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- MakaleAçık Erişim2021Scopus SJRQ2Geochemistry and Pb isotopic proof for sources of heavy metal(loid)s in Late Cretaceous sandstones from Eastern Pontides (NE Turkey)
Saydam Eker, Çiğdem
Upper Cretaceous sedimentary rocks are widely exposed around Trabzon, Giresun and Gümüşhane in the eastern Pontides. The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trabzon, Giresun and Gümüşhane regions to identify the concentrations, sources, deposition environment and conditions of certain heavy metal(loid)s (Zn, Pb, Cu, Ni, As, Co, Mo and V). Enrichment factor (EF), geo-accumulation index (Igeo), Pollution index (Pi), Pollution load index (Pln), Pb isotope and multivariate statistical analysis were performed to elucidate the pollution levels and sources. In general, the evaluation indices exhibited that the sandstones were moderately polluted by As in the Trabzon area, and strongly polluted by Ni and As, moderately polluted by Co and V in the Giresun and Gümüşhane areas. The results of multivariate statistical analyses indicated that As and partly Pb might be originated from anthropogenic sources, whereas other metals were derived from geogenic origin. Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. The sandstones were deposited in transition—marine environment under oxic—weak oxic conditions and paleoclimatic conditions ranged from arid to moist during Late Cretaceous period.
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İncele - MakaleYalnız künye2021Scopus SJRQ2Assessment of the concentration and environmental impacts of potential hazardous elements in coalfields in Northeastern Turkey
Saydam Eker, Ç.; Sipahi, F.; Akpınar, I.
To investigate the impact of potential hazardous element (PHE) contamination on environmental and human health, the coaly shale, coal and shale coal outcrops of four sites, namely Ozyurt, Tarhanas, Kayadibi (Gümüşhane), and Manas (Bayburt), were selected as sampling areas for this study. The samples were analyzed using inductively coupled plasma (ICP) emission spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS) and a Rock–Eval 6 analyzer with a total organic carbon module. The enrichment factor (EF), potential ecological risk index (RI), and potential health risk index (HI) assessment models were used to evaluate the environmental and health risks in the vicinity of the coals. Results indicated that the mean concentrations of PHEs extensively changed and even exceeded the upper continental crust and world average values of low-rank coal concentrations. The assessment of the EF, RI and HI models revealed that the contamination levels of As, Hg, and Cd were higher than those of Pb, Co, Ni, V, and Mo. The evaluation of the EF revealed that the largest and lowest contamination levels of As, Hg, and Cd were observed in Ozyurt (29) and Kayadibi (1.8), Manas (9.6) and Kayadibi (1), and Kayadibi (5.6) and Tarhanas (1.9), respectively. A high-potential ecological risk was present in Ozyurt and Manas, whereas a considerable risk exists in Kayadibi and Tarhanas. The potential health risk values of As for children in Ozyurt, Tarhanas, and Manas and adults in Ozyurt were excessively high. This finding suggested the possibility of transferring the contamination from the coal, shale coal, and coaly shale outcrops
AtıfScopus5WoS4OpenAlex6İncele - MakaleYalnız künye2020Scopus SJRQ2Comparison of sandstone and mudstone with different methods for assessing toxic element contamination in the Early–Middle Jurassic sediments of Gümüşhane (NE Turkey)
Saydam Eker, Çiğdem; Arı, Uğur Volkan
To investigate the vertical changes of toxic elements in Jurassic sediments, sampling was performed in four sites. Samples were collected from sandstones and mudstones/marls and analyzed for some toxic elements (Cu, Pb, Zn, As, Ni and V). Results exhibited that the sediment grain size played a significant role in controlling the concentrations of the toxic elements in the sediments. The mean toxic element contents of mudstones/marls were higher than those of sandstones (except Cu). The contamination level of toxic elements was detected by enrichment factor (EF), geo-accumulation index (Igeo), potential ecological risk index (Eir), pollution index (Pi) and united pollution index (PIn). The low EF, Igeo, Eir, Pi and PIn for Cu, Pb, Zn, Ni, V in the sandstones and Cu, Zn, Ni in the mudstones/marls exhibited an absence of clear these elements pollution. The high EF, Eir, Pi and PIn for As (9.7, 73, 7 and 29, respectively, as mean values) in the sandstones and for As (49.3, 222, 22 and 75, respectively, as mean values) Pb (8.8, 24, 5 and 19, respectively, as mean values), V (8.3, 15, 7 and 39, respectively, as mean values) in the mudstones/marls indicated significant contamination. Additionally, according to the potential ecological risk (RI) values, the sandstones had low potential ecological risk for the toxic elements (RI < 150) and the mudstones/marls had moderate potential ecological risk (150 ≤ RI ≤ 300). The potential ecological risk As, Pb, V (especially As) were higher in urban areas than in agricultural activities. Therefore, the source of As, Pb, V could be gasoline combustion, burning coal and vehicle exhausts. The contents of these elements generally increased from bottom to top of the measured stratigraphic sections, which indicated transported by atmospheric conditions.
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