Sürdürülebilir Kalkınma Amaçları

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• MakaleAçık Erişim2026/r/gumushane/13917
  A novel cloud point extraction method using a benzimidazole-based ligand for the preconcentration of toxic heavy metals in water and food samples

  Ozdemir, Olcay; Duran, Celal; Mentese, Emre; Ozdes, Duygu

  In the present research, a novel cloud point extraction (CPE) method was developed for the separation and preconcentration of toxic Cu(ii), Ni(ii), Pb(ii), and Cd(ii) ions in environmental water and vegetable samples, prior to their determination by flame atomic absorption spectrometry (FAAS). The ligand 2-(2-(4-fluorobenzyl)-1H-benzo[d]imidazole-1-yl)acetohydrazide (FB-BIAH) was employed for the first time as an analytical complexing agent for the aforementioned metal ions, and Triton X-114 (TX-114) was preferred as the nonionic surfactant. Within the scope of optimizing CPE conditions, experimental parameters, such as pH, FB-BIAH and surfactant amounts, and incubation temperature and time, as well as centrifugation speed and duration, were systematically investigated. The optimal conditions for the simultaneous quantitative recovery of analyte ions were established as pH 7.0, an FB-BIAH amount of 2.5 mg, a TX-114 quantity of 25 mg, an incubation temperature of 60 °C, and an incubation time of 30 min. Under optimal conditions, the proposed method was successfully applied to river water and seawater, as well as different vegetable samples such as lettuce, parsley, and pepper. The results obtained demonstrated that the analyte ions could be reliably determined in complex matrices and that the method exhibited high analytical performance. Due to its simplicity, rapid applicability, environmentally friendly nature, and cost-effectiveness, the proposed CPE-FAAS method represents a promising approach for the routine analysis of toxic heavy metals in environmental water and food samples. This journal is

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• MakaleAçık Erişim2026/r/gumushane/12320
  Waste to resource approach: CoFe2O4-modified spent tea waste for magnetic solid-phase extraction of toxic metal ions from water samples

  Seker, Serdal; Ozdes, Duygu; Duran, Celal

  In this research, within the framework of a waste-to-resource conversion approach, biochar obtained from spent tea waste (STWB), a widely available and cost-free biomass source, was modified with magnetic CoFe2O4 nanoparticles to develop an environmentally friendly adsorbent (CoFe2O4/STWB). The applicability of this material for efficient separation and preconcentration of Cd(ii), Pb(ii), and Ni(ii) ions from mining wastewater, stream water, and wastewater samples collected from an organized industrial zone was systematically investigated using the solid phase extraction (SPE) method. Optimization of the experimental variables was conducted to enhance the extraction performance of the target analyte ions. The fact that the adsorption and desorption equilibrium times occur in less than 1 min demonstrates the rapid and highly efficient extraction performance of the developed adsorbent. Langmuir isotherm model analysis revealed that CoFe2O4/STWB exhibits adsorption capacities of 69.4 mg g−1 for Cd(ii), 185.2 mg g−1 for Pb(ii), and 45.2 mg g−1 for Ni(ii). In contrast, the corresponding adsorption capacities obtained for unmodified STWB were considerably lower, with values of 42.9, 75.8, and 16.8 mg g−1 for Cd(ii), Pb(ii), and Ni(ii), respectively. These results clearly demonstrate that modification with CoFe2O4 significantly enhances the adsorption performance of STWB. Consequently, CoFe2O4-modified spent tea waste can be regarded as an effective, economical, and sustainable adsorbent for trace heavy metal analysis in environmental water samples, owing to its rapid extraction kinetics, high adsorption capacity, and low detection limits. This journal is

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• MakaleYayıncıda açık erişim2025/r/gumushane/13812
  Efficient extraction and determination of Au(iii) ions from acid mine drainage and water samples using silica gel immobilized with Brevibacillus borstelensis

  Camoglu, Aslihan Yilmaz; Duran, Celal; Ozdes, Duygu; Nalcaoglu, Aleyna; Bektas, Kadriye Inan; Belduz, Ali Osman

  The analysis of gold, which is a precious metal with limited resources, in environmental samples is crucial for the sustainable utilization of natural resources. Therefore, in the present research we have aimed to develop a novel and environmentally friendly bioadsorbent, Brevibacillus borstelensis loaded on silica gel (BB@Si), with outstanding adsorptive properties that can be implemented for quantitative recovery of Au(iii) ions via the solid phase extraction (SPE) technique. After characterizing the developed adsorbent using FTIR and SEM techniques, we conducted a detailed investigation of the critical parameters that influence the extraction performance of Au(iii) ions. Optimum parameters were observed as follows: pH 3.0, adsorption contact time 30 min, eluent type 0.1% (w/v) thiourea in 0.5 M HNO3, elution time 60 min, BB@Si amount 1.0 g L−1, and sample volume 400 mL. Some of the well-known isotherm and kinetic models were applied to the results observed from the adsorption studies. Equilibrium adsorption capacity of BB@Si was estimated to be 66.2 mg g−1 utilizing the Langmuir isotherm model while the limit of detection (LOD) and relative standard deviation (RSD%) were established as 0.99 μg L−1 and 3.7%, respectively. The developed method was utilized smoothly for the quantification of Au(iii) ions in mining wastewater, acid mine drainage (AMD), streams and seawater.

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