. Pyroxene is replaced by epidote and hornblende at the retrograde stage. The exoskarn zone comprises garnet with andradite (Ad91-99Gr01–07) and grossular-andradite (Ad44-95Gr05–54), epidote and quartz as silicate minerals, and magnetite and hematite as ore minerals. Magnetite is the abundant ore mineral and is accompanied by chalcopyrite and minor pyrite at retrograde stage. On the basis of fluid inclusion values of minerals, the temperature range for hedenbergite in endo-exoskarn is 350 °C–425 °C, for epidote in exoskarn is 365 °C–376 °C, and for quartz in exoskarn 200 °C–380 °C. NaCl equivalent salinity for hedenbergite 6.88–10.73 wt% and for quartz is 3.9–15.38 wt. The δ18O values of hedenbergite is 4.1 to 4.7‰ and for garnet 3.4‰ at prograde stage, for epidote 7.9–9.2‰, for magnetite 1 to 4.4‰, for hematite − 2.9 to − 1.6‰ and for quartz range between 8.5‰ and 15.2‰. The δ18O value of epidote suggests that oxygen is a magmatic fluid whereas hedenbergite, garnet, quartz and magnetite show the mixing of magmatic and meteoric fluids. In addition, the C isotope values (− 3.2 to 2.8‰) of calcite and marble in Eğrikar Fe–Cu skarn reflect those of metamorphic, and skarns. Based on oxygen isotope data from mineral pairs, the retrograde skarn formation is characterized by epidote–magnetite assemblage formed at 255 °C–438 °C. Fluid oxygen isotope compositions of magnetite and epidote pairs of the exoskarn skarn zone indicate a mixing of magmatic and meteoric fluids with narrow δ18O values between 7.17‰ and 8.9‰. The δ34S values of the pyrites exhibit a narrow range of 3‰ and 4.4‰, thereby indicating that sulfur were probably leached from magmatic rocks. Based on the field and laboratory observation, mineral chemistries, fluid inclusion studies and isotope composition analysis, it is suggested that the Eğrikar Fe–Cu skarn mineralization occurs in a magmatic origin fluids being initially under reduced conditions, subsequently under oxidized conditions, and at shallow depth.

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• MakaleYalnız künye2016/r/gumushane/13350
  Concentrations of elements in Lias coals from the eastern Black Sea Region, NE-Turkey

  Eker, Çiğdem Saydam; Akpınar, İbrahim; Sipahi, Ferkan; Yapıcı, Ejder

  ABSTRACT: The element contents and organic matter-element relation between Lias-aged coals exposed in four fields in Gümüşhane and Bayburt were investigated. In general, fixed carbon and gross calorific values of the Edire and Balkaynak coals are higher than Güvercinlik and Çerçi coals. The highest ash yields were observed in the Çerçi coals. The concentrations of Mg, P, Ca, Mo, Y, Ni, U, Zn, Ga, Ba, W, Sr, Ta, and Be of the analysed coals are positively correlated with ash yield, indicating an organic affinity. The Lias-aged coals located in Gümüşhane and Bayburt are low-rank coals.

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• MakaleYayıncıda açık erişim2016/r/gumushane/11364
  Organic geochemistry and element distribution in coals formed in eocene lagoon facies from the Eastern Black Sea Region,NE Turkey

  Saydam Eker, Çiğdem; Akpinar, İbrahim; Sipahi, Ferkan

  The amount and type,the inorganic element content,and the maturity of organic materials of Eocene coals,shaly coals,and coaly shales exposed in the Gümüşhane and Bayburt districts of the Eastern Black Sea Region of Turkey were investigated. The depositional environments and hydrocarbon potentials were also interpreted. The total organic carbon concentrations in the studied samples ranged from 0.50% to 63.08%. The samples from Özyurt,Kayadibi,and Tarhanas contained types II and III kerogen,and those from Sökmen and Manas contained type III kerogen. The samples contained Co,Cs,Ga,Hf,Th,U,Y,Mo,Be,Cd,Sb,and La,with average values similar to those of standard brown coals. The samples showed average contents of Co,Ga,Nb,Rb,V,Y,Cu,Pb,Zn,As,Be,and Se,similar to those of other Turkish coals. The sediment source of Eocene samples in the five areas was characterized by rocks with intermediate or mafic geochemical characteristics. The terrigenous/aquatic ratio of coal and shaly coal samples of the areas in question is >1. The sterane distribution was C29 > C28 > C27 and C29 > C27 > C28 for the Özyurt and Tarhanas areas,respectively. The average Tmax values for samples are between 424 °C and 460 °C. For samples Oz-1 and Ta-2,22S/(22S + 22R) homohopane (C32) ratios are 0.48 and 0.61,respectively; 20S/(20S + 20R) sterane (C29) ratios are 0.18 and 0.53,respectively; and Ts/(Ts + Tm) ratios are 0.015 and 0.64,respectively. The Pr/Ph ratios of the samples are >3. The studied samples have low sterane/hopane and high (C19+C20)/C23) ratios without anoxic biomarkers (17α(H)-28,30-bisnorhopane). Based on these data,the coals,shaly coals,and coaly shales were probably deposited under an oxic-suboxic mixture of marine and terrestrial environment conditions; these materials contain terrestrial organic matter and cannot generate hydrocarbon.

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