Sürdürülebilir Kalkınma Amaçları
Yayınlar
- MakaleAçık Erişim2013Separation and preconcentration of copper in environmental samples on amberlite XAD-8 resin after complexation with a carbothioamide derivative
Elvan, Hamide; Ozdes, Duygu; Duran, Celal; Sahin, Deniz; Tufekci, Mehmet; Bahadir, Zekeriyya
A new solid phase extraction (SPE) method has been developed for the selective separation and preconcentration of Cu (II) ions in food and water samples prior to its flame atomic absorption spectrometry determination. The method is based on the adsorption of the Cu(II)-2-{[4-Amino-3-(4-methylphenyl-5- oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]acetyl}-N-phenyl hydrazinecarbothioamide complex on Amberlite XAD-8 resin. The metal complex retained on the resin was eluted with 7.5 mL of 2.0 mol L-1 HCl in acetone. The optimum conditions for the SPE of Cu(II) ions were investigated, and the method was subsequently applied to sea water, stream water, rice, tea, and tobacco samples for the determination of Cu(II) levels.
- MakaleYalnız künye2013Cadmium and nickel determinations in some food and water samples by the combination of carrier element-free coprecipitation and flame atomic absorption spectrometry
Bahadir, Zekeriyya; Ozdes, Duygu; Bulut, Volkan Numan; Duran, Celal; Elvan, Hamide; Bektas, Hakan; Soylak, Mustafa
A procedure for separation and enrichment of Cd(II) and Ni(II) ions based upon carrier element-free coprecipitation by using an organic coprecipitant, 2-{4-[2-(1H-Indol-3-yl)ethyl]-3-(4-methylbenzyl)-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl}-N-(3-fluoro-phenylmethyliden) acetohydrazide, prior to their flame atomic absorption spectrometric detections has been developed. The effects of varied experimental conditions on the performance of the developed method such as pH, sample volume, amount of coprecipitating agent, etc. were evaluated in detail on the recovery of analyte ions, and the influences of some anions and cations were investigated. The limits of detection for Cd(II) and Ni(II) ions based on three times the standard deviation of the blanks (N: 10) were obtained as 0.70 g L-1 and 1.21 g L-1, respectively. The accuracy of the method was tested by analyzing a certified reference material and by spike tests. The method was applied to determine the levels of cadmium and nickel in stream and sea water, rice, red lentil, and wheat samples.