Yazarlar
Yayınlar
- MakaleYalnız künye2011Aromatisation in adducts of a-terpinene: Influence of hindered internal Rotations
Kaya, Afşin Ahmet; Şengül, Mehmet Emin; Menzek, Abdullah; Kayaardi, Ibrahim; Karakuş, Murat; Şahin, Ertan
Each adduct of α-terpinene with p-quinone and 1,4-naphthoquinone in Ac2O/Et3N at 180 °C gives two aromatic products, one of which had a distinctive smell formed by the loss of an ethylene group. Here, we report the crystal structure of (1RS, 4RS)-1-isopropyl-4-methyl-1,4-dihydro- 1,4-ethanoanthracene-9,10-diyl diacetate. It is crystallised in an orthorhombic space group, Pbca, with cell dimensions a = 10.2899(7), b = 19.7804(9), c = 19.7519(8) Å and Z = 8. According to its NMR and X-ray diffraction data, the isopropyl and acetate groups slowly rotate.