Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleYalnız künye2026Late Cretaceous hybrid melt sources and flare-up magmatism in the eastern Sakarya Zone, NE Türkiye: Zircon Hf-O constraints and implications for VMS fertility
Aydin, Faruk; Oguz-Saka, Simge; Karsli, Orhan; Dokuz, Abdurrahman; Moghadam, Hadi Shafaii; Zhao, Junxing; Schmitt, Axel K.
Understanding melt source evolution during arc-back-arc magmatism is essential for resolving crustal growth processes and the development of felsic-hosted volcanogenic massive sulfide (VMS) systems. Here we integrate new zircon HfO isotope data with published geochronological and whole-rock geochemical datasets to reassess the petrogenesis of Late Cretaceous arc and back-arc magmatic flare-ups in the eastern Sakarya Zone (ESZ), NE T & uuml;rkiye. Two high-flux magmatic episodes are recognized: a Turonian-Santonian pulse (similar to 92-86 Ma) forming the lower volcanic sequence (LVS), and a younger Campanian pulse (similar to 84-75 Ma) forming the upper volcanic sequence (UVS), accompanied by contemporaneous arc-related granitoids. Zircons from both LVS and UVS display predominantly positive epsilon Hf(t) values (+2 to +12) coupled with mantle-like delta O-18 (5.0-5.6 parts per thousand), but contain abundant inherited Mesoproterozoic-Paleozoic cores and show variable two-stage model ages (T-DM (c) = 0.4-1.4 Ga). Together with the peraluminous affinity of many felsic units, these features indicate that the dacite-rhyolite suites hosting VMS deposits were generated by melting of compositionally heterogeneous lower crust variably hybridized by juvenile basaltic inputs. Arc granitoids likewise record a transition from dominantly juvenile, I-type magmatism during the Coniacian-Santonian to more evolved, crust-influenced signatures during the Campanian. We propose that both flare-ups reflect repeated episodes of basaltic underplating and deep-crustal heating, producing voluminous felsic magmas capable of sustaining long-lived hydrothermal systems. The spatial and temporal coincidence between felsic-dominated flare-ups and VMS mineralization suggests that hybridized felsic magmas, rather than purely juvenile mantle melts, played a central role in generating the physiochemical conditions required for metal-bearing hydrothermal fluids in the ESZ.
- MakaleAçık Erişim2025Geçmişten Günümüze Gümüşhane’de Madencilik
Sukuroglu, Ebru Emine; Dağ, Serhat; Alemdag, Selcuk; Saylan, Kemal; Nazir, Bayram; Ozer, Ismail; Kurucu, Muhammet; Sipahi, Ferkan; Atalan, Öznur; Zeybek, Halil
Türkiye, madenler bakımından oldukça çeşitli ve zengin bir ülkedir. Ülkede yer alan bazı madenlerin dünya çapında önemli bir yere sahip olduğu bilinmektedir. Türkiye'nin Doğu Karadeniz bölgesinde bulunan Gümüşhane ili de madenler bakımından zengin bir çeşitliliğe sahiptir. Öyle ki, Gümüşhane’de var olan bu çeşitlilik ilk medeniyetlerin bölgeye hâkim olması ile önemli hâle gelmiş, şehirde bulunan madenlerin dışında şehrin İpek Yolu güzergâhında yer alması da bu bölgenin önemini daha da arttırmıştır. Hiç şüphesiz bu önem, Osmanlı Devleti’nin Trabzon’un fethi ile bölgeyi topraklarına katması ile devam etmiştir. Bu dönem ile birlikte şehirde madencilik faaliyetleri artmaya başlamış ve bu yönde yapılan çalışmalar ülkeye maddi anlamda katkı sağlamıştır. Bu açıdan Osmanlı Devleti, 16., 17. ve 18. yüzyıllarda bünyesinde barındırdığı başta gümüş ve altın madenleri olmak üzere diğer madenlerin varlığı nedeniyle ticari olarak canlı bir özellik gösteren Gümüşhane’ye büyük önem vermiştir. Böylece 17. yüzyılda adeta altın çağını yaşayan maden ocakları, 18. yüzyılın sonlarına kadar faaliyetlerini devam ettirmiştir. Bu yüzyıldan sonra da madenlerde yapılan üretim zamanla azalarak bölgedeki maden işletmelerinde çalışan işçiler madenleri terk etmeye başlamıştır. 19. yüzyılın ortalarına gelindiğinde maden ocaklarının işletilmesinde büyük oranda çözülme ortaya çıkmıştır. Yapılan bu çalışma; Gümüşhane şehrinin tarihî çağlar, Osmanlı Dönemi ve Cumhuriyetten günümüze kadar olan maden çalışmalarını ele alarak şehir ekonomisine birinci derecede yön veren madenlerin şehir açısından önemini ortaya koymayı amaçlamıştır. Çalışmada alan ile ilgili yapılmış çalışmalardan ve arşiv vesikalarından istifade edilmiştir.
- MakaleAçık Erişim2025Mescitli Formasyonu’na (Gümüşhane, Türkiye) ait kumtaşlarının endüstriyel hammadde olarak kullanım potansiyelinin incelenmesi
Aliyazıcıoğlu, Şener; Dağ, Serhat; Zeybek, Halil İbrahim; Çavuşoğlu, İbrahim; Gücer, Mehmet Ali; Sipahi, Ferkan; Dokuz, Abdurrahman
Doğal zenginliklerin ortaya çıkarılması ve yöresel kayaçların ekonomiye kazandırılarak endüstriyel kullanım alanlarının belirlenmesi günümüzde büyük önem taşımaktadır. Bu çalışmada, Gümüşhane’deki Mescitli Formasyonu kumtaşlarının endüstriyel hammadde olarak kullanım potansiyeli araştırılmıştır. Kumtaşları başlıca monokristalin ve polikristalin kuvars, feldispat, volkanik ve tortul kayaç parçaları, opak mineral, kil matriks ve az oranda bağlayıcı karbonat/silis minerali içermektedir. Grovak (psammit) olarak sınıflandırılan kumtaşlarının kimyasal ayrışma indeksi (CIA) parametresine göre alterasyondan çok fazla etkilenmediği belirlenmiştir. Jeoteknik özellikler açısından, ortalama kuru yoğunluk 2.48 gr/cm3, doygun yoğunluk 2.54 gr/cm3, gözeneklilik %6.63 boşluk oranı %7.11, ultrasonik P-dalga hızı 4793 m/sn, tek eksenli basınç dayanımı 103.09 MPa ve dolaylı çekme dayanımı 5,86 MPa olarak belirlenmiştir. Donma-çözünme deneyi ile don kaybı %1.19 olarak belirlenmiş, 600-800ºC sıcaklıklara kadar ısıtılan kumtaşı numunelerinde ortalama 9.8 gr ve 17.9 gr kütle kaybı gözlenmiştir. Aynı sıcaklık koşullarında kumtaşlarının dayanımının sıra ile %7.64 ve %15.17 oranında azaldığı görülmüştür. Hücre Sitotoksisite analizlerinde toksik etkiye rastlanmamıştır. Sonuçlar, kumtaşlarının günlenmeye maruz kalacak alanlarda kullanım için uygun olmadığı, bina içyapı ve dekoratif amaçlı kaplamalarda kullanılabileceğini göstermiştir. Sıcaklık dayanımı ve hücre sitotoksisite analizleri ise kumtaşlarının ızgara taşı olarak kullanılabileceğini ortaya koymuştur.
- MakaleAçık Erişim2025Paleolatitudinal movements of the eastern Sakarya Zone from Jurassic to Eocene
Kayın, Sercan; Hisarlı, Z. Mümtaz; İşseven, Turgay; Dokuz, Abdurrahman; Algur, Bahadırhan Sefa
The study area covers a region oriented north-south from the Black Sea coastline in the north to the Kelkit Basin in the south within the eastern Sakarya Zone in northern Türkiye. The objective of this study is to investigate the paleolatitudinal movements of the eastern Sakarya Zone during the Jurassic-Eocene time interval through paleomagnetism. Various volcanic and sedimentary units (e.g., the Şenköy, Berdiga, Mescitli, Çatak, Kızılkaya, and Çağlayan Formations) spanning the time interval from the Early Jurassic to Middle Eocene were identified. A total of 98 locations belonging to Early/Middle Jurassic to Eocene volcanic and sedimentary units were selected for paleomagnetic core sample collection. The samples were subjected to demagnetization through thermal and alternating field methods. Characteristic remanent magnetization directions (ChRM) were obtained. Isothermal remanent magnetization (IRM) and high temperature susceptibility (HTS) measurements were made to identify the minerals responsible for magnetization. To ascertain whether magnetization was acquired through rock formation or as a consequence of subsequent tectonic processes, conglomerate and fold tests were performed. The results showed that magnetization was acquired before folding, i.e., the rocks have primary magnetization. Polarity tests were also conducted using coeval normal and reverse polarity sites. The results indicate that the mean magnetization direction for the Early-Middle Jurassic is 18.1°/55.2° (D/I) and 3.3°/51.5° (D/I) for sedimentary and volcanic rocks, respectively, and 348.7°/46.7° (D/I) for Late Jurassic/Early Cretaceous sedimentary rocks. In the Late Cretaceous period, the mean magnetization direction is 8.0°/49.3° (D/I) and 9.1°/47.0° (D/I) for sedimentary and volcanic rocks, respectively. In the case of the Early/Middle Eocene, the mean magnetization direction is 348.6°/52.7° (D/I) and 5.9°/48.8° (D/I) for sedimentary and volcanic rocks, respectively. In this study, the E/I correction was applied to the Late Jurassic/Early Cretaceous sedimentary rocks, and paleolatitude data obtained from sedimentary rocks were also utilized. Our paleomagnetic results indicate that the eastern Sakarya Zone was situated at latitudes spanning from 27.9° to 35.7° during the Early Jurassic - Middle Eocene time interval. In consequence, the eastern Sakarya Zone constituted a portion of the southern margin of the Eurasian continent during the Late Jurassic and Middle Eocene periods.
- MakaleYalnız künye2023Post-Variscan autochthonous cover in the eastern Sakarya Zone, Turkey: Evolution of the late Carboniferous back-arc ocean to the Triassic Karakaya Ocean
Dokuz, Abdurrahman; Alçiçek, Mehmet Cihat; Tunçdemir, Vahdet; Kandemir, Raif; Aydinçakir, Emre
The processes that caused removal of the upper Carboniferous to Permian sediments in the eastern Sakarya Zone, Turkey, are modeled by using of geochemical data and LA-ICP-MS U-Pb ages from detrital zircons. A felsic provenance and passive margin setting during the deposition of the upper Carboniferous catalcesme sediments are inferred from the geochemistry of sandstones (SiO2 > 85 wt%). Chemical Index of Alteration (CIA) values (75 - 81) indicate warm and humid climatic conditions and tectonic tranquility during deposition. Fifty-three (58%) concordant zircon grains produce a youngest age population in the range of 308.7 +/- 4.4 to 342.1 +/- 6.9 Ma, typical for the Variscan events. The burgundy color and upward-fining in clast size and bed thickness are the most prominent features of the concordantly overlying Hardisi Formation. Geochemistry (SiO2 = 66-81 wt%) and CIA values (58-65) of the clastic rocks point to a subduction-related tectonic setting and increasing rate of erosion in the source area. We highlight that the catalcesme sediments were deposited in a back-arc basin opened to the south of a continental ribbon separated from Gondwana. Approaching of the Paleotethyan mid-ocean ridge to the subduction zone was resulted in flattening in subducting slab, which in turn caused the back-arc basin to migrate into the interior parts of Gondwana and the former back-arc basin to evolve into a lacustrine setting. Increase in the elevation of source areas was resulted in an increase in the rate of physical erosion and trans-portation of burgundy Hardisi clastic sediments into the lacustrine basin.
- MakaleYalnız künye2023The Sr, Nd, Pb and Hf isotopes and crystallization conditions of the middle Eocene Daǧdibi Pluton in the eastern Sakarya Zone, Turkey
Sipahi, Ferkan; Gücer, Mehmet Ali; Dokuz, Abdurrahman; Yi, Keewook; Kaygusuz, Abdullah; Akaryall, Enver; Saydam Eker, Çiǧdem; Doruk, Cüneyt
Magmatic activity in the Sakarya Zone, an important segment of the Alpine orogenic belt, continues intermittently from the middle Carboniferous to Miocene. In this study, we provide geochronological and geochemical data from the Daǧdibi Pluton in the eastern Sakarya Zone to present some inferences on the source region and petrogenesis of the middle Eocene magmatism. U-Pb zircon geochronology from two granodiorite samples gives middle Eocene ages of 44.75 ± 0.92 and 45.01 ± 0.59 Ma. The pluton is mainly composed of K-feldspar, plagioclase, quartz, Mg-hornblende/actinolite, Fe-Ti oxides and small amounts of biotite, and secondary chlorite and epidote. Parental magma of the intrusive rocks has a high-K calc-alkaline affinity with metaluminous character. The oxygen fugacity values vary between -18 and -17. The rocks show slightly radiogenic 87Sr/86Sr(i) (0.704845-0.705726) ratios and μNdi values between -0.96 and +0.52. Pb-Pb isotope ratios are typical for those of the lower continental crust. μHf(i) values of the zircons range from 0.14 to 10.26. The geochemical and isotopic features of the pluton point to a parental magma derived from a depleted mantle that was metasomatized by fluids during previous subduction events. The volumetric abundances of the rock types are decreased as the silica content increase, implying that the fractional crystallization is the most important process during the formation of the present compositional range of the pluton. Amphibole, plagioclase and Fe-Ti oxides are the fractionated phases while K-feldspar is largely accumulated. In the light of the data presented above, slab breakoff is regarded as the geodynamic process responsible for the formation of the Daǧdibi Pluton in the middle Eocene.
- MakaleAçık Erişim2023Ordovician S-type granites in the western Sakarya Zone, NW Turkey; linkage to a back-arc setting
Karsli, Orhan; Sengun, Firat; Aydin, Faruk; Moghadam, Hadi S.; Dokuz, Abdurrahman; Griffin, William L.; Saka, Simge Oguz; Zack, Thomas
Turkey's Early Paleozoic tectonic evolution has received much attention in recent years. Early Paleozoic intrusive rocks are mainly distributed across Europe, Turkey (Istanbul-Zonguldak Zone, Strandja Zone, and Tauride Block), and Iran. However, the Early Paleozoic rocks have not yet been identified in north Turkey's Sakarya Zone, and thus the Early Paleozoic paleogeography of the Sakarya Zone remains enigmatic. Here, we provide new field observations, petrography, geochemistry, and geochronology of the western Sakarya Zone to identify the nature, origin, and tectonic setting of the Ordovician magmatic rocks cropping out in the So center dot gut area (Bilecik, northwest Turkey). Our Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) U-Pb analyses on zircons suggest that the So center dot gut metagranites were emplaced at-484-461 Ma (except two zircons with ages of 490 and 494 Ma). There are abundant inherited zircon cores in the So center dot gut metagranites, with ages of >500 Ma to-2.2 Ga. The inherited Cadomian cores give concordant ages of 588 and 572 Ma. The So center dot gut metagranites are felsic and have high SiO2 (72-76 wt%) and K2O (4.1-5.3 wt%) contents, with high K2O/Na2O ratios (1.2-1.9), and low Mg# (17-35) values. The samples are Ca-poor (CaO = 0.52-0.68 wt%) and show peraluminous [A/CNK = molar Al2O3/(K2O + CaO + Na2O) = 1.15-1.28] and high-K calc-alkaline geochemical characters, with high modal content of muscovite (-10%), consistent with S-type compositions. The samples have low REE concentrations, with negative Eu anomalies. Ordovician zircon rims show epsilon Hf(t) values of +3.6 to-35.4, whereas inherited zircon cores have epsilon Hf(t) values of +33.9 to-26.1. Our data, in conjunction with previous studies, suggest that the So center dot gut metagranites were generated by fluid-absent muscovite-dehydration melting of metasediments accumulated in a back-arc setting. This back-arc basin was characterized by a denuded continental crust with abundant pelite-dominated sediments and minor input of juvenile mafic melts. Our results, combined with previously published data and paleogeographic reconstructions, allow us to conclude that the Ordovician S-type granites were formed by progressive back-arc extension and crustal thinning prompted by the rollback of the southward subducting oceanic-lithosphere slab. This led to the opening of the Rheic Ocean on the northern side of Gondwana in response to the final closure and termination of the Tornquist Ocean as a branch of the Iapetus Ocean. We argue that the Ordovician S-type granites from the northern side of Gondwana could signal significant crustal reworking away from any clear continental collision zone.
- MakaleYalnız künye2023Two-stage bimodal volcanism in a Late Cretaceous arc/back-arc setting, NE Turkey: Constraints from volcano-stratigraphy, zircon U-Pb and 40Ar/39Ar geochronology and whole-rock elemental and Sr-Nd-Pb isotope geochemistry
Oguz-Saka, Simge; Aydin, Faruk; Karsli, Orhan; Dokuz, Abdurrahman; Aiglsperger, Thomas; Miggins, Daniel P.; Sen, Cuneyt; Kandemir, Raif; Sari, Bilal; Koppers, Anthony A. P.
The eastern Blacksea magmatic arc (EBMA) in the eastern Sakarya Zone (ESZ) provides an excellent opportunity to investigate birth of an extensional intra-arc and back-arc settings in the Late Cretaceous over the Early Cretaceous northern passive margin of the Neotethys Ocean. Volcano-stratigraphy clearly shows that the Late Cretaceous volcanic activity of the EBMA occurred in two major phases. Bimodality, characterized by mafic/ basaltic rocks at the base and felsic/silicic types on top of it, is a typical feature of the lower (LVS) and upper (UVS) volcanic successions in the Giresun region of the ESZ. U-Pb and Ar-Ar ages support the volcanic suc-cession as two-stage (LVS: ca. 92-85 and UVS: ca. 83-67 Ma) bimodal volcanism. Both the volcanic successions are represented by similar rock types consisting of tholeiitic to calc-alkaline basalt-basaltic andesites and calc-alkaline to shoshonitic dacite-rhyolites. Basaltic (M1-and M2-series) and felsic/silicic (F1-and F2-series) sam-ples of the LVS and UVS have an arc-like signature with enriched large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depleted high field strength elements (HFSEs). Also, the felsic/silicic samples of the F1-and F2-series show prominent negative Sr and Eu anomalies (Eu/Eu* = 0.4 to 0.9), suggesting that plagioclase fractionation played a key role on the evolution of both felsic series. Bimodal rock series in two phases have a wide range of 87Sr/86Sr(i) (0.7048-0.7075) and 143Nd/144Nd(i) (0.5123-0.5127) ratios with var-iable epsilon Nd(i) values of-3.8 to +3.0. 206Pb/204Pb(i), 207Pb/204Pb(i) and 208Pb/204Pb(i) isotope ratios of the Giresun volcanic rocks vary in the range of 17.97-18.52, 15.55-15.65 and 37.53-38.56, respectively. Geochemical and isotopic data suggest that the parental magma of the M1-basaltic rocks were probably derived from a shallow (spinel-bearing) mantle metasomatized by slab/sediment-derived fluids. In contrast, the M2-basalts seem to have been originated from a deeper mantle source (spinel-garnet transition zone) enriched by slab/sediment-derived fluids and hydrous melts (bulk sediment) metasomatism with some contributions of lower/upper crustal materials. The least evolved basaltic samples in two phases are consistent with moderate (-10-15%) to high degree (-20-30%) partial melting of the metasomatized mantle. The silicic melts of the F1 -and F2-rocks series, on the other hand, were likely derived from melting of lower crustal materials consisting of meta-basalts/andesites and lesser amount of meta-sediments. Subsequently, these melts experienced FC +/- AFC and mixing processes during their ascent and emplacement to generate high-silica (rhyolitic) melts. Our data, combined with previous studies, suggest that two-stage bimodal volcanic rocks of the Late Cretaceous in the ESZ were formed in the transition from an extensional continental intra-arc to a back-arc setting during the north-ward subduction of the northern branch of Neotethys Ocean.
- MakaleYalnız künye2022From Cadomian back-arc basin to Rheic Ocean closure: the geochronological records of the Kurtoglu Massif, eastern Sakarya Zone, Turkey
Dokuz, Abdurrahman; Gücer, Mehmet Ali; Karsli, Orhan; Yi, Keewook
New U-Pb zircon data from the Kurtoglu Massif (eastern Sakarya Zone, Turkey) reveal a Cadomian back-arc basin, evolving to closure of the Rheic Ocean. A host metapsammite from the lower tectonic slice of the massif yielded detrital zircon ages ranging from Neoarchean (2.73 Ga) to late Neoproterozoic with a major population between 610 and 553 Ma and a peak at 592 Ma, implying that the basement of the Sakarya Zone has a Cadomian affinity. This metasedimentary sequence was intruded by an orthogneiss in the early Ordovician (481 Ma) probably during the opening of the Rheic Ocean. Zircon grains from the overlying metasedimentary sample yielded concordant ages spreading throughout the Mesoproterozoic (1608-1032 Ma) and early Paleozoic (516-351 Ma), suggesting that they were deposited in the Rheic Ocean likely prior to its final closure. The muscovite metagranite, emplaced into the host rocks of the Kurtoglu Massif at 388 Ma, formed probably during northward closure of the Rheic Ocean. Zircon grains of a metasiltstone from the upper tectonic slice of the massif, represented mainly by phyllites, yielded similar age spectra to that of the host metapsammite of the lower tectonic slice. Such phyllites in the Pulur Massif similar to 35 km to the southeast display a close association with the ophiolitic complexes of the Rheic Ocean. This relationship together with the age spectra mentioned above suggests that sedimentation was on a place away from the Paleozoic igneous sources, in an analogous position to the southern passive margin of the Rheic Ocean.
- MakaleAçık Erişim2022Late Jurassic Paleotethyan oceanic slab break-off revealed by Sr-Nd-Hf isotopes of Na-rich adakitic granites from northwestern Turkey
Karsli, Orhan; Şengün, Fırat; Santos, José Francisco; Uysal, İbrahim; Dokuz, Abdurrahman; Aydin, Faruk; Kandemir, Raif
The Mesozoic geodynamic evolution of the Paleotethys Ocean is critical but a poorly known piece of the geological history of the Sakarya Zone, north Turkey. Here, we describe new integrated research of zircon U-Pb geochronology, bulk-rock major-trace element and Sr–Nd isotopes as well as Hf isotope of zircons from the granitic rocks of the Demirköy and Kızıldamlar plutons located in Bilecik area along the western Sakarya Zone, northwestern Turkey. Zircon U–Pb ages obtained by LA-ICP-MS reveal that the granitic magma intruded into the basement rocks during the Late Jurassic (ca. 162–157 Ma). The granites are tholeiitic and show slightly metaluminous to peraluminous geochemical affinities. The granite samples are adakitic, having relatively high Na2O (6.35–7.58 wt%) and Sr (172–580 ppm), and low K2O (0.39–1.13 wt%) and Y (3.2–5.3 ppm), and thus have high Sr/Y (70–250). The samples exhibit enrichment of light rare earth elements (REE) and large ion lithophile elements (LILE) and depletion in heavy REE and the high field strength elements (HFSE; e.g., Nb, Ti, Ta). The samples possess low 87Sr/86Sr(t) values of 0.70313 to 0.70372, and εNd(t) of −0.66 to +9.24. Zircon grains exhibit positive εHf (t) values of 5.0 to 12.8 and depleted mantle model ages of Hf (TDM1 = 0.24 to 0.68 Ga). These geochemical features and Sr–Nd–Hf radiogenic isotope systematics reveal that the adakitic rocks were likely formed by low degree melting (<10%) of the eclogitic part of an oceanic slab and subsequent melt fractionation and crustal contamination. An ongoing subduction scenario cannot explain the formation of the investigated adakitic rocks. We suggest that the adakitic plutons were generated through slab break-off after the final closure of the Paleotethys Ocean throughout the Late Jurassic (ca. 162–157 Ma). Considering the previous data, the continental back-arc basin system, leading to the opening of Neotethys Ocean at the southern margin of the continent, has been put forward to decipher the Late Jurassic tectonic evolution of the Paleotethys Ocean and the western Sakarya Zone.
- MakaleYalnız künye2022Early Cambrian S-type granites in the Sakarya Zone, NE Turkey: A record for transition from subduction to post-collisional extension deduced from U-Pb zircon age and Nd-Hf isotopes
Karsli, Orhan; Sengün, Firat; Dokuz, Abdurrahman; Aydin, Faruk; Kandemir, Raif; Kristoffersen, Magnus; Santos, Jose Francisco; Hofmann, Mandy; Duygu, Levent
Cadomian realms have recently received much attention in the Alpine-Mediterranean orogenic belts, with discontinuous outcrops extending from the Alps to the Istanbul Zone, Menderes Massif, Taurides in Turkey and Iran as well. However, they have not been identified in the Sakarya Zone, northern Turkey to date. Here, we present, for the first time, zircon U-Pb geochronology, zircon Hf-isotopes and trace elements as well as whole-rock geochemistry and Nd-isotopes from the Karamese metagranitoid in the Yusufeli (Artvin) area, NE Turkey. The zircon U-Pb age data demonstrate that the Karamese metagranitoid intruded into the Precambrian basement units in the Early Cambrian (ca. 534-530 Ma). Zircon overgrowths in the Karamese metagranitoid interpreted as a result of metamorphic overprint yielded ages of 328 Ma. This age indicates that the Sakarya Zone experienced the Variscan metamorphic events at 328 Ma. The Early Cambrian metagranitoid shows that some rocks in the basement of the Sakarya Zone date back to Precambrian in age. The Karamese metagranitoid is an S-type granite, with high modal content of muscovite (similar to 10%). The samples show highly peraluminous [A/CNK = molar Al2O3/(CaO + K2O + Na2O) = 1.34-1.58] and medium-K calc-alkaline geochemical affinities. The Karamese metagranitoid displays low REE concentrations and a slight positive Eu anomaly and show slightly light REEs and LILEs enrichments, and HFSEs depletions. The samples have negative epsilon(Nd)(t) of -4.76 to -2.90 and epsilon(Hf) (t) of -4.75 to -1.08 values. These geochemical-isotopic characteristics reveal that the Karamase metagranitoid originated through fluid-absent muscovite dehydration melting of heterogeneous metasedimentary source rocks (mostly greywacke), with a minor input of juvenile mafic melt. We argue that the Early Paleozoic metagranitoids along the eastern Sakarya Zone is an expression of crustal thinning in the Cadomian orogenic belt in northern Gondwana, with the tectonic turnover from convergent margin to crustal extension possibly induced by break-off of Tornquist oceanic lithosphere which is a branch of Iapetus Ocean during Early Cambrian.
- BildiriYalnız künye2022Magmatic, tectonic and metallogenic evolution of the Eastern Pontides, Turkey: a protracted or discrete construction of the crustal fertility?
Turlin, Francois; Moritz, Robert; Sönmez, Safak Utku; Keskin, Serdar; Karsli, Orhan; Aydin, Faruk; Ulyanov, Alexey; Dokuz, Abdurrahman; Christie, AB
Even though mechanisms of crustal growth and differentiation are well known, the spatial and temporal evolution of the composition of the continental crust remains poorly constrained, even more when considering the metal budget in mountain belts. In this study, we use the Eastern Pontides, NE Turkey, as a natural laboratory to decipher the role of successive tectono-magmatic events during the buildup of the continental crust fertility. This area is a Gondwana-derived terrane that accreted to the Eurasian margin. It underwent successive orogenic phases associated with the closure of the Paleo- and Neotethys oceans, and lastly the Alpine orogeny. It hosts abundant volcanogenic massive sulfide, porphyry and epithermal deposits, mostly formed in the latest stages of arc construction. These features relative to the buildup of metal fertility in this continental crust raise questions such as were the physico-chemical conditions during the early sterile history of the Eastern Pontides unfavorable to form ore deposits or were the metals progressively concentrated in the crust during successive orogenic events? We will use whole-rock geochemistry, U-Pb zircon dating, and Hf-O isotopic and trace element compositions of magmatic zircons to constrain the construction of the continental crust in the Eastern Pontides, and its metal fertility through time.
- MakaleYalnız künye2021Nature of the Early Cretaceous lamprophyre and high-Nb basaltic dykes, NE Turkey: Constraints on their linkage to subduction initiation of Neotethyan oceanic lithosphere
Karsli, Orhan; İlhan, Mehdi; Kandemir, Raif; Dokuz, Abdurrahman; Aydin, Faruk; Uysal, İbrahim; Duygu, Levent
Late Mesozoic evolution of the Neotethys Ocean is critical and still remains unclear along the entire Sakarya Zone (SZ), Turkey, because previous interpretations of the Middle to Late Jurassic rifting of the SZ have not been consensually accepted. We identified, for the first time, the Early Cretaceous dykes intruded into the Late Jurassic and Late Carboniferous bodies in the Çamlıkaya (Erzurum) area in the SZ. Here, we present a data set of new field observations, 40Ar/39Ar geochronology, whole-rock geochemical and Sr–Nd isotopes to find out the tectonic setting of previously undated basic to intermediate igneous rocks. 40Ar/39Ar technique on the groundmass separations yielded the plateau ages of 128.78 ± 1.02 to 122.89 ± 0.82 Ma. The investigated dykes are compositionally divided into two sub-groups: calc-alkaline lamprophyres (CAL) and high-Nb alkaline basalts (HNB). They show enrichment in large ion lithophile elements (LILE: e.g., Rb, Ba, K) and depletion in high field strength elements (HFSE: Nb and Ti) as well as moderate fractionation of light rare earth elements relative to heavy rare earth elements. The HNB have high Mg# (47–66), and relatively unradiogenic Sr [87Sr/86Sr(t) = 0.70385 to 0.70510] and Nd [εNd(t) = +0.5 to +5.3] isotopic composition, whereas the CAL possess moderate to high Mg# (32–72), and relatively high Sr [87Sr/86Sr(t) = 0.70586 to 0.71379] and Nd [εNd(t) = +1.5 to −9.9] isotopic composition. Early Cretaceous high-angle subduction triggered upwelling of the asthenosphere at 126 Ma, which likely generated a heat anomaly. This anomaly has probably induced melting of the oceanic slab and the metasomatized mantle to form the CAL and HNB. The HNB were generated by low degrees of melting of mantle domain that was previously reacted by oceanic slab-related adakitic melts at the depths of the garnet stability field (≥70 km). However, the CAL were probably formed at shallower mantle levels within the garnet-amphibole field by a relatively higher degree of melting of the mantle, also modified by subducted slab sediments. A new field, age, and petrochemical data from the Early Cretaceous dykes, combined with the presence of Aptian deep-water sediments to the north and the Late Jurassic-Early Cretaceous platform carbonates deposited in the passive margin setting along the entire SZ, imply the initiation of active-margin magmatism in the SZ. We suggest that the coexistence of the Early Cretaceous CAL and HNB points to the formation of an Andean-type active margin above a north-dipping Neotethyan oceanic slab. Their emplacement ages are associated with the inception of the magmatic arc structure and refer to a significant geodynamic turnover from passive-margin to active-margin tectonics along the SZ.
- MakaleYalnız künye2020Temporal, geochemical and geodynamic evolution of the Late Cretaceous subduction zone volcanism in the eastern Sakarya Zone, NE Turkey: Implications for mantle-crust interaction in an arc setting
Aydin, Faruk; Oğuz Saka, Simge; Şen, Cüneyt; Dokuz, Abdurrahman; Aiglsperger, Thomas; Uysal, İbrahim; Kandemir, Raif; Karslı, Orhan; Sarı, Bilal; Başer, Rasim
The Late Cretaceous Artvin volcanic rocks (LCAVs) from the eastern Sakarya zone (ESZ) of NE Turkey are composed of mafic/basaltic (S1-Çatak and S2-Çağlayan) and felsic/acidic (S1-Kızılkaya and S2-Tirebolu) rock types that occurred in two successive stages: (i) first stage (S1: Turonian–Early Santonian) and (ii) second stage (S2: Late Santonian–Campanian). Clinopyroxene thermobarometric results point that the S2-Çağlayan basaltic rocks have crystallised at higher temperatures and under deeper crustal conditions than those of the S1-Çatak basaltic rocks. The LCAVs show a wide compositional spectrum, ranging from tholeiite to calc-alkaline/shoshonite and are typically represented by a geochemical composition resembling subduction-related arc rocks although the 87Sr/86Sr(i) (0.7044–0.7071) and ɛNd(i) values (−0.63 to + 3.47) as well as 206Pb/204Pb(i) (18.07–18.56), 207Pb/204Pb(i) (15.57–15.62) and 208Pb/204Pb(i) (37.12–38.55) ratios show very limited variation. The parent magmas of the S1-Çatak and S2-Çağlayan mafic volcanic rocks were derived from underplated basaltic melts that originated by partial melting of metasomatised spinel lherzolite and spinel-garnet lherzolite, respectively. It is proposed that the compositions of the S1-Kızılkaya (mainly dacitic) and S2-Tirebolu (rhyolitic to trachytic) felsic rocks were particularly controlled by metasomatised mantle–crust interaction and MASH zone + shallow crustal fractionation processes. Our data, together with data from previous studies, suggest that the S1- and S2-mafic and felsic rocks of the LCAVs (~95–75 Ma) are the products of two-stage volcanic event that took place during the northward subduction of the northern Neotethys Ocean (NNO).
- MakaleAçık Erişim2020Tracking the timing of Neotethyan oceanic slab break-off: Geochronology and geochemistry of the quartz diorite porphyries, NE Turkey
Karsli, Orhan; Dokuz, Abdurrahman; Aydin, Faruk; Uysal, Ibrahim; Sengün, Firat; Kandemir, Raif; Santos, Jose Francisco; Andersen, Tom
The initiation of the break-off of the northern branch of the Neotethyan oceanic lithosphere is an important but poorly understood event in the geology of the Sakarya Zone (SZ) in northeastern Turkey. Although it is wellknown that Latest Cretaceous intrusives (-70 Ma) and early Eocene adakitic magmatic rocks are present in the eastern SZ, the outcrops of the early Eocene non-adakitic rocks are very limited, and their tectono-magmatic evolution has not been studied. We describe a small outcrop of non-adakitic quartz diorite porphyry in the Kov area of the Gumushane region in northeastern Turkey. The genesis of these porphyries is significant in evaluating the syn-to post-collision-related magmatism. The LA-ICP-MS zircon U-Pb dating revealed that the Kov quartz diorite porphyries (KQDP) formed at ca. 50 Ma, coeval with adakitic rocks, and-20 Myr later than the slab rollback-related intrusive rocks. The KQDPs are calc-alkaline in composition and enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depleted in high field strength elements (HFSEs; e.g., Nb, Ta, Ti), with significant negative anomalies of Nb, Ta, and Ti but positive anomalies of Th, U, and Pb. Isotopic compositions of the samples show limited range of variation and slight enrichment of 87Sr/86Sr(t) (0.70489 to 0.70555), epsilon Nd(t) (-1.4 to -1.2) with TDM of 1.11 to 1.61 Ga. Pb isotopic ratios of the samples point to an enriched mantle source. They were likely crystallized from the melt that originated from an EM2-type spinel-facies subcontinental lithospheric mantle (SCLM), followed by the fractionation with insignificant crustal assimilation. The SCLM was metasomatically enriched, and the metasomatic agent was likely H2O-rich fluids rather than sediments released from subducting oceanic crust during the Late Cretaceous closure of the Neotethyan oceanic lithosphere. In conjunction with the geological background and previous data, we propose that the generation of the KQDPs resulted from a slab break-off event that caused ascending or infiltration of hot asthenosphere, triggering mantle melting. Such sporadic occurrences of the KQDPs, with coeval adakitic rocks in the SZ, are likely associated with the onset of extensional tectonics due to the earlier stage of slab break-off along the region during the early Eocene period.
- MakaleYalnız künye2020Silurian to Early Devonian arc magmatism in the western Sakarya Zone (NW Turkey), with inference to the closure of the Rheic Ocean
Karsli, Orhan; Sengün, Firat; Dokuz, Abdurrahman; Kandemir, Raif; Aydin, Faruk; Andersen, Tom
The Rheic Ocean is the most significant Paleozoic ocean that detached peri-Gondwana terranes from the northern Gondwana margin throughout the closure of the Iapetus Ocean. The suture of the Rheic Ocean spreads from Mexico to the Middle East, and the timing of its final closure is well-documented by the rocks formed in the Variscan-Alleghanian-Ouachita orogeny which led to the formation of the supercontinent Pangaea. However, as robust paleomagnetic and quantitative data are mostly lacking, the onset and evolution of the subduction of the Rheic Ocean are highly speculative, and they require further confirmation. Recently, the well-preserved metagranitoids along the western Sakarya Zone (SZ) in Anatolia have been identified, and they provide new data that improve our knowledge on the evolution of the Early Paleozoic Rheic Ocean along the northern Gondwana. Here, we present new geochronological, in situ zircon Hf isotope, and whole-rock geochemical analyses of these metagranitoids from the western SZ to enhance our understanding of the subduction processes of the Rheic Ocean. IA-ICP-MS zircon U-Pb dating demonstrated that the Boziiyuk and Borcak metagranitoids from the western SZ were emplaced during the Silurian to Early Devonian (431 +/- 2.7 to 403 +/- 3.5 Ma). The both granitoids have medium- to high-K. calc-alkaline magmatic character, and exhibit peraluminous to slightly metaluminous geochemical signature. They show a typical arc pattern in terms of trace elements and have a uniform, moderate negative epsilon(Hf) (t) of -3.2 to -9.7, with Mesoproterozoic Hf depleted mantle model ages (T-DM1 = 12 to 1.4 Ga). The geochemical and isotopic characteristics are not consistent with those of depleted mantle melts and melts derived from the crustal rocks in an intracontinental environment. Instead, the parental magma is likely generated from the partial melting of a homogeneous and enriched mantle wedge source. We propose that the Silurian to Early Devonian arc-related magmatism is associated with a northward subduction episode of the Rheic Oceanic lithosphere beneath the peri-Gondwana terranes. Hence, we consider that the opening of Paleotethys Ocean formed in a back-arc basin of subduction in Andean style to the north rather than a continental rift to the south in response to south-directed and short-lived supra-subduction zone (SSZ)-type subduction during the Silurian to Early Devonian. (C) 2020 Elsevier B.V. All rights reserved.
- MakaleYalnız künye2019Adakite-like parental melt generation by partial fusion of juvenile lower crust, Sakarya Zone, NE Turkey: A far-field response to break-off of the southern Neotethyan oceanic lithosphere
Karsli, Orhan; Dokuz, Abdurrahman; Kandemir, Raif; Aydin, Faruk; Schmitt, Axel K.; Ersoy, E. Yalçın; Alyıldız, Cihangir
The timing of major tectonic events and the driving mechanisms for magma generation during Late Cenozoic convergence and collision between Arabia and Eurasia still remain unknown. The Sakarya Zone (SZ) in northern Turkey is a critical member of this collisional assemblage. In the easternmost part of the SZ, we have recognized a Late Miocene volcanic suite termed the Çağirankaya volcanics which displays characteristic post-collisional geochemical features. Here, we report a new data set of zircon U–Pb ages, whole-rock major and trace element, as well as Sr–Nd isotope analyses for dacite and andesite samples from the Çağirankaya volcanics. Zircon U–Pb ages for a selected dacitic sample average 5.16 ± 0.11 Ma (mean square of weighted deviates, MSWD = 0.45, n = 35), confirming a late Miocene age of this volcanic episode. The high-K calc-alkaline andesites and dacites exhibit an adakite-like geochemical signature, and are characterized by high Sr (424 to 552 ppm), Sr/Y ratios (31–43), and low Mg# (42 to 46) values, along with low Y (12–14 ppm) and heavy rare earth element (HREE) concentrations, that resemble those in adakites formed by partial melting of hot oceanic slab during subduction. Isotopic compositions are near bulk Earth (87Sr/86Sr(t) = 0.70482 to 0.70489, εNd(t) = +1.08 to +1.33), which rules out a solely asthenospheric origin. Elevated Nb/Ta (14 to 17) and K2O/Na2O (0.6–1.0) imply a juvenile mafic lower crustal source composed of ~20% garnet-bearing amphibolite. Geochemical modeling suggests that adakite-like parental melts were generated in the absence of subduction and without large-scale delamination of lower continental crust. Instead, our findings suggest that Late Miocene adakite-like volcanic rocks in the SZ formed in a post-collisional intra-continental setting, which experienced far-field extension after the subducted slab of the southern Neotethyan branch became detached in the collision zone. Asthenospheric upwelling and underplating of basaltic magma provided the heat for partial melting of lower crustal amphibolite, forming minor amounts of adakite-like melts in the SZ.
- MakaleYalnız künye2019Jurassic acidic magmatism in a back-arc setting, eastern Sakarya Zone, Turkey: Geochemical constraints and an evolutionary model
Dokuz, Abdurrahman; Sünnetçi, Kadir
The Early Jurassic in the Sakarya Zone, Turkey, was dominated by basic magmatism. The products of this magmatic episode are found as basaltic lavas and pyroclastic rocks in the Şenköy Formation, which was deposited in an extensional basin, or as intrusives cutting Variscan crystalline basement rocks. The Olur (Erzurum) region in the easternmost part of the Sakarya Zone is one of the few locations where contemporaneous acidic rocks crop out, exposed in an area of ~50 km 2 . The acidic rocks in the eastern Sakarya Zone consist of dacitic lavas, rare pyroclastic rocks, and very rare pebble dikes. Porphyries and trondhjemites are their intrusive equivalents and crop out as dikes and small stocks within the underlying Variscan basement. These Early Jurassic rocks have modal K-feldspar contents of <10% and are trondhjemitic in character. Laser ablation–inductively coupled plasma–mass spectrometry U-Pb dating of zircons from two samples yielded formation ages for these rocks of 185.3 ± 1.0 and 184.1 ± 1.1 Ma (±2σ). Geochemically, the rocks are strongly peraluminous and display a medium- to low-K affinity and sodic compositions (K 2 O/Na 2 O = 0.03–0.49). Enrichment in large-ion lithophile elements and depletion in Nb, Ta, P, and Ti are regarded as signatures of a subduction-related setting. Moderately radiogenic I Sr ratios (0.70508–0.70877) and depleted mantle-like Ɛ Nd (t) values (−0.6 to +3.0) and Pb(t) isotopes suggest that the acidic rocks were derived from juvenile lower crust. Geochemical and isotope data imply that the partial melting of juvenile mafic lithologies of the lower crust produced K-poor tonalitic melts that later fractionated to trondhjemitic melts while ascending to the surface. Considering the available data, we suggest that the Early Jurassic bimodal magmatic rocks of the eastern Sakarya Zone were formed in a back-arc setting during the southward subduction of the Paleotethys oceanic lithosphere. These rocks are a prime example of the formation of shallow subduction products following Late Triassic ridge subduction.
- MakaleYalnız künye2019Postcollisional transition from subduction- to intraplatetype magmatism in the eastern Sakarya zone, Turkey: Indicators of northern Neotethyan slab breakoff
Dokuz, Abdurrahman; Aydin, Faruk; Karsli, Orhan
Postcollisional magmatism in the eastern Sakarya zone was recorded by voluminous basic volcanism and repeated plutonism during the early Cenozoic. The temporal and geochemical evolution of these magmatic rocks is important for understanding the possible geodynamic history of the Sakarya zone. Here, we investigated three representative plutons lying between the towns of çamlihemşin (Rize) and Ispir (Erzurum), Turkey. These are largely composed of medium-K gabbroic diorites (Marselavat Pluton), shoshonitic monzonites (Güllübağ Pluton), and high-K granites (Ayder Pluton). We present whole-rock geochemistry, 40Ar/39Ar geochronology, and Sr, Nd, and Pb isotope analyses from the plutons to constrain the timing of variations in magmatism and source characteristics, and we provide a new approach to the proposed geodynamic models, which are still heavily debated. The 40Ar/39Ar geochronology reveals a cooling sequence from ca. 45 Ma for the Marselavat Pluton through ca. 41 Ma for the Güllübağ Pluton to ca. 40 Ma for the Ayder Pluton. Whole-rock geochemistry and Sr, Nd, Pb isotopes suggest that crustal contamination was not an important factor affecting magma compositions. Although there was no arc-related tectonic setting in the region during the middle Eocene, the Marselavat Pluton shows some subduction affinities, such as moderately negative Nb and Ta anomalies, and slightly positive Pb anomalies. These signatures were possibly inherited from a depleted mantle source that was modified by hydrous fluids released from the oceanic slab during Late Cretaceous subduction. Geochemical traces of the earlier subduction become uncertain in the Güllübağ samples. They display ocean-island basalt-like multi-element profiles and Nb/Ta, Ce/Pb, and La/Ba ratios. All these point to a mantle source in which earlier subduction signatures were hybridized by the addition of asthenospheric melts. Melting of calc-alkaline crustal material, probably emplaced during the first phase of middle Eocene magmatism (Marselavat), led to the formation of granitic plutonism (Ayder Pluton). Our data in conjunction with early Eocene adakite-like rocks show that melt generation, as in the given sequence, was most probably triggered by breakoff of the northern Neotethyan oceanic slab, ~13 m.y. after the early Maastrichtian collision between the Sakarya zone and Anatolide-Tauride block, and continued until the end of the middle Eocene. A shallow-marine transgression occurred contemporaneously with the middle Eocene magmatism throughout the Sakarya zone. An extension in this magnitude seems unlikely to be the result of orogenic collapse processes only. The main cause of this extension was most probably related to the northward subduction of the southern Neotethys Ocean beneath the Anatolide-Tauride block. The result is a volumetrically larger amount of middle Eocene magmatism than that expected in response to slab breakoff.
- MakaleYalnız künye2018Latest Cretaceous “A2-type” granites in the Sakarya Zone, NE Turkey: Partial melting of mafic lower crust in response to roll-back of Neo-Tethyan oceanic lithosphere
Karsli, Orhan; Aydin, Faruk; Uysal, Ibrahim; Dokuz, Abdurrahman; Kumral, Mustafa; Kandemir, Raif; Budakoglu, Murat; Ketenci, Murat
An integrated study of comprehensive geochronological, geochemical, and Sr-Nd-Hf isotopic data was undertaken for the A-type Topcam pluton that intruded within the Sakarya Zone (NE Turkey) with the aims of elucidating its origin and tectonic significance and gaining new insights into the generation of aluminous A-type granites. New LA-ICP-MS zircon U-Pb crystallization ages of 72 and 73 Ma indicate emplacement in the Late Cretaceous time, just after extensive metaluminous I-type magmatism in the area. The pluton consists mainly of alkali feldspar, quartz, plagioclase, amphibole, and biotite with accessory minerals such as magnetite, apatite, and zircon. The outcrop is composed of granite, syenite, monzonite, and quartz monzonite and possesses a wide range of SiO2 content (57–70 wt%) with elevated Ga/Al ratios and low Mg# (mostly < 43). The pluton is metaluminous to weakly peraluminous, with aluminium saturation index (ASI) (molar Al2O3/[CaO + K2O + Na2O]) values of 0.82 to 1.18, and belongs to the shoshonitic and ultra-potassic series. All the samples exhibit relative enrichment in light rare earth elements (LREE) and significant negative Eu (Eu/Eu* = 0.31 to 0.86) anomalies on the chondrite-normalized REE diagram. The rocks are enriched in some large ion lithophile elements (e.g., Rb, Th and Ba), and spidergrams show a relative depletion in Nb, Ti, and Sr. The granitic rocks of the pluton have identical 87Sr/86Sr(i) ratios ranging from 0.70518 to 0.70716, relatively low εNd (t) values varying from − 5.5 to − 0.4, and TDM ages (0.82–1.19 Ga). In situ zircon analyses show that the rocks have variable negative and positive εHf (t) values (− 5.5 to 5.9) and Hf two-stage model ages (742 to 1468 Ma), which are indicative of minor addition of juvenile material. Sr-Nd isotope modelling suggests mixing of 70–90% of lower crustal-derived melt with ~ 10–30% of mantle-derived melt at lower crust depths. The heat source for partial melting is provided by upwelling of hot asthenosphere triggered by slab roll-back events. Geochemical and isotopic data reveal that metaluminous A2-type granites were derived from partial melting of the Paleozoic lower continental crust dominated by mafic rocks in amphibolitic composition, with minor input of subcontinental lithospheric mantle-derived magma followed by subsequent limited fractional crystallization to generate a variety of rock types. From integrating all available data with the regional tectonic evolution in the Sakarya Zone and adjacent regions, we attribute generation of aluminous A2-type granites to a back-arc extension in the subduction zone, which is induced by the roll-back of the Neo-Tethyan oceanic slab around 72 Ma. Consequently, we conclude that these A-type granites were related to intensive extension tectonic, which peaked during the late Cretaceous (Maastrichtian) in response to the roll-back of the Neo-Tethyan oceanic slab, which is indicative of the final-stage subduction-related magmatism in the Sakarya Zone.