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- MakaleAçık Erişim2026Scopus SJRQ1Thermochemical Activation of Lightweight Slag–Perlite Alkali-Activated Slag (AAS): Overcoming Aggregate Brittleness and Sulfate Degradation
Eker, Hasan; Demir Şahin, Demet
The successful realization of a circular economy in the cement industry, coupled with a substantial reduction in carbon emissions, relies on the development of sustainable alternative binder systems. This study investigated the physicomechanical performance and sulfate resistance of composites produced by alkali activation of natural perlite and blast furnace slag. The aim of the research was to improve mechanical properties under low- and medium-alkalinity conditions (5–10 M NaOH). The samples were cured at an ambient temperature of 20 °C and then treated with heat at 60 °C. These samples were then mechanically processed and subjected to five soak–dry cycles in 5% and 10% Na2SO4 solutions. The results showed that heat treatment resulted in the formation of a dense C-A-S-H gel, increasing compressive strength approximately eightfold, from 11.64 MPa to 92 MPa. However, perlite’s porous and brittle structure limits its flexural strength to 0.27 MPa; this value is insufficient for structural applications. Under severe sulfate attack (10% Na2SO4), samples cured at ambient temperature showed a 12% mass increase in the first cycle due to solution infiltration into capillary voids. As a consequence of extensive ettringite and gypsum formation, the specimens experienced severe deterioration, resulting in a complete loss of mechanical integrity and a residual compressive strength of 0 MPa. In contrast, heat-treated samples showed limited ion diffusion due to a denser matrix and an improved aggregate interface transition zone, resulting in a 2.6% mass increase and a residual compressive strength of 5.17 MPa. Consequently, the obtained findings indicate that thermally treated alkali-activated slag–perlite composites exhibit high resistance against sodium sulfate attack and may have potential for use in specific industrial environments with high sulfate concentrations. However, the performance of these materials under more complex aggressive conditions, such as mining environments involving magnesium sulfate exposure and acidic drainage waters, should be further validated through future studies.
AtıfScopus1WoS1OpenAlex1İncele - MakaleYalnız künye2026Scopus SJRQ1Analysis of microstructural properties and durability characteristics of geopolymer mortars with mining waste
Aksüt, Yavuz Selim; Kaya, Yusuf; Sünnetçi, Kadir
The growing environmental concerns over resource depletion and carbon emissions from cement production have accelerated the search for sustainable alternatives to conventional concrete. In this context, geopolymers have emerged as promising binders, particularly through the utilization of aluminosilicate-rich industrial wastes to reduce environmental impact and support waste recycling. This study examines the mechanical and durability properties of geopolymer mortars produced by partially replacing ground granulated blast furnace slag (GGBFS) with mining waste (MW) at ratios of 0%, 10%, 20%, and 30%. The mixtures were activated using 10 M sodium hydroxide and sodium silicate under standard water curing conditions. Mechanical strength, ultrasonic pulse velocity (UPV), freeze–thaw resistance, and sulfate durability were evaluated. The optimum performance was obtained with 20% MW, which achieved a 30.4% increase in flexural strength and 18% in compressive strength at 7 days. This mixture also showed the lowest mass (10.69%) and strength loss (18.36%) after 50 freeze–thaw cycles. Scanning electron microscopy analysis confirmed enhanced gel formation and microstructural densification. The findings demonstrate that controlled use of MW not only improves durability but also promotes sustainable binder development in geopolymer technology.
AtıfScopus1OpenAlex1İncele