Yazarlar

• Kaya, Afşin Ahmet(1)
• Menzek, Abdullah(1)
• Şahin, Ertan(1)

• MakaleYalnız künye2014Scopus SJRQ3/r/gumushane/13201
  Synthesis of cyclohexane derivatives including Br, Cl, N, O, and S at 1,2,4,5-positions: Selectivity in addition reactions Dedicated to Professor Dr. Metin Balci on the occasion of his 65th anniversary

  Kaya, Afşin Ahmet; Menzek, Abdullah; Şahin, Ertan

  Brominations of mono addition products of 1,4-cyclohexadiene with 2,4-dinitrobenzenesulfenyl chloride (RSCl) selectively gave 1R(S),2R(S),4R(S), 5R(S)-4,5-dibromo-2-(2,4-dinitrophenylthio)cyclohexyl acetate and 1R(S),2R(S),4R(S),5R(S)-4,5-dibromo-2-chlorocyclohexyl)(2,4-dinitrophenylthio) sulfane. From series reactions 7-oxabicyclo[4.1.0]hept-3-ene with reagents, such as RSCl, NaN3, and H2SO4/Ac2O, six 1,2,4,5-tetrasubstituted cyclohexane derivatives including S, O, N, Cl, and Br were selectively obtained. Formations and structures of the products were discussed.

  AtıfScopus6·WoS5·OpenAlex10

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