Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleYalnız künye2026Natural Radioactivity and Radiological Risk Assessment of Rocks Around the Mines: A Case Study From the Mastra and Hazine Mağara Mining Areas, Northeastern Türkiye
Sipahi, Ferkan; Çelik, Necati; Gücer, Mehmet Ali; Dizman, Serdar
This study presents a comprehensive assessment of natural radioactivity levels and associated radiological hazards in rock samples collected from Mastra and Hazine Mağara mining sites in the Gümüşhane province, Türkiye. The concentrations of primordial radionuclides (226Ra, 232Th, and 40K) were measured in samples of andesite, granite, and limestone using a High Purity Germanium (HPGe) detector. Complementary whole-rock geochemical analysis (XRF and ICP-MS) was conducted to understand the geochemical controls on radioactivity concentrations. The results reveal significant heterogeneity in activity concentrations both within and between the two sites. For 226Ra, the Hazine Mağara site exhibited a wider range (2.44–22.57 Bq kg−1) with a higher maximum value compared to Mastra (2.65–13.96 Bq kg−1). Similarly, 232Th and 40K activity concentrations showed considerable variability, often linked to the presence of specific accessory minerals like zircon, monazite, and K-feldspar. Geochemical data indicated that element concentrations (K, U, Th) were generally lowest in limestone and highest in granite, showing a strong correlation with the measured activity concentration values. Radiological risk indices, including radium equivalent activity, absorbed dose rate, annual effective dose equivalent, and excess lifetime cancer risk, were calculated. While values remain below international public health safety limits, localized anomalies were identified. Multivariate statistical methods were used to determine the relationship between the 226Ra, 232Th, 40K, Raeq (Bq/kg), Ig, Hex, D (nGy/h), AEDE (μSv/y), AGDE (μSv/y), and ELCR (×10−5). The study concludes that despite these localized anomalies, both mining areas pose an overall minimum environmental radiation risk, underscoring the necessity for site-specific assessments to ensure safe resource utilization and radiation protection.
- MakaleYalnız künye2026Mineralogical and geochemical controls on Co-V-Pt-Ni enrichment in manganese mineralization: evidence from the Dilli deposit, Eastern Türkiye
Gücer, Mehmet Ali; Çimen, Okay; Aktağ, Alican; Keskin, Serdar
The growing demand for critical minerals driven by the global energy transition and advanced technologies highlights the importance of unconventional metal reservoirs. This study investigates the Ni-, Co-, V-, and Pt-enriched Dilli manganese deposit (Kemaliye-Erzincan, Eastern Türkiye) to constrain the mineralogical, geochemical, and genetic controls on critical metal enrichment in Mn oxide mineralization. An integrated approach combining field observations, petrography, X-ray diffraction (XRD), whole-rock geochemistry, mineral chemistry, and stable C-O isotope analysis was applied to better understand the potential origin of critical mineral enrichments. The mineralization is dominated by Mn4+-bearing oxides, principally pyrolusite and hollandite, accompanied by minor rhodochrosite. High MnO (39-64 wt%) and very low Al2O3 and Fe2O3 contents indicate chemical precipitation with negligible detrital input. Discrimination diagrams and trace-element systematics consistently support a structurally controlled hydrothermal origin. Chondrite-normalized REE patterns display low total REE and very low Nd contents comparable to typical hydrothermal deposits, whereas neutral to slightly positive Ce anomalies and non-chondritic Y/Ho ratios suggest limited oxidative interaction with surface-derived fluids rather than primary marine hydrogenetic growth. Stable C–O isotope compositions of co-genetic calcite are inconsistent with a purely marine depositional environment and indicate precipitation from low-to moderate-temperature hydrothermal fluids. Mineral chemistry reveals strong phase-specific partitioning: hollandite preferentially incorporates V and Ba, whereas pyrolusite is enriched in Ni. Cobalt occurs in both phases, whereas Pt may also be present in both Mn oxide phases, suggesting that trace-element distribution is influenced by both crystallochemical and physicochemical controls. The enrichment of Ni, Co, and Pt is most plausibly linked to hydrothermal fluid circulation through ultramafic units, which likely acted as the primary metal source prior to precipitation. The Dilli deposit thus represents a structurally controlled hydrothermal Mn system enriched in critical metals, emphasizing the exploration relevance of Mn oxide mineral chemistry in identifying alternative sources of critical metals in Türkiye.
- MakaleYalnız künye2026Geochemical signature, detrital zircon U-Pb, and mica Ar-Ar age systematics from the Karadere Basement Unit of the İstanbul-Zonguldak Terrane (NW, Türkiye): evidence for an Avalonian-Cadomian active continental margin
Çimen, Okay; Gücer, Mehmet Ali; Göncüoglu, Mehmet Cemal; Akal, Cuneyt; Arslan, Mehmet; Simonetti, Antonio; Karaoglan, Fatih
The & Idot;stanbul-Zonguldak Terrane is located in northwest Anatolia and includes several outcrops with pre-Cambrian basement units. The Karadere Basement Unit represents the easternmost basement of this terrane and is composed of paragneiss, quartzite, and orthogneiss. The paragneiss and quartzite are cut by orthogneisses and disconformably overlain by Lower Ordovician to Middle Devonian cover units. Its pre-Cambrian to Palaeozoic tectonic evolution remains poorly understood, and therefore, this study reports whole-rock trace element signatures, detrital zircon U-Pb, and muscovite Ar-Ar age data for samples of paragneiss, quartzite, amphibolite, and orthogneiss. The whole-rock geochemical data indicate that the protoliths of the paragneiss and quartzite samples investigated here could have been derived from arc-related felsic magmatic units located in an active continental margin. The protoliths of amphibolites and orthogneiss samples are gabbro and granite, respectively, and their geochemical signatures are akin to those from continental arc igneous suites. The detrital zircon U-Pb data are characterized by predominantly Mesoproterozoic (84%) and lesser amount of Palaeoproterozoic and Neoproterozoic ages and suggest an early Tonian (youngest peak age of 915 +/- 18 Ma) maximum depositional age. Moreover, zircon U-Pb dating analyses from an orthogneiss sample yielded an age of 603 +/- 2 Ma, indicating the occurrence of mid-Ediacaran arc magmatism. This represents one of the oldest Ediacaran ages obtained from the metamagmatic basement rocks of the & Idot;stanbul-Zonguldak Terrane. Ar-Ar dating of muscovite from ortho- and paragneiss samples yielded ages of 533 +/- 25 Ma and 530 +/- 9 Ma, respectively, which are interpreted as early Cambrian cooling ages. Overall, the combined results reported here reveal that the Karadere Basement Unit is markedly different from NE African basement units but displays similarities to the basement rocks of both Avalonian and Amazonian terranes. It may have been formed and metamorphosed in an Avalonian-Cadomian active continental margin during the mid- to late Neoproterozoic and early Cambrian.
- MakaleAçık Erişim2025Mescitli Formasyonu’na (Gümüşhane, Türkiye) ait kumtaşlarının endüstriyel hammadde olarak kullanım potansiyelinin incelenmesi
Aliyazıcıoğlu, Şener; Dağ, Serhat; Zeybek, Halil İbrahim; Çavuşoğlu, İbrahim; Gücer, Mehmet Ali; Sipahi, Ferkan; Dokuz, Abdurrahman
Doğal zenginliklerin ortaya çıkarılması ve yöresel kayaçların ekonomiye kazandırılarak endüstriyel kullanım alanlarının belirlenmesi günümüzde büyük önem taşımaktadır. Bu çalışmada, Gümüşhane’deki Mescitli Formasyonu kumtaşlarının endüstriyel hammadde olarak kullanım potansiyeli araştırılmıştır. Kumtaşları başlıca monokristalin ve polikristalin kuvars, feldispat, volkanik ve tortul kayaç parçaları, opak mineral, kil matriks ve az oranda bağlayıcı karbonat/silis minerali içermektedir. Grovak (psammit) olarak sınıflandırılan kumtaşlarının kimyasal ayrışma indeksi (CIA) parametresine göre alterasyondan çok fazla etkilenmediği belirlenmiştir. Jeoteknik özellikler açısından, ortalama kuru yoğunluk 2.48 gr/cm3, doygun yoğunluk 2.54 gr/cm3, gözeneklilik %6.63 boşluk oranı %7.11, ultrasonik P-dalga hızı 4793 m/sn, tek eksenli basınç dayanımı 103.09 MPa ve dolaylı çekme dayanımı 5,86 MPa olarak belirlenmiştir. Donma-çözünme deneyi ile don kaybı %1.19 olarak belirlenmiş, 600-800ºC sıcaklıklara kadar ısıtılan kumtaşı numunelerinde ortalama 9.8 gr ve 17.9 gr kütle kaybı gözlenmiştir. Aynı sıcaklık koşullarında kumtaşlarının dayanımının sıra ile %7.64 ve %15.17 oranında azaldığı görülmüştür. Hücre Sitotoksisite analizlerinde toksik etkiye rastlanmamıştır. Sonuçlar, kumtaşlarının günlenmeye maruz kalacak alanlarda kullanım için uygun olmadığı, bina içyapı ve dekoratif amaçlı kaplamalarda kullanılabileceğini göstermiştir. Sıcaklık dayanımı ve hücre sitotoksisite analizleri ise kumtaşlarının ızgara taşı olarak kullanılabileceğini ortaya koymuştur.
- MakaleAçık Erişim2025Granodiyorit atıklarının demir oksitli sırlarda kullanımının araştırılması: estetik ve sürdürülebilirlik perspektifi
Arıanpour, Aslı Çakır; Gücer, Mehmet Ali; Isiktas, Imre Deniz; Özek, Serap Bedel; Helvacıkara, Fidan Tonza; Sipahi, Ferkan
Seramik üretimi, doğal hammaddelere dayalı çok aşamalı süreçler gerektirir. Ancak artan çevresel kaygılar ve hammadde kaynakların tükenmesi, alternatif hammadde arayışını ve atık yönetimini seramik endüstrisinin öncelikli konuları haline getirmiştir. Özellikle doğal taş endüstrisinde oluşan atıklar hem çevresel etkilerin azaltılması hem de ekonomik değer yaratılması açısından önemli fırsatlar sunmaktadır. Bu bağlamda, granitoyidik kayaçlar, özellikle demir oksit içeriği sayesinde seramik sırlarında estetik ve işlevsel katkı sağlayabilecek potansiyel bir atık malzeme olarak değerlendirilmiş ve Gümüşhane il merkezindeki bir mermer işletmesinden temin edilen granodiyorit atıklar, demir oksitli sırların renklendirici bileşeni olarak kullanılmıştır. Petrografik analizler sonucunda kayaç numuneleri granodiyorit, diyorit ve granit olarak sınıflandırılmış; özellikle biyotit ve hornblend gibi mafik mineralleri yüksek oranda içeren granodiyorit (H1) örneklerinde toplam Fe₂O₃ oranının %3,96 olduğu belirlenmiştir. Bu nedenle sır formülasyonlarında granodiyorit örneği esas alınmıştır. Beş farklı seramik bünye (kırmızı, şamot, döküm, porselen ve stoneware) üzerine uygulanan granodiyorit katkılı sırlar 1040°C–1100°C aralığında pişirilmiş ve özellikle aventurin etkili yüzeyler elde edilmiştir. Denemeler sonucunda, granodiyorit atıklarının sır yüzey özelliklerini, renklenme karakterini ve estetik niteliklerini olumlu yönde etkilediği gözlemlenmiştir. Elde edilen veriler, bu atık malzemenin seramik sektöründe hem sürdürülebilirlik hem de estetik çeşitlilik açısından değerli bir alternatif sunduğunu göstermektedir.
- MakaleYalnız künye2025Mantle genesis and crustal contamination in Carboniferous granitoids using U-Th-K concentrations at the Akşar Pluton in the Eastern Pontides, NE Türkiye
Maden, Nafız; Gücer, Mehmet Ali; Akaryalı, Enver
New radiogenic heat production (RHP) data are presented for Carboniferous granites outcropping in the Akşar region (Bayburt, NE Turkey) to contribute to ongoing debates on the genetic and lithologic relationship between the Akşar and Gümüşhane plutons, which is the most widely distributed granitic rocks in the region. The scope of this study consists of rocks composed of enriched mantle material metasomatized by fluids from the previously subducted plate. We observed average K value for the Akşar Pluton was found to be 3.09 ± 1.58 %. Additionally, average Th/U and U/Th values of 3.95 ± 1.37 and 0.29 ± 0.10, respectively. The calculated RHP value for the Akşar Pluton was 2.20 ± 0.56 μWm−3. Numerical results suggest that the Carboniferous Akşar pluton's primary magma was the product of mixing lithospheric mantle and mid-to-lower crustal melts because of partial melting, differentiation, and emplacement in the shallow continental magma chamber. The geochemical and petrogenetic characteristics of the Akşar region magmas suggest that crustal contamination occurred at multiple levels, particularly within the lower to middle crust of the plutonic core complex. This complex likely retains geochemical signatures indicative of subducted Paleotethys oceanic lithosphere. These findings provide critical insights into the magmatic evolution of the Eastern Pontides, contributing to a more comprehensive understanding of crust–mantle interactions and the broader geodynamic framework of northeastern Türkiye.
- MakaleYalnız künye2025Origin and tectonic setting of the carbonate-hosted Kopuz Fe skarn Deposit, Sakarya Zone, NE Türkiye
Sipahi, Ferkan; Akpınar, İbrahim; Gücer, Mehmet Ali; Kaygusuz, Abdullah; Vural, Alaaddin; Saydam Eker, Çiğdem
The Kopuz Fe skarn deposit in the eastern Sakarya Zone is genetically associated with the 44–45 Ma Kopuz granitoid. The Fe ores are hosted within the contact zone between this granitoid and Jurassic Lower Cretaceous limestone. The deposit is characterized by both endo- and exoskarn zones, which exhibit a diverse range of minerals including clinopyroxene, plagioclase, amphibole, biotite, garnet, epidote, phlogopite, magnetite, hematite, pyrite, quartz, calcite, actinolite, limonite, and goethite. Magnetite and hematite, accompanied by small amounts of pyrite, are primarily ore minerals. Pyroxene types observed in the mineralization include diopsidic hedenbergite in the endoskarn zone and diopside in the exoskarn zone. Plagioclase in the endoskarn zone vary from oligoclase to Labrador in composition, which transition towards Na-rich plagioclase and orthoclase in the ore-bearing exoskarn zone. Amphiboles, primarily calcic in nature, are classified as Mg-hornblende and actinolite, with low F and Cl contents, indicating minimal F enrichment during Fe-skarn formation. Garnet is characterized by andradite in the exoskarn zone close to the endoskarn and grossular-andradite in the distal exoskarn zone. The increase of Ad/Gr ratios in zoned garnet indicate an increasing ƒO2 value outward from it. Considering that rare pyrite occur together with magnetite and hematite, we suggest that the deposit formed under conditions of low ƒS2 and high ƒO2 conditions. The homogenization temperature and salinity of the fluid inclusions in quartz from the exoskarn zone vary from 224 °C to 349 °C and 4.18 % (wt% NaCl equiv.), respectively. The oxygen isotope composition (5.10 ‰ to 7.86 ‰) of the fluids in equilibrium with magnetite and quartz minerals in the exoskarn zone supports a magmatic fluid origin. The oxygen isotopic signatures of epidote and amphibole further indicate a minor interaction with an additional source, likely meteoric waters. The sulfur isotope composition of pyrite (2.3 ‰) is consistent with a magmatic sulfur source. In summary, the middle Eocene-aged Kopuz Fe skarn deposit occurred a shallow depth within a magmatic arc, where oxidized conditions predominated.
- MakaleAçık Erişim2025Geochronological and isotopic data from the adakitic Dodurga Pluton (Central Pontides, N Turkiye): new insights for the geodynamic evolution of the northern Neotethys
Çimen, Okay; Gücer, Mehmet Ali; Simonetti, Antonio; Karaoglan, Fatih
The Dodurga Pluton is located within the Central Pontides (northern Turkiye), has a SW-NE elongation, and consists of granodiorite and dacite porphyry. Previous studies have suggested that this pluton is Triassic in age, and its whole-rock geochemical systematics is consistent with that from adakitic magmatic occurrences rather than the classic arc granitoid suite. This study reports for the first time in situ/whole-rock radiogenic isotopic (Sr, Nd, and Pb) and mica/amphibole Ar-Ar age data to evaluate better its petrogenetic/geodynamic evolution and the chemical nature of mantle source(s). Unlike previous data, combined new in situ zircon U-Pb yield Late Cretaceous crystallization ages of 84.2 +/- 0.9 Ma and 86.9 +/- 0.9 Ma, and the Ar-Ar age data along with apatite fission track measurements suggest magma cooling extending to 82.3 +/- 0.4 Ma and 85.4 +/- 0.4 Ma, respectively. The apatite fission track (AFT) dating results also reveal that this pluton was buried at a depth of 2.5-3 km following a fast-cooling period during the Late Cretaceous and cooled/exhumed over similar to 2 km during the Middle-Late Miocene (15-10 Ma) in a slow cooling phase. The overall data reported here suggest that the Dodurga Pluton represents melts derived from an enriched/metasomatized mantle source that interacted with lower crustal mafic rocks in an active continental margin as a result of northward subduction of the northern branch of the Neotethys Ocean.
- MakaleAçık Erişim2024Erken Eosen yaşlı adakitik andezitler (Gümüşhane, KD Türkiye) içerisindeki mikrogranüler anklavların jeokimyasal karakteristikleri
Çimen, Okay; Gücer, Mehmet Ali; Güner, Abdulkadir Murat
Doğu Sakarya Zonu’ndaki (KD Türkiye) erken Senozoyik magmatizması, bölgesel tektonomagmatik gelişime dair önemli veriler sağlamaktadır. Bölgede, adakit veya adakitik intrüzif/ekstrüzif kayaçlar Geç Paleosen’den Pliyo-Kuvaterner döneme kadar yaygın olarak gözlenmektedir. Çalışma alanında, Erken Eosen adakitik andezitler, genellikle 10 km2’den küçük mostralar halinde gözlenmektedir. Adakitik bileşimli bu andezitler bol miktarda mikrogranüler anklav içermekte olup bu çalışmada petrografik/jeokimyasal özellikleri ve ana kayaç ile olan petrolojik ilişkileri irdelenmiştir. Ana kayaca kıyasla nispeten bazik bileşimli anklavlar, küreselden elipsoidala kadar değişen şekillerde ve birkaç cm ile 20 cm arasında değişen boyutlarda gözlenmektedir. Anklavlar mikrolitik yer yer porfirik dokulu olup başlıca plajiyoklas, hornblend, klinopiroksen, ortoklas ve opak minerallerden meydana gelmektedir. Gerek petrografik gerekse petrokimyasal özellikleri anklavların bazaltik andezit türünde olduğunu ve sub-alkalin bir magmadan türemiş olabileceğini göstermektedir. Ana ve iz element değişimleri, gelişimlerinde fraksiyonel kristallenmenin etkili olduğunu ve plajiyoklas, piroksen, hornblend, magnetit ve apatit ayrımlaşmasının büyük ölçüde rol oynadığını göstermiştir. Anklav ve ana kayaçların benzer iz element davranışları felsik ve mafik magmaların karışması esnasındaki etkileşim süreçlerini işaret edebilir. NTE dağılımları ise gelişimlerinde hornblend fraksiyonlaşmasının önemli rol oynadığını, buna karşılık plajiyoklas ayrımlaşmasının etkili olmadığını işaret etmektedir. Petrokimyasal veriler, anklavların ana magmasının, kuzey Neotetis Okyanusu’nun tamamen kapanmasından hemen sonra; genleşmeli tektonik rejimin başlangıç aşamalarında, amfibol-eklojit fasiyesi koşullarında okyanusal bazaltların kısmi erimesi ile üretildiğini göstermektedir.
- MakaleAçık Erişim2024Geochemical and petrological features of Carboniferous granites from the Güneydere (Bayburt) area
Gücer, Mehmet Ali; Delimehmet, Zeynep; Çimen, Okay
Middle-Late Carboniferousgranitic rocks are widely observed in larger outcrops in the Eastern Pontide orogenic belt of the Eastern Sakarya Zone. This tectonic belt is an important part of the Anatolian plate in terms of containing igneous rocks with a wide age and composition range. This study presents new petrochemical-petrological data on Carboniferous granites in the G & uuml;neydere and surrounding area of Bayburt (NE Turkey). The granitic rocks, which include an area of approximately 5 km, represent the pre-Jurassic basement in the study area. Besides, they are unconformably overlain by Early- Middle Jurassic volcano-clastics units and Late Jurassic- Early Cretaceous limestones. They mainly consist ofgranite, granite porphyry and aplite, to a lesser extent granodiorite and quartz monzonite. Rocks have high SiO2 contents (60.43-75.51%) and high K calc-alkali to shoshonitic affinities and have been derived from an I-type source. The granitic rocks are metalumine-peralumine in character and are similar to postcollisional volcanic arc granitoids. Whole-rocks major and trace element trends show that plagioclase, hornblende, biotite, apatite, and Fe-Ti oxide mineral fractionations play an important role in the formation of the rocks. It has been revealed that fractional crystallization and assimilation+magma mixing processes play a role in the development of granites. Also, the saturation temperatures calculated from the whole-rock zircon values reflect lower initial magma temperatures. All results obtained indicate that parental magma of studied granitic rocks have evolved from lower/middle crust- derived melts as a result of partial melting and differentiated and emplaced in the continental magma chamber.
- MakaleAçık Erişim2024Comparison with carbonate rocks hosted iron skarn in the eastern Sakarya Zone (Gümüşhane, NE Turkey): a geomorphologic, geochemical and stable isotopic approach
Sipahi, Ferkan; Zeybek, Halil İbrahim; Gücer, Mehmet Ali; Işık, Fatih
The carbonate rocks in the eastern part of NE Turkey are situated within the Pontide paleo-magmatic arc and are frequently in contact with granitoid formations, often hosting skarn mineralization in the region. These carbonate rocks, typically found on ridges and hillsides exhibit predominant orientations along east–west, northeast-southwest, and northwest-southeast directions. A part of limestone, named as biomicrite, metamorphosed and display a saccharoidal texture. Comprised mainly of calcite, with less secondary quartz and iron oxide minerals, these carbonate rocks are classified as Fe-poor calcio-carbonate and magnesio-carbonate, having higher CaO and LOI contents. Marble and recrystallized limestone with granoblastic texture mainly comprise of calcite, less quartz, magnetite, and hematite. Marble classification diagrams suggest calcic skarn mineralization, indicated by decreasing CaO (or CO2) and increasing MgO from limestone to marble (or skarn). Strontium contents deviate slightly from the lithosphere carbonate average, while low Rb contents, attributed to skarn metamorphism, indicate the absence of K-bearing minerals. The high Al2O3/SiO2 in the carbonate rocks can points out hydrothermal activity and carbonate disengagement can indicate to actualize at temperatures that can affect Ce and Al mobilities. The low authigenic U value, low U/Th and Ni/Co ratios in carbonate rocks have been implied that protolith constituents deposited under oxic conditions. Positive Eu anomalies in limestone and marble suggest the influence of hydrothermal fluids. Carbon and oxygen isotope values in marble are similar with those of metamorphic and skarn marbles, indicating a magmatic origin. Overall, mineralogical and geochemical analyses propose a uniform source and/or geological process for all studied marbles.
- MakaleAçık Erişim2023Köprüyanı (Maçka-Trabzon) Fe-Cu skarn cevherleşmesinin jeolojisi ve mineral kimyası özellikleri
Akaryali, Enver; Gücer, Mehmet Ali; Sivrikaya, Adem
Bu çalışmada, Doğu Pontidler’ in Kuzey Zonunda Trabzon ili sınırlarında Köprüyanı mevkiindeki Fe-Cu skarn cevherleşmesinin; jeolojisi, petrografisi, cevher mikroskobisi özellikleri ve mineral kimyası içeriklerinin belirlenmesi amaçlanmıştır. Köprüyanı cevherleşme sahasında, aktinolit, tremolit, pirit, kalkopirit, manyetit ve malakit mineralleri ile kırık çatlak zonları boyunca gelişmiş limonitleşme, hematitleşme kloritleşme ve epidotlaşma türü alterasyonlar gözlenmektedir. Manyetit minerallerinin genellikle kalkopirit, pirit ve granat ile birlikte bulunduğu, TiO2 içeriklerinin çok düşük (%0.02-1.02) olduğu buna karşılık FeOt içeriklerinin ise %83.13-92.00 arasında değiştiği belirlenmiştir. Manyetit ile beraber bulunan ve ekzoskarn zonunda yer alan kalkopirit minerallerinin Cu içeriğinin %33.50-43.27 ve Fe içeriği %29.84-39.11 arasında değiştiği belirlenmiştir. Epidot minerallerinin Al içeriklerinin yüksek (2.06-2.46), Mn içeriklerinin düşük (0.01-0.03) ve Fe+3 içeriklerinin ise nispeten yüksek (0.59-0.96) olduğu belirlenmiştir. Al bakımından zengin olan epidotların türünün ise klinozoisit olduğu tespit edilmiştir. Granat türleri ağırlıklı olarak andradit ve grossular-andradittir. Cevher mikroskobisi ve mineral kimyası çalışmaları kapsamında derlenen verilere bağlı olarak, Köprüyanı cevherleşmesinin Fe-Cu skarn tipinde olduğu ve bölgede var olan skarn cevherleşmelerinin parajenez, süksesyon ve mineral kimyası verileri ile benzerlik gösterdiği sonucuna ulaşılmıştır.
- MakaleAçık Erişim2023Geochemical and radiometric data for mafic rocks from the Guleman Ophiolite (SE, Turkey): New insights on the geodynamic evolution of the southern Neo-Tethyan ocean
Sapancı, Özgür; Tokat, Gürkan; Eraslan, Nuh Kadri; Karakaya, Abdullah Onur; Gücer, Mehmet Ali; Çimen, Okay
The Guleman Ophiolite is located in the southeast of Turkey and mainly consists of harzburgites and dunites hosting economically viable chromitite bodies, and lesser amounts of cumulate and isotropic gabbro, diabase dykes, pyroxenite and locally plagiogranite. This study reports the combined whole-rock geochemical and radiogenic isotope (Sr and Nd) data for gabbro and diabase dykes, and in-situ zircon U-Pb geochronological data for plagiogranite and gabbro from the Guleman Ophiolite. Two different geochemical groups were determined based on immobile minor and trace elements, and radiogenic isotope characteristics of gabbro and diabase dykes investigated here. The first group is represented by boninites and displays highly depleted elemental patterns compared to NMORB, and spoon-shaped rare earth element profiles. Contrarily, the second group resembles back-arc basin basalts and is characterized by NMORB-like rare earth element patterns associated with negative Nb anomalies. The boninitic samples are characterized by less radiogenic 143Nd/144Nd(i) (0.51229 to 0.51267; ƐNd = −4.8 to +2.7) and more radiogenic 87Sr/86Sr(i) (0.70549 to 0.70758) isotope compositions compared to the back-arc basin basalt-like samples (143Nd/144Nd(i) = 0.51289 to 0.51296; ƐNd = +7.0 to +8.4; 87Sr/86Sr(i) = 0.70496 to 0.70629), indicating derivation from distinct and/or heterogeneous mantle source regions within a supra-subduction zone. The LA–ICP–MS zircon U-Pb analyses yielded concordant late Cretaceous ages for gabbro (82 ± 2.9 Ma) and plagiogranite (79.9 ± 0.8 Ma) samples. The overall geochemical, isotopic and geochronological data presented here suggest that the Guleman Ophiolite consists of forearc and initial back-arc spreading sections of oceanic crust, which may have been formed in an intra-oceanic subduction zone within the Berit Ocean (northern branch of the southern Neo-Tethyan ocean). Moreover, the generation of continental arc magmatism (i.e. Baskil and Esence Granitoids) was well-documented on the active margin of the Malatya-Keban Metamorphics to the north. Therefore the closure of this oceanic basin should have resulted in multiple coeval northward subduction events during the late Cretaceous.
- MakaleYalnız künye2023The Sr, Nd, Pb and Hf isotopes and crystallization conditions of the middle Eocene Daǧdibi Pluton in the eastern Sakarya Zone, Turkey
Sipahi, Ferkan; Gücer, Mehmet Ali; Dokuz, Abdurrahman; Yi, Keewook; Kaygusuz, Abdullah; Akaryall, Enver; Saydam Eker, Çiǧdem; Doruk, Cüneyt
Magmatic activity in the Sakarya Zone, an important segment of the Alpine orogenic belt, continues intermittently from the middle Carboniferous to Miocene. In this study, we provide geochronological and geochemical data from the Daǧdibi Pluton in the eastern Sakarya Zone to present some inferences on the source region and petrogenesis of the middle Eocene magmatism. U-Pb zircon geochronology from two granodiorite samples gives middle Eocene ages of 44.75 ± 0.92 and 45.01 ± 0.59 Ma. The pluton is mainly composed of K-feldspar, plagioclase, quartz, Mg-hornblende/actinolite, Fe-Ti oxides and small amounts of biotite, and secondary chlorite and epidote. Parental magma of the intrusive rocks has a high-K calc-alkaline affinity with metaluminous character. The oxygen fugacity values vary between -18 and -17. The rocks show slightly radiogenic 87Sr/86Sr(i) (0.704845-0.705726) ratios and μNdi values between -0.96 and +0.52. Pb-Pb isotope ratios are typical for those of the lower continental crust. μHf(i) values of the zircons range from 0.14 to 10.26. The geochemical and isotopic features of the pluton point to a parental magma derived from a depleted mantle that was metasomatized by fluids during previous subduction events. The volumetric abundances of the rock types are decreased as the silica content increase, implying that the fractional crystallization is the most important process during the formation of the present compositional range of the pluton. Amphibole, plagioclase and Fe-Ti oxides are the fractionated phases while K-feldspar is largely accumulated. In the light of the data presented above, slab breakoff is regarded as the geodynamic process responsible for the formation of the Daǧdibi Pluton in the middle Eocene.
- MakaleAçık Erişim2023A study on the magnetite skarn mineralization (Gümüşhane, Türkiye): a magnetic survey
Sipahi, Ferkan; Sadiklar, M. Burhan; Gücer, Mehmet Ali; Aydin, Ali; Kara, Rasim Taylan
Iron (Fe)-skarn mineralizations (Çambaşı, Dereli, Eğrikar, Karadağ, Kopuz, Sekü, Donguldere, Arnastal, Özdil, Ögene, İkizdere, Ovit Dağı, Kartiba, etc.) in the eastern part of the Pontides (NE Türkiye) are accommodated in the Pontide paleomagmatic arc and the eastern part of the Pontides Metallogenic Belt containing numerous various deposits. Fe-skarn mineralization around the Arnastal Plateau (Gümüşhane-Türkiye) is fragmentary in this area, which is covered with plants (grasses, flowers, etc.). Thus, it was attempted to describe the subsurface structures and Fe mineralization using an interpretation of the available geological and existing magnetic data in this area. Granitoid and volcano-sedimentary series (Upper Cretaceous) outcrop in the study area. These volcanosedimentary series consist of limestone, sandy limestone, marl, andesite, quartz andesite, basalt, and their equivalent pyroclastics. They include a thin layer of the red limestone (Upper Cretaceous) and olistolith recrystallized limestones (Jurassic-Lower Cretaceous). Zigana granitoid, intruding into all of these rocks, is high-K calc-alkaline and metaluminous and is classified as quartz monzonite, monzogranite, granite, and syenogranite as a result of its modal composition. Contact pyrometasomatic mineralization occurs in between the limestone and granitoids in the Arnastal Plateau. In addition to petrographic and mineralogical studies, magnetic methods were applied to an area of approximately 10 km2 to find any covered Fe deposits. Magnetic susceptibility values measured on the outcropped rocks ranged from 1 to 34 (10–7 SI) for limestone, 78 to 3750 (10–7 SI) for basalt, and 105 to 3946 (10–7 SI) for granitoids. It is considered that these ranges express the alteration (physical or chemical) of the rocks, their homogeneity, and the lack or presence of Fe minerals. The magnetic survey was conducted along a study area measuring 12,075 m long with 25 and/or 50 m station spacing. Processing of the magnetic data revealed the presence of eight buried Fe ores that could represent either massive or disseminated mineralization between the Sarıtaş and Kurtdere plateaus. Magnetite ore bodies may be present from the surface to a depth of approximately 15–25 m inside the limestone. In addition to the identification of new magnetite ore mineralization or bodies, a new geological map was designed by determining probable formation boundaries with this magnetic survey.
- MakaleAçık Erişim2022Gold Mining, History and Today: The Case of Gümüşhane
Zeybek, Halil İbrahim; Akaryali, Enver; Çavuşoğlu, İbrahim; Gücer, Mehmet Ali; Sipahi, Ferkan
As in the history of humanity, the need for mines, causing important developments in human life, is gradually increasing. The mines, whose names are given to historical ages, have been a necessary source of raw materials for human beings to survive. Mines are one of the factors that directly affect the country's economy. Gold is a mine whose history is based on ancient history, its production has gained importance especially in recent years as a result of increasing demand and the research for new gold sources. Türkiye is a rich country with a 2% share in the world, with gold deposits of different geological characteristics and 431 ton reserves. Depending on the gold mining in recent years, gold explorations in Türkiye continue intensively and the annual gold production has increased to 39 tons in 2021. It has been determined that gold mining is concentrated in the Aegean and Marmara Regions with the Eastern Black Sea part in Türkiye. Gümüşhane is one of the provinces where gold mining is intense. In this study, the gold mining and importance in Gümüşhane are discussed by giving information about the history of gold mining.
- MakaleYalnız künye2022From Cadomian back-arc basin to Rheic Ocean closure: the geochronological records of the Kurtoglu Massif, eastern Sakarya Zone, Turkey
Dokuz, Abdurrahman; Gücer, Mehmet Ali; Karsli, Orhan; Yi, Keewook
New U-Pb zircon data from the Kurtoglu Massif (eastern Sakarya Zone, Turkey) reveal a Cadomian back-arc basin, evolving to closure of the Rheic Ocean. A host metapsammite from the lower tectonic slice of the massif yielded detrital zircon ages ranging from Neoarchean (2.73 Ga) to late Neoproterozoic with a major population between 610 and 553 Ma and a peak at 592 Ma, implying that the basement of the Sakarya Zone has a Cadomian affinity. This metasedimentary sequence was intruded by an orthogneiss in the early Ordovician (481 Ma) probably during the opening of the Rheic Ocean. Zircon grains from the overlying metasedimentary sample yielded concordant ages spreading throughout the Mesoproterozoic (1608-1032 Ma) and early Paleozoic (516-351 Ma), suggesting that they were deposited in the Rheic Ocean likely prior to its final closure. The muscovite metagranite, emplaced into the host rocks of the Kurtoglu Massif at 388 Ma, formed probably during northward closure of the Rheic Ocean. Zircon grains of a metasiltstone from the upper tectonic slice of the massif, represented mainly by phyllites, yielded similar age spectra to that of the host metapsammite of the lower tectonic slice. Such phyllites in the Pulur Massif similar to 35 km to the southeast display a close association with the ophiolitic complexes of the Rheic Ocean. This relationship together with the age spectra mentioned above suggests that sedimentation was on a place away from the Paleozoic igneous sources, in an analogous position to the southern passive margin of the Rheic Ocean.
- MakaleYalnız künye2022Eocene magmatism and associated Fe-Cu mineralization in northeastern Turkey: a case study of the Karadağ skarn
Sipahi, Ferkan; Saydam Eker, Çiğdem; Akpınar, İbrahim; Gücer, Mehmet Ali; Vural, Alaaddin; Kaygusuz, Abdullah; Aydurmuş, Tanju
The metallogenic belt containing numerous skarn mineralized systems starting from Eastern Europe continues through Turkey and Iran. The study area in the Eastern Pontides is within this metallogenic belt. The 44.39 ± 0.53 Ma Karadağ Intrusion sourced skarn mineralization is located along the granitoid-to-limestone contact. The Karadağ Intrusion is an arc-like pluton with medium–high K calc-alkaline and peraluminous–metaluminous affinity. The Karadağ Fe–Cu skarn mineralization (Gümüşhane, Turkey), an exoskarn, is hosted by Late Cretaceous limestone and consists of early garnet, clinopyroxene, and orthoclase with late epidote and chlorite. Primary ore minerals are magnetite and haematite, accompanied by minor amounts of chalcopyrite and pyrite. Pyroxene comprises mostly diopside and less hedenbergitic diopside and johannsenite. Wollastonite is very rare. Garnet is andradite and grossular–andradite. Thus, all these results imply that the Karadağ Fe–Cu skarn mineralization formed under relatively oxidized and Fe-rich conditions. The homogenization temperatures of the fluid inclusions vary from 189°C to 405°C for quartz and 186°C to 430°C for calcite. The salinity contents in the fluid inclusions are within 0.2–9 wt% NaCl equivalent for quartz and 0.4–14.8 wt% NaCl equivalent for calcite. First melting temperatures between −36.5 and −47.4°C were attained with the presence of NaCl–FeCl2± CaCl2 in the initial phase of fluid inclusions. The first melting in the later stage of fluid inclusions is between −3.8 and −17.2°C, thereby, supporting the existence of NaHCO3-Na2CO3-KCl-type salt composition. The δ18O values of minerals are 1.7–10.3‰ for garnet, 11.1–14.6‰ for quartz, 6.4 to 6.8‰ for epidote, and 2.8–3.8‰ for magnetite in the Karadağ skarn mineralization. The δ18O value of epidote indicates magmatic fluid, whereas those of garnet, magnetite, and quartz suggest magmatic fluids together with less meteoric effect. The δ18O values in limestone (18.7 to 22.3‰), marble (8.7‰), and calcite (10.5 to 12.2‰) were depleted relative to typical δ18O contents of marine carbonates (20 to 30‰). Moreover, the C isotope values of calcite (−5.4 to −1.4‰), marble (−2.1‰), and limestone (1.0 to 1.2‰) reflect those of metamorphic rocks and skarns (−4.0 to 3‰ and −18 to 2‰). Mineral paragenesis, fluid inclusion, and stable isotopic signatures are consistent with ore mineralization caused by the interaction of magmatic fluids with carbonate host rocks. Karadağ Fe-Cu skarn mineralization, associated with Karadağ postcollisional magmatism, is an example of skarn mineralized system in the Eastern Pontides.
- MakaleAçık Erişim2022Petrogenesis of post-collisional Middle Eocene volcanism in the Eastern Pontides (NE, Turkey): Insights from geochemistry, whole-rock Sr-Nd-Pb isotopes, zircon U-Pb and 40Ar-39Ar geochronology
Aydınçakır, Emre; Yücel, Cem; Ruffet, Gilles; Gücer, Mehmet Ali; Akaryalı, Enver; Kaygusuz, Abdullah
The debate about whether Eocene magmatism is considered to be post-collisional or subduction-related or not still continues. Here we offer new 40Ar-39Ar ad U-Pb zircon geochronology, mineral chemistry, bulk rock and Sr-Nd-Pb isotope geochemistry data obtained from the southern dike (SD) suite, in comparison with the northern dike (ND) suite, from the Eastern Pontides. The geochronological data indicate that the SD suite erupted between 45.89 and 45.10 Ma corresponding to the Lutetian (Middle Eocene). The magmas of the ND suite are characterised by slightly more alkaline affinity compared to the SD suite. The trace and rare earth element (REEs) content of the SD suite is characterised by large ion lithophile element (LILEs; Sr, K2O, Ba, Rb) enrichment and depletion of Nb, Ta, and TiO2 elements to different degree with high Th/Yb ratios, which indicate that the magmas forming the SD and ND suites were derived from lithospheric mantle sources enriched by mostly slab-derived fluids in the spinel stability field. The Sr, Nd and Pb radiogenic isotope ratios of the dikes support the view that the magma for the hydrous group (H-SD) was derived from a relatively more enriched mantle source than the other SD and ND suites. The ND suite and the anhydrous group (A-SD) display similar geochemical features characterised by moderate light earth element (LREE)/heavy rare earth element (HREE) ratios, while the H-SD group has respectively lower LREE/HREE ratios indicating higher melting degree. Detailed considerations of the alkalinity, enrichment and partial melting degree for the source of the studied volcanic rocks indicate that the magmas of the northern dike suite are characterised by slightly more alkaline affinity, whereas the magmas throughout the southern dike suite show increments in the enrichment rate and melting degree. In light of the obtained data and comparative interpretations, the geodynamic evolution and differences in petrogenetic character of the Lutetian magmas from both the northern and southern parts of the Eastern Pontides may be explained by different degrees of melting of a net veined mantle source initially metasomatized by mostly subduction fluids during asthenospheric upwelling due to fragmented asymmetric delamination in a post-collisional extensional tectonic environment.
- MakaleAçık Erişim202240Ar–39 Ar dating, whole-rock and Sr-Nd isotope geochemistry of the Middle Eocene calc-alkaline volcanic rocks in the Bayburt area, Eastern Pontides (NE Turkey): Implications for magma evolution in an extension-related setting
Kaygusuz, Abdullah; Yücel, Cem; Aydınçakır, Emre; Gücer, Mehmet Ali; Ruffet, Gilles
Discussions continue about whether Middle Eocene magmatism in the Eastern Pontides is associated with collision or subduction. This paper presents new whole-rock geochemistry, Sr-Nd isotopic and 40Ar-39Ar age data for Middle Eocene volcanic rocks from the Bayburt area of the Eastern Pontides (NE Turkey) to investigate their sources and evolutionary history. The new 40Ar–39Ar ages reveal that these volcanic rocks erupted between 44.6 ± 0.1 Ma and 43.5 ± 0.1 Ma, within the Lutetian (Middle Eocene). The studied volcanic rocks are composed of basalt, andesite, basaltic andesite and minor dacite lava and pyroclastic rocks. These rocks consist of plagioclase, amphibole, pyroxene, olivine, biotite, sanidine and minor quartz phenocrysts with Fe-Ti oxides. They have microlithic, hyalo-microlithic, porphyritic and rarely glomeroporphyritic textures. The volcanic rocks have low to high-K calc-alkaline affinities. They display enrichment in large-ion lithophile elements and depletion in high-field strength elements with high Th/Yb ratios, which indicate that the magmas forming the volcanic rocks were derived from lithospheric mantle sources enriched by mostly slab-derived fluids in the spinel stability field. 87Sr/86Sr(i) values vary between 0.70485 and 0.70551 and 143Nd/144Nd(i) values vary between 0.51255 and 0.51267. These data correspond to the mantle array on the isotope ratio diagram. The main solidification processes consist of fractional crystallization with minor assimilation. In light of the data obtained in this study together with data from previous studies, petrogenetic character of the Middle Eocene magmas from the southern parts of the Eastern Pontides may be explained by melting of an enriched lithospheric mantle source initially metasomatized by subduction fluids in a post-collisional extensional-related tectonic setting.