Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2026Removal of Pb(II) ions from aqueous solutions by Brevibacillus agri-loaded clay: Kinetic, isotherm, and artificial neural network modeling
Belduz, Ali Osman; Inan, Kadriye; Duran, Celal; Ozdes, Duygu; Ozeken, Sengul Tugba; Nalçaoğlu, Aleyna; Şeker, Serdal
In this study, a novel and efficient adsorbent was developed by immobilizing inactivated Brevibacillus agri biomass onto an abundant natural clay via a simple synthesis route for Pb(II) removal from aqueous media. The adsorption behavior of inactivated Brevibacillus agri-loaded clay (BLC) was evaluated using batch experiments by investigating the effects of initial solution pH (2.0–6.0), BLC dosage (0.5–4.0 g/L), contact time (1–180 min), initial Pb(II) concentration (10–420 mg/L), temperature (25–80°C), and the presence of foreign ions. The optimum conditions were determined to be an initial solution pH of 5.0 and a contact time of 120 min. Isotherm models were applied to elucidate the interactions between Pb(II) ions and BLC, while kinetic studies were conducted to evaluate the adsorption performance and underlying mechanisms. The maximum adsorption capacity of BLC was determined as 65.4 mg/g according to the Langmuir isotherm model. Thermodynamic parameters revealed that Pb(II) adsorption on BLC was exothermic, feasible, and spontaneous at 25ºC. Artificial neural network (ANN) studies provided highly accurate predictions by modeling and confirmed the reliability and applicability of the model for Pb(II) removal in industrial applications. This study presents an innovative and sustainable approach for heavy metal removal, offering an effective solution applicable to environmental remediation processes.
- MakaleYayıncıda açık erişim2025Efficient extraction and determination of Au(iii) ions from acid mine drainage and water samples using silica gel immobilized with Brevibacillus borstelensis
Camoglu, Aslihan Yilmaz; Duran, Celal; Ozdes, Duygu; Nalcaoglu, Aleyna; Bektas, Kadriye Inan; Belduz, Ali Osman
The analysis of gold, which is a precious metal with limited resources, in environmental samples is crucial for the sustainable utilization of natural resources. Therefore, in the present research we have aimed to develop a novel and environmentally friendly bioadsorbent, Brevibacillus borstelensis loaded on silica gel (BB@Si), with outstanding adsorptive properties that can be implemented for quantitative recovery of Au(iii) ions via the solid phase extraction (SPE) technique. After characterizing the developed adsorbent using FTIR and SEM techniques, we conducted a detailed investigation of the critical parameters that influence the extraction performance of Au(iii) ions. Optimum parameters were observed as follows: pH 3.0, adsorption contact time 30 min, eluent type 0.1% (w/v) thiourea in 0.5 M HNO3, elution time 60 min, BB@Si amount 1.0 g L−1, and sample volume 400 mL. Some of the well-known isotherm and kinetic models were applied to the results observed from the adsorption studies. Equilibrium adsorption capacity of BB@Si was estimated to be 66.2 mg g−1 utilizing the Langmuir isotherm model while the limit of detection (LOD) and relative standard deviation (RSD%) were established as 0.99 μg L−1 and 3.7%, respectively. The developed method was utilized smoothly for the quantification of Au(iii) ions in mining wastewater, acid mine drainage (AMD), streams and seawater.